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Journal Article

Physics-Based Models, Sensitivity Analysis, and Optimization of Automotive Batteries

2013-10-14
2013-01-2560
The analysis of nickel metal hydride (Ni-MH) battery performance is very important for automotive researchers and manufacturers. The performance of a battery can be described as a direct consequence of various chemical and physical phenomena taking place inside the container. In this paper, a physics-based model of a Ni-MH battery will be presented. To analyze its performance, the efficiency of the battery is chosen as the performance measure, which is defined as the ratio of the energy output from the battery and the energy input to the battery while charging. Parametric sensitivity analysis will be used to generate sensitivity information for the state variables of the model. The generated information will be used to showcase how sensitivity information can be used to identify unique model behavior and how it can be used to optimize the capacity of the battery. The results will be validated using a finite difference formulation.
Journal Article

Thermal Management of Lithium-Ion Pouch Cell with Indirect Liquid Cooling using Dual Cold Plates Approach

2015-04-14
2015-01-1184
The performance, life cycle cost, and safety of electric and hybrid electric vehicles (EVs and HEVs) depend strongly on their energy storage system. Advanced batteries such as lithium-ion (Li-ion) polymer batteries are quite viable options for storing energy in EVs and HEVs. In addition, thermal management is essential for achieving the desired performance and life cycle from a particular battery. Therefore, to design a thermal management system, a designer must study the thermal characteristics of batteries. The thermal characteristics that are needed include the surface temperature distribution, heat flux, and the heat generation from batteries under various charge/discharge profiles. Therefore, in the first part of the research, surface temperature distribution from a lithium-ion pouch cell (20Ah capacity) is studied under different discharge rates of 1C, 2C, 3C, and 4C.
Technical Paper

Effect of Cross Flow on Performance of a PEM Fuel Cell

2007-04-16
2007-01-0697
A serpentine flow channel is one of the most common and practical channel layouts for a PEM fuel cell since it ensures the removal of water produced in a cell. While the reactant flows along the flow channel, it can also leak or cross to neighboring channels via the porous gas diffusion layer due to a high pressure gradient. Such a cross flow leads to effective water removal in a gas diffusion layer thus enlarging the active area for reaction although this cross flow has largely been ignored in previous studies. In this study, neutron radiography is applied to investigate the liquid water accumulation and its effect on the performance of a PEM fuel cell. Liquid water tends to accumulate in the gas diffusion layer adjacent to the flow channel area while the liquid water formed in the gas diffusion layer next to the channel land area seems to be effectively removed by the cross leakage flow between the adjacent flow channels.
Technical Paper

An Analytical Analysis on the Cross Flow in a PEM Fuel Cell with Serpentine Channel

2008-04-14
2008-01-0314
A serpentine flow channel can be considered as neighboring channels connected in series, and is one of the most common and practical channel layouts for PEM fuel cells since it ensures the removal of liquid water produced in a cell with excellent performance and acceptable parasitic load. During the reactant flows along the flow channel, it can also leak or cross directly to the neighboring channel via the porous gas diffusion layer due to the high pressure gradient caused by the short distance. Such a cross flow leads to a larger effective flow area resulting in a substantially lower amount of pressure drop in an actual PEM fuel cell compared to the case without cross flow. In this work, an analytical solution is obtained for the cross flow in a PEM fuel cell with a serpentine flow channel based on the assumption that the velocity of cross flow is linearly distributed in the gas diffusion layer between two successive U-turns.
Technical Paper

Extended Range Electric Vehicle Powertrain Simulation, and Comparison with Consideration of Fuel Cell and Metal-Air Battery

2017-03-28
2017-01-1258
The automobile industry has been undergoing a transition from fossil fuels to a low emission platform due to stricter environmental policies and energy security considerations. Electric vehicles, powered by lithium-ion batteries, have started to attain a noticeable market share recently due to their stable performance and maturity as a technology. However, electric vehicles continue to suffer from two disadvantages that have limited widespread adoption: charging time and energy density. To mitigate these challenges, vehicle Original Equipment Manufacturers (OEMs) have developed different vehicle architectures to extend the vehicle range. This work seeks to compare various powertrains, including: combined power battery electric vehicles (BEV) (zinc-air and lithium-ion battery), zero emission fuel cell vehicles (FCV)), conventional gasoline powered vehicles (baseline internal combustion vehicle), and ICE engine extended range hybrid electric vehicle.
Technical Paper

Measurement of Temperature Gradient (dT/dy) and Temperature Response (dT/dt) of a Prismatic Lithium-Ion Pouch Cell with LiFePO4 Cathode Material

2017-03-28
2017-01-1207
Lithium-ion batteries, which are nowadays common in laptops, cell phones, toys, and other portable electronic devices, are also viewed as a most promising advanced technology for electric and hybrid electric vehicles (EVs and HEVs), but battery manufacturers and automakers must understand the performance of these batteries when they are scaled up to the large sizes needed for the propulsion of the vehicle. In addition, accurate thermo-physical property input is crucial to thermal modeling. Therefore, a designer must study the thermal characteristics of batteries for improvement in the design of a thermal management system and also for thermal modeling. This work presents a purely experimental thermal characterization in terms of measurement of the temperature gradient and temperature response of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration.
Technical Paper

Efficient Electro-Thermal Model for Lithium Iron Phosphate Batteries

2018-04-03
2018-01-0432
The development of a comprehensive battery simulator is essential for future improvements in the durability, performance and service life of lithium-ion batteries. Although simulations can never replace actual experimental data, they can still be used to provide valuable insights into the performance of the battery, especially under different operating conditions. In addition, a single-cell model can be easily extended to the pack level and can be used in the optimization of a battery pack. The first step in building a simulator is to create a model that can effectively capture both the voltage response and thermal behavior of the battery. Since these effects are coupled together, creating a robust simulator requires modeling both components. This paper will develop a battery simulator, where the entire battery model will be composed of four smaller submodels: a heat generation model, a thermal model, a battery parameter model and a voltage response model.
Technical Paper

Degradation Testing and Modeling of 200 Ah LiFePO4 Battery

2018-04-03
2018-01-0441
In this paper, a degradation testing of a lithium-ion battery used for an electric vehicle (EV) is performed and the capacity fade is measured over 400 cycles. For this, a 200 Ah LiFePO4 battery cell is tested under ambient temperature conditions with charge-discharge cycles at rate of 1C (constant current). Additionally, individual cell characterization is conducted using a C/25 (0.8A) charge-discharge cycle and hybrid pulse power characterization (HPPC). Later, the Thevenin battery model was constructed in MATLAB along with an empirical degradation model and validated in terms of voltage for all cycles. It is also found that the presented model closely estimated the profiles observed in the experimental data. Data collected from the experimental results showed that a capacity fade occurred over the 400 cycles and the discharge capacity at the end of 400th cycle is found to be 137.73 Ah. The error between model/experiments is found to be less than 3.5% for all cycles.
Technical Paper

The University of Waterloo Alternative Fuels Team's Approach to EcoCAR 2

2012-09-10
2012-01-1761
A series plug-in hybrid electric powertrain with all-wheel drive is designed using real-world drive cycles as part of the EcoCAR 2 competition. A stock 2013 Chevrolet Malibu Eco is being re-engineered to reduce fuel consumption and emissions while improving consumer acceptability. Waterloo utilizes a 18.9 kWh A123 energy storage system (ESS), which powers two 105 kW TM4 traction motors. A 2.4 L LE9 General Motors coupled to a 105 kW TM4 motor provides range extending performance. Each step of the design process is discussed, including a novel approach to powertrain selection and controls requirement selection that uses real-world drive cycles. The mechanical integration and unique ESS design is also discussed.
Technical Paper

A Review Study of Methods for Lithium-ion Battery Health Monitoring and Remaining Life Estimation in Hybrid Electric Vehicles

2012-04-16
2012-01-0125
Due to the high power and energy density and also relative safety, lithium ion batteries are receiving increasing acceptability in industrial applications especially in transportation systems with electric traction such as electric vehicles and hybrid electric vehicles. In this regard, to ensure performance reliability, accurate modeling of calendar life of such batteries is a necessity. In fact, potential failure of Li-ion battery packs remains a barrier to commercialization. Battery pack life is a critical feature to warranty and maintenance planning for hybrid vehicles, and will require adaptive control systems to account for the loss in vehicle range, and loss in battery charge and discharge efficiency. Failure not only results in large replacement costs, but also potential safety concerns such as overheating or short circuiting which may lead to fires.
Technical Paper

Impact of Temperature on the A123 Li-Ion Battery Performance and Hybrid Electric Vehicle Range

2013-04-08
2013-01-1521
Within the last decade, the automotive industry has made major progress toward the electrification of drive trains and application of electrochemical power sources. Among available storage solutions, Li-ion batteries are considered as the most attractive and are set to be used in the next generation of hybrid and electric vehicles. This is due to their superiority in energy density, power density, and low self-discharge and high cycle life compared to other chemistries. However, there are some limitations associated with Li-ion battery; among them is the operating temperature range. Any deviation from a narrow temperature range may result in low overall performance and potential degradation of the cells. In this paper, impact of ambient temperature on the A123 Li-ion batteries performance is investigated. A123 cells have been tested under constant charge-discharge cycles, hybrid pulse power characterization (HPPC) tests and also standard drive cycle tests.
Technical Paper

Fuel Cell Hybrid Control Strategy Development

2006-04-03
2006-01-0214
Supervisory control strategies for a hybrid fuel cell powertrain are developed and simulated using Simulink models and the Powertrain Systems Analysis Toolkit (PSAT). The control strategy selects the power splitting ratio between a 65kW Hydrogenics fuel cell power module and a 70kW Cobasys Nickel Metal Hydride (NiMH) battery pack. Simple control algorithms targeting a battery pack State of Charge (SOC), or maximizing the instantaneous powertrain efficiency are initially considered and analyzed. A comprehensive control strategy optimizing powertrain efficiency, vehicle performance, emissions, and long-term reliability is then developed and simulated. The simulated vehicle using the comprehensive control strategy with reliability considerations exhibits a 21% mileage improvement as compared to a simple rule-based control algorithm.
Technical Paper

Fuel Cell Hybrid Powertrain Design Approach for a 2005 Chevrolet Equinox

2006-04-03
2006-01-0744
A fuel cell-battery hybrid powertrain SUV vehicle is designed using an optimized model-based design process. Powertrain and fuel storage components selected include a 65 kW Polymer Electrolyte Membrane Fuel Cell (PEMFC) power module, two 67 kW electric traction motors, a 35 MPa compressed hydrogen storage tank, a 70 kW nickel metal hydride battery pack, and a University of Waterloo in-house DC/DC converter design. Hardware control uses two controllers, a main supervisory controller and a subsystem controller in addition to any embedded component control modules. Two key innovations of this work include the hybrid control strategy and the DC/DC converter. The final powertrain characteristics are expected to meet a set of Vehicle Technical Specifications (VTS).
Technical Paper

Design of a Test Geometry to Characterize Sheared Edge Fracture in a Uniaxial Bending Mode

2023-04-11
2023-01-0730
The characterization of sheet metals under in-plane uniaxial bending is challenging due to the aspect ratios involved that can cause buckling. Anti-buckling plates can be employed but require compensation for contact pressure and friction effects. Recently, a novel in-plane bending fixture was developed to allow for unconstrained sample rotation that does not require an anti-buckling device. The objective of the present study is to design the sample geometry for sheared edge fracture characterization under in-plane bending along with a methodology to resolve the strains exactly at the edge. A series of virtual experiments were conducted for a 1.0 mm thick model material with different hardening rates to identify the influence of gage section length, height, and the radius of the transition region on the bend ratio and potential for buckling. Two specimen geometries are proposed with one suited for constitutive characterization and the other for sheared edge fracture.
Technical Paper

Numerical Prediction of the Autoignition Delay in a Diesel-Like Environment by the Conditional Moment Closure Model

2000-03-06
2000-01-0200
The autoignition delay of a turbulent methane jet in a Diesel-like environment is calculated by the conditional moment closure(CMC) model. Methane is injected into hot air in a constant volume chamber under various temperatures and pressures. Detailed chemical reaction mechanisms are implemented with turbulence-chemistry interaction treated by the first order CMC. The CMC model solves the conditional mean species mass fraction and temperature equations with the source term given in terms of the conditional mean quantities. The flow and mixing field are calculated by the transient SIMPLE algorithm with the k -ε model and the assumed beta function pdf. The CMC equations are solved by the fractional step method which sequentially treats the transport and chemical reaction terms in each time step. The predictions in quiescent homogeneous mixture are presented to evaluate the effects of turbulence in jet ignition.
Technical Paper

Three-Dimensional Electrochemical Analysis of a Graphite/LiFePO4 Li-Ion Cell to Improve Its Durability

2015-04-14
2015-01-1182
Lithium-ion batteries (LIBs) are one of the best candidates as energy storage systems for automobile applications due to their high power and energy densities. However, durability in comparison to other battery chemistries continues to be a key factor in prevention of wide scale adoption by the automotive industry. In order to design more-durable, longer-life, batteries, reliable and predictive battery models are required. In this paper, an effective model for simulating full-size LIBs is employed that can predict the operating voltage of the cell and the distribution of variables such as electrochemical current generation and battery state of charge (SOC). This predictive ability is used to examine the effect of parameters such as current collector thickness and tab location for the purpose of reducing non-uniform voltage and current distribution in the cell. It is identified that reducing the non-uniformities can reduce the ageing effects and increase the battery durability.
Technical Paper

Thermal Behavior of Two Commercial Li-Ion Batteries for Plug-in Hybrid Electric Vehicles

2014-04-01
2014-01-1840
In electrified vehicle applications, the heat generated of lithium-ion (Li-ion) cells may significantly affect the vehicle range and state of health (SOH) of the pack. Therefore, a major design task is creation of a battery thermal management system with suitable control and cooling strategies. To this end, the thermal behavior of Li-ion cells at various temperatures and operating conditions should be quantified. In this paper, two different commercial pouch cells for plug-in hybrid electric vehicles (PHEVs) are studied through comprehensive thermal performance tests. This study employs a fractional factorial design of experiments to reduce the number of tests required to characterize the behavior of fresh cells while minimizing the effects of ageing. At each test point, the effects of ambient temperature and charge/discharge rate on several types of cell efficiencies and surface heat generation are evaluated.
Technical Paper

Modeling and Evaluation of Li-Ion Battery Performance Based on the Electric Vehicle Field Tests

2014-04-01
2014-01-1848
In this paper, initial results of Li-ion battery performance characterization through field tests are presented. A fully electrified Ford Escape that is equipped by three Li-ion battery packs (LiFeMnPO4) including an overall 20 modules in series is employed. The vehicle is in daily operation and data of driving including the powertrain and drive cycles as well as the charging data are being transferred through CAN bus to a data logger installed in the vehicle. A model of the vehicle is developed in the Powertrain System Analysis Toolkit (PSAT) software based on the available technical specification of the vehicle components. In this model, a simple resistive element in series with a voltage source represents the battery. Battery open circuit voltage (OCV) and internal resistance in charge and discharge mode are estimated as a function of the state of charge (SOC) from the collected test data.
Technical Paper

Evaluation of Air Conditioning Impact on the Electric Vehicle Range and Li-Ion Battery Life

2014-04-01
2014-01-1853
Despite significant progress toward application of Li-ion batteries in electric vehicles, there are still major concerns about the range of electric vehicles and battery life. Depending on the climate of the region where the vehicle is in use, auxiliary loads could also play a significant role on the battery performance and durability. In this paper, the effect of air conditioning (AC) load on the electric range and Li-ion battery life is evaluated. For this purpose, a thermodynamic model for the vehicle cabin is developed and integrated to a battery model. The thermodynamic model takes the ambient conditions, solar load, and the vehicle drive cycle as inputs and calculates the instantaneous cabin temperature and humidity. The battery model, which represents a Li-on battery pack installed on a fully electrified Ford Escape 2009, consists of a voltage source in series with a lump resistance, a thermal sub-model, and a degradation sub-model to predict the battery capacity fade.
Technical Paper

Comparison of Optimization Techniques for Lithium-Ion Battery Model Parameter Estimation

2014-04-01
2014-01-1851
Due to rising fuel prices and environmental concerns, Electric Vehicles (EVs) and Hybrid Electric Vehicles (HEVs) have been gaining market share as fuel-efficient, environmentally friendly alternatives. Lithium-ion batteries are commonly used in EV and HEV applications because of their high power and energy densities. During controls development of HEVs and EVs, hardware-in-the-loop simulations involving real-time battery models are commonly used to simulate a battery response in place of a real battery. One physics-based model which solves in real-time is the reduced-order battery model developed by Dao et al. [1], which is based on the isothermal model by Newman [2] incorporating concentrated solution theory and porous electrode theory [3]. The battery models must be accurate for effective control; however, if the battery parameters are unknown or change due to degradation, a method for estimating the battery parameters to update the model is required.
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