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The development of a comprehensive battery simulator is essential for future improvements in the durability, performance and service life of lithium-ion batteries. Although simulations can never replace actual experimental data, they can still be used to provide valuable insights into the performance of the battery, especially under different operating conditions. In addition, a single-cell model can be easily extended to the pack level and can be used in the optimization of a battery pack. The first step in building a simulator is to create a model that can effectively capture both the voltage response and thermal behavior of the battery. Since these effects are coupled together, creating a robust simulator requires modeling both components. This paper will develop a battery simulator, where the entire battery model will be composed of four smaller submodels: a heat generation model, a thermal model, a battery parameter model and a voltage response model.

In this paper, a degradation testing of a lithium-ion battery used for an electric vehicle (EV) is performed and the capacity fade is measured over 400 cycles. For this, a 200 Ah LiFePO4 battery cell is tested under ambient temperature conditions with charge-discharge cycles at rate of 1C (constant current). Additionally, individual cell characterization is conducted using a C/25 (0.8A) charge-discharge cycle and hybrid pulse power characterization (HPPC). Later, the Thevenin battery model was constructed in MATLAB along with an empirical degradation model and validated in terms of voltage for all cycles. It is also found that the presented model closely estimated the profiles observed in the experimental data. Data collected from the experimental results showed that a capacity fade occurred over the 400 cycles and the discharge capacity at the end of 400th cycle is found to be 137.73 Ah. The error between model/experiments is found to be less than 3.5% for all cycles.