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Empirical models for engine-out oxides of Nitrogen (NOx) and smoke emissions have been developed for the purpose of minimizing transient emissions while maintaining transient response. Three major issues have been addressed: data acquisition, data processing and modeling method. Real and virtual transient parameters have been identified for acquisition. Accounting for the phase shift between transient engine events and transient emission measurements has been shown to be very important to the quality of model predictions. Several methods have been employed to account for the transient transport delays and sensor lags which constitute the phase shift. Finally several different empirical modeling methods have been used to determine the most suitable modeling method for transient emissions. These modeling methods include several kinds of neural networks, global regression and localized regression.

A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.

One field-returned DPF loaded with a high amount of ash is examined using experimental and modeling approaches. The ash-related design factors are collected by coupling the inspection results from terahertz spectroscopy with a calibrated DPF model. The obtained ash packing density, ash layer permeability and ash distribution profile are then used in the simulation to assess the ash impact on DPF backpressure and regeneration behaviors. The following features have been observed during the simulation: 1 The ash packing density, ash layer permeability and ash distribution profile should be collected at the same time to ensure the accurate prediction of ash impact on DPF backpressure. Missing one ash property could mislead the measurement of the other two parameters and thus affects the DPF backpressure estimation. 2 The ash buildup would gradually increase the frequency for the backpressure-based active soot regeneration.

The performance, life cycle cost, and safety of electric and hybrid electric vehicles (EVs and HEVs) depend strongly on their energy storage system. Advanced batteries such as lithium-ion (Li-ion) polymer batteries are quite viable options for storing energy in EVs and HEVs. In addition, thermal management is essential for achieving the desired performance and life cycle from a particular battery. Therefore, to design a thermal management system, a designer must study the thermal characteristics of batteries. The thermal characteristics that are needed include the surface temperature distribution, heat flux, and the heat generation from batteries under various charge/discharge profiles. Therefore, in the first part of the research, surface temperature distribution from a lithium-ion pouch cell (20Ah capacity) is studied under different discharge rates of 1C, 2C, 3C, and 4C.

Forecasting the motion of the leading vehicle is a critical task for connected autonomous vehicles as it provides an efficient way to model the leading-following vehicle behavior and analyze the interactions. In this study, a personalized time-series modeling approach for leading vehicle trajectory prediction considering different driving styles is proposed. The method enables a precise, personalized trajectory prediction for leading vehicles with limited inter-vehicle communication signals, such as vehicle speed, acceleration, space headway, and time headway of the front vehicles. Based on the learning nature of human beings that a human always tries to solve problems based on grouping and similar experience, three different driving styles are first recognized based on an unsupervised clustering with a Gaussian Mixture Model (GMM).

The vision for the future automotive chassis is to interconnect the lateral, longitudinal, and vertical dynamics by separately controlling driving, braking, steering, and damping of each individual wheel. A major advantage of all wheel drive electric vehicles with four in-wheel motors is the possibility to control the torque and speed at each wheel independently. This paper proposes a traction controller for such a vehicle. It estimates the road's adhesion potential at each wheel and adjusts each motor voltage, such that the longitudinal slip is kept in an optimal range. For development and validation, a full vehicle model is designed in ADAMS/View software, in co-simulation with motor and control elements, modeled in MATLAB/Simulink.

The performance of a commercial Cu-zeolite SCR catalyst after differing degrees of hydrothermal aging (aged for 72 hours at 500, 700 and 800°C with 10% moisture balanced with air) was studied by spatially resolving different key reactions using gas-phase FTIR measurements. Gases were sampled along a channel at different positions and analyzed using FTIR, which overcomes the interference of water and nitrogen on ammonia concentration detection encountered in standard mass spectrometer-based spatial resolution measurements. The NO:NO₂ concentration ratio was changed so that the standard (NO:NO₂ = 1:0), fast (NO:NO₂ = 1:1) and NO₂ (NO:NO₂ = 0:1) SCR reactions could be investigated as a function of the catalyst's hydrothermal aging extent. In addition, the effects of hydrothermal aging on the activity of NH₃ and NO oxidation were also investigated. Hydrothermal aging had little effect on NO oxidation activity.

In this work, an alternative method is proposed and validated for quantifying the axial performance of a state-of-the-art Cu zeolite SCR catalyst. Catalyst cores of a standard length, with varying lengths of wash-coated regions were used to axially resolve the functional performance of the SCR catalyst. This proposed method was validated by quantifying the catalyst entrance and exit effects, as well as the effect of non-uniform wash-coat loading densities. This method is less susceptible to some of the complications highlighted in the previous studies, such as flow uniformity between channels, as well as radiative heating effects, since the product gases are sampled across the entire monolith cross-section rather than through a single catalyst channel. The specific catalyst functions quantified include: NO and NH₃ oxidation, NH₃ storage capacity, as well as NOx conversion efficiency.

In this study we investigated the interaction of short- and long-chain hydrocarbons (HCs), represented by propene (C₃H₆) and n-dodecane (n-C₁₂H₂₆), respectively, with a state-of-the-art small-pore Cu-Zeolite SCR catalyst. By varying HC adsorption conditions, we determined that physisorption was the primary mechanism for some minor HC storage at low temperatures (≺ 200°C), while chemical transformation was involved in more substantial HC storage at higher temperatures (200-400°C). The latter was evidenced by the oxygen-dependent and thermally activated nature of the storage process, and further confirmed by the carbon-rich composition of the deposits. The nature of HC-derived deposits of different origins and amounts was further probed using the standard SCR reaction at kinetically challenging conditions (at 200°C), as well by ammonia adsorption/desorption experiments.

Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.

For renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1001 h using 20% biodiesel blended into ultra-low sulfur diesel (B20) doped with 14 ppm Na. This Na level is equivalent to exposure to Na at the uppermost expected B100 value in a B20 blend for the system full-useful life. During the study, NOx emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement.

A simple 1-dimensional filter model, with symmetric and asymmetric channels, has been developed to investigate the fundamental behavior and performance of ceramic partial diesel particulate filters (PFs). The governing equations of mass and momentum are similar to those of a full DPF [7, 15]. A standard DPF with the plugs at its inlet face removed has been referred to as a ‘rear-plugged PF’ while, one with the plugs at the outlet face removed has been referred to as a ‘front-plugged PF’ in the present study. Removal of some of the plugs from a standard ceramic DPF reduces the (i) overall pressure drop (ΔP) across the filter, (ii) filtration efficiency (FE) of the DPF, and (iii) manufacturing cost. Partial filters stand a high chance of being deployed in diesel exhaust after-treatment systems for the emerging markets (Brazil, Russia, India, China) that follow Euro 4 emission regulations.

In this contribution, nuanced changes of a commercial Cu-SSZ-13 catalyst with hydrothermal aging, which have not been previously reported, as well as their corresponding impact on SCR functions, are described. In particular, a sample of Cu-SSZ-13 was progressively aged between 550 to 900°C and the changes of performance in NH3 storage, oxidation functionality and NOx conversion of the catalyst were measured after hydrothermal exposure at each temperature. The catalysts thus aged were further characterized by NH3-TPD, XRD and DRIFTS techniques for structural changes. Based on the corresponding performance and structural characteristics, three different regimes of hydrothermal aging were identified, and tentatively as assigned to “mild”, “severe” and “extreme” aging. Progressive hydrothermal aging up to 750°C decreased NOx conversion to a small degree, as well as NH3 storage and oxidation functions.

The conversion design strategy, and emissions and performance results for a dedicated propane, vapour injected, 1995 Dodge Dakota truck are reported. Data is obtained from the University of Waterloo entry in the 1997 Propane Vehicle Challenge. A key feature of the design strategy is its focus on testing and emissions while preserving low engine speed power for drivability. Major changes to the Dakota truck included the following: installation of a custom shaped fuel tank, inclusion of a fuel temperature control module, addition of a vaporizer and a fuel delivery metering unit, installation of a custom vapour distribution manifold, addition of an equivalence ratio electronic controller, inclusion of a wide range oxygen sensor, addition of an exhaust gas recirculation cooler and installation of thermal insulation on the exhaust system. A competition provided natural gas catalyst was used.

A serpentine flow channel is one of the most common and practical channel layouts for a PEM fuel cell since it ensures the removal of water produced in a cell. While the reactant flows along the flow channel, it can also leak or cross to neighboring channels via the porous gas diffusion layer due to a high pressure gradient. Such a cross flow leads to effective water removal in a gas diffusion layer thus enlarging the active area for reaction although this cross flow has largely been ignored in previous studies. In this study, neutron radiography is applied to investigate the liquid water accumulation and its effect on the performance of a PEM fuel cell. Liquid water tends to accumulate in the gas diffusion layer adjacent to the flow channel area while the liquid water formed in the gas diffusion layer next to the channel land area seems to be effectively removed by the cross leakage flow between the adjacent flow channels.

A fuel cell hybrid powertrain design is implemented and optimized by the University of Waterloo Alternative Fuels Team for the ChallengeX competition. A comprehensive set of bench-top and in-vehicle validation results are used to generate accurate fuel cell vehicle models for SIL/HIL control strategy testing and tuning. The vehicle is brought to a “99% buy-off” level of production readiness, and a detailed crashworthiness analysis is performed. The vehicle performance is compared to Vehicle Technical Specifications (VTS).

A serpentine flow channel can be considered as neighboring channels connected in series, and is one of the most common and practical channel layouts for PEM fuel cells since it ensures the removal of liquid water produced in a cell with excellent performance and acceptable parasitic load. During the reactant flows along the flow channel, it can also leak or cross directly to the neighboring channel via the porous gas diffusion layer due to the high pressure gradient caused by the short distance. Such a cross flow leads to a larger effective flow area resulting in a substantially lower amount of pressure drop in an actual PEM fuel cell compared to the case without cross flow. In this work, an analytical solution is obtained for the cross flow in a PEM fuel cell with a serpentine flow channel based on the assumption that the velocity of cross flow is linearly distributed in the gas diffusion layer between two successive U-turns.

Porous silicon as gas/chemical sensing material has been widely investigated in recent years. In this paper, the humidity sensing property of n-type porous silicon with ordered structure is studied for the first time. The ordered porous silicon used in this experiment has uniform pore size, pore shape and distribution. Both the membrane and closed bottom samples were studied. The resistance change of the porous silicon was measured. A 22-28% decrease of resistance was observed when relative humidity was changed from 1% to 100%. Both the response time and the recovery time were within 10 minutes, and 90% of the response can be reached in 6 minutes for the PS membrane sample. The possible sensing mechanism and future work are also discussed in this paper.

The response to increasingly stringent light duty diesel emission regulation is a nearly unanimous increase in heavy Exhaust Gas Recirculation (EGR) application to reduce feedgas NOx emissions. Little attention has been paid to the fact that heavy EGR usage is likely to push the engine operating conditions towards less efficient or even unstable regions of conventional centrifugal compressor operating maps. Moreover, the low oxygen content at part load operation also poses transient response challenges. Therefore, improving turbocharger efficiency at part load and extending the stable operating range is becoming critical for viable future low emission diesel engines. In this study of a turbocharger compression system, encompassing the airflow geometry from compressor impeller inlet to volute exit, a dual volute compressor concept was introduced, and Computational Fluid Dynamics (CFD) was used to investigate its effects on the overall expected performance level and range.

In this work, a new air hybrid engine is introduced in which two throttles are used to manage the engine load in three modes of operation i.e. braking, air motor, and conventional mode. The concept includes an air tank to store pressurized air during braking and rather than a fully variable valve timing (VVT) system, two throttles are utilized. Use of throttles can significantly reduce the complexity of air hybrid engines. The valves need three fixed timing schedules for the three modes of operation. To study this concept, for each mode, the results of engine simulations using GT-Power software are used to generate the operating maps. These maps show the maximum braking torque as well as maximum air motor torque in terms of air tank pressure and engine speed. Moreover, the resulting maps indicate the operating conditions under which each mode is more effective. Based on these maps, a power management strategy is developed to achieve improved fuel economy.