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We are witnessing a rapid and ongoing expansion of nanoscience, driven by potential applications in advanced materials and nanotechnology. There is a race to develop techniques that may allow controlling the size, shape of nanostructures that can allow the tuning of their optical and electronic properties. Plasmonics is a field that encompasses and profits from the optical enhancement in nanostructures that support plasmon excitations. One of these new techniques is surface-enhanced Raman scattering (SERS), commonly used for nanostructure characterization. In the present report, we present a theoretical model for plasmon excitation and electric field enhancement that help to provide an explanation for the special features observed in experimental SERS. Two sets of experimental results are discussed illustrating the make out of the signature of the plasmonics producing the optical enhancement.

Experimental and numerical studies have been completed on the deformation behaviour of round AA6061-T6 aluminum extrusions during an axial cutting deformation mode employing both curved and straight deflectors to control the bending deformation of petalled side walls. Round extrusions of length 200 mm with a nominal wall thickness of 3.175 mm and an external diameter of 50.8 mm were considered. A heat treated 4140 steel alloy cutter and deflectors, both straight and curved, were designed and manufactured for the testing considered. The four blades of the cutter had an approximate average thickness of 1.00 mm which were designed to penetrate through the round AA6061-T6 extrusions. Experimental observations illustrated high crush force efficiencies of 0.82 for the extrusions which experienced the cutting deformation mode with the deflectors. Total energy absorption during the cutting process was approximately 5.48 kJ.

Fatigue analysis incorporating explicit finite element simulation was conducted on a forged magnesium wheel model where a rotating bend moment was applied to the hub to simulate rotary fatigue testing. Based on wheel fatigue design criteria and a developed fatigue post-processor, the safety factor of fatigue failure was calculated for each finite element. Fatigue failure was verified through experimental testing. Design modifications were proposed by increasing the spoke thickness. Further numerical and experimental testing indicated that the modified design passed the rotary fatigue test.

Carburized parts often see use in powertrain components for the automotive industry. These parts are commonly quenched and tempered after the carburizing process. The present study compared the austempering heat treatment to the traditional quench-and-temper process for carburized parts. Samples were produced from SAE 8620, 4320, and 8822 steels and heat treated across a range of conditions for austempering and for quench-and-tempering. Distortion was examined through the use of Navy C-Ring samples. Microstructure, hardness, and Charpy toughness were also examined. X-ray diffraction was used to compare the residual stress found in the case of the components after the quench-and-temper and the austempering heat treatments. Austempering samples showed less distortion and higher compressive residual stresses, while maintaining comparable hardness values in both case and core. Toughness measurements were also comparable between both processes.

Gray cast iron brake rotor experiences substantial wear during braking and contributes largely to the wear debris emissions. Surface coating on the gray cast iron rotor represents a trending approach dealing with the problems. In this research, a new plasma electrolytic aluminating (PEA) process was used for preparing an alumina-based ceramic coating with metallurgical bonding to the gray cast iron. Three different types of brake pads (ceramic, semi-metallic and non asbestos organic (NAO)) were used for tribotests. Performances of PEA coatings vs. different brake pad materials were comparatively investigated with respect to their coefficients of friction (COFs) and wear. The PEA-coated brake rotor has a dimple-like surface which promotes the formation of a thin transferred film to protect the rotor from wear. The transferred film materials come from the wear debris of the pads. The secondary plateaus are regenerated on the brake pads through compacting wear debris of the pads.

Sliding wear of magnesium (Mg) engine cylinder bore surfaces and corrosion of Mg engine coolant channels are the two unsolved critical issues that automakers have to deal with in development of magnesium-intensive engines. In this paper, Plasma Electrolytic Oxidation (PEO) process was used to produce oxide coatings on AJ62 Mg alloy to provide wear and corrosion protection. In order to optimize the PEO process, orthogonal experiments were conducted to investigate the effect of PEO process parameters on the wear properties of PEO coatings. The PEO coatings showed a much better wear resistance, as well as a smaller friction coefficient, than the AJ62 substrate. The galvanic corrosion property of AJ62 Mg coupled with stainless steel and aluminum (Al) was investigated via immersion corrosion test in an engine coolant. Applying PEO coating on Mg can effectively prevent the galvanic corrosion attack to Mg.

A Mg-5.0wt.%Al-2.0wt.%Ca alloy (AC52) was cast at different cooling rates varying from 0.5 to 65 °C/s. The dendrites was characterized by determining the secondary dendrite arm spacing (SDAS) and the volume fraction of secondary eutectic phases with the linear intercept and point counting methods, respectively. The SDAS decreases significantly with increasing cooling rates, while the volume fraction of the eutectic phase increases from 10.8 ± 1.44 vol.% at 0.5 °C/s to 20.4 ± 1.52 vol.% at 20 °C/s. However, a further increase in cooling rate beyond 20 °C/s has limited influence on the volume fraction of eutectic phases. A large number of dispersed eutectic phases were observed in the primary α-Mg of the alloys cast at low cooling rates. Although, at the microscale, there were no dispersed eutectic phases in alloys cast at a high cooling rate of 30 °C/s, nanoscale eutectic phases were found by TEM observation.

The implementation of fuel cell-battery hybrid vehicles requires a supervisory control strategy that manages the power distribution between the fuel cell and the energy storage device (i.e., battery). Several advanced control methods have already been developed and published in literature. However, most control methods have been developed for different vehicle types and using different mathematical models. The performance of these power management methods have not been directly compared for the same application. This study aims at obtaining direct analytical comparisons, which will provide useful insight in selecting a power management method for fuel cell-battery hybrid vehicles.

Hybrid Vehicles have gained momentum in the automotive industry. The joint action of power sources and energy storage systems for energizing the vehicle improves the vehicle's fuel economy while reducing its pollutant emissions and noise levels, challenging automotive designers to optimize vehicle's cost, weight and control. The marketing success of hybrid vehicles significantly depends on the selection, integration and cost of the energy systems. The internal combustion engine, dominant of the vehicle market, has been the “option of choice” for auxiliary power unit of the hybrid vehicle, although other power sources as fuel cells, Stirling engines and gas turbines have been employed as well [1]. This document is focused in the application of Stirling engines as the power source for automobile propulsion.

Stabilized Aluminum Foam (SAF) is a material produced by introducing gas bubbles into molten aluminum. Two examples will be used to illustrate the potential use of SAF in energy absorption and structural reinforcement applications. The first is use of SAF in a crashbox to absorb energy in a 15km/hr collision and prevent damage to the rails as part of a front-end energy management system. The second is as a filler in a hollow structure subject to bending loads, which potentially could find application in rails and pillars. By filling a hollow structure with SAF, the bending strength is increased dramatically while the weight increases are not significant. Numerical modeling using LS DYNA gave very good agreement with experimental results.

Laser cladding is a novel process of surface coating, and researchers in both academia and industry are developing additive manufacturing solutions for large, metallic components. There are many interlinked process parameters associated with laser cladding, which may have an impact on the resultant microhardness profile throughout the bead zone. A set of single bead laser cladding experiments were done using a 4 kW fiber laser coupled with a 6-axis robotic arm for 420 martensitic stainless steel powder. A design of experiments approach was taken to explore a wide range of process parameter settings. The goal of this research is to determine whether robust predictive models for hardness can be developed, and if there are predictive trends that can be employed to optimize the process settings for a given set of process parameters and microhardness requirements.

Cylindrical extrusions of magnesium AZ31B were subjected to quasi-static axial compression and cutting modes of deformation to study this alloy’s effectiveness as an energy absorber. For comparison, the tests were repeated using extrusions of AA6061-T6 aluminum of the same geometry. For the axial compression tests, three different end geometries were considered, namely (1) a flat cutoff, (2) a 45 degree chamfer, and (3) a square circumferential notch. AZ31B extrusions with the 45 degree chamfer produced the most repeatable and stable deformation of a progressive fracturing nature, referred to as sharding, with an average SEA of 40 kJ/kg and an average CFE of 45 %, which are nearly equal to the performance of the AA6061-T6. Both the AZ31B specimens with the flat cutoff and the circumferential notch conditions were more prone to tilt mid-test, and lead to an unstable helical fracture, which significantly reduced the SEA.

Ultra-high strength steel (UHSS) and magnesium (Mg) alloy have found their importance in response to automotive strategy of light weighting. UHSS to be metal-formed by hot stamping usually has a hot-dipped aluminum-silicon alloy layer on its surface to prevent the high temperature scaling during the hot stamping and corrosion during applications. In this paper, a plasma electrolytic oxidation (PEO) process was used to produce ceramic oxide coatings on aluminized UHSS and Mg with intention to further improve their corrosion resistances. A potentiodynamic polarization corrosion test was employed to evaluate general corrosion properties of the individual alloys. Galvanic corrosion of the aluminized UHSS and magnesium alloy coupling with and without PEO coatings was studied by a zero resistance ammeter (ZRA) test. It was found that the heating-cooling process simulating the hot stamping would reduce anti-corrosion properties of aluminized UHSS due to the outward iron diffusion.

A three-pole spark igniter, with the concept to broaden the ignition area, is employed in this paper to investigate the effect of spark discharge strategies on the early ignition burning process. The prototyped three-pole igniter has three independent spark gaps arranged in a triangular pattern with a circumradius of 2.3 mm. Direct-capacitor discharge techniques, utilizing close-coupled capacitors parallel to the spark gap, are applied on the three-pole igniter to enhance either the transient spark power or the overall energy. In particular, the simultaneous discharge of high energy plasma on three spark gaps can produce a surface-like ignition process which intensifies the plasma-flame interaction, thereby producing a rapid flame kernel development. The ignition strategies are evaluated in both constant volume combustion vessels and a modified single-cylinder metal engine.

Automobile body panels made from advanced high strength steel (AHSS) provide high strength-to-mass ratio and thus AHSS are important for automotive light-weighting strategy. However, in order to increase their use, the significant wear damage that AHSS sheets cause to the trim dies should be reduced. The wear of dies has undesirable consequences including deterioration of trimmed parts' edges. In this research, die wear measurement techniques that consisted of white-light optical interferometry methods supported by large depth-of-field optical microscopy were developed. 1.4 mm-thick DP980-type AHSS sheets were trimmed using dies made from AISI D2 steel. A clearance of 10% of the thickness of the sheets was maintained between the upper and lower dies. The wear of the upper and lower dies was evaluated and material abrasion and chipping were identified as the main damage features at the trim edges.

In this work, a pseudo three-dimensional coupled thermal-electrochemical model is established to estimate the heat generation and temperature profiles of a lithium ion battery as functions of the state of the discharge. Then, this model is used to investigate the effectiveness of active and passive thermal management systems. The active cooling system utilizes cooling plate and water as the working fluid while the passive cooling system incorporates a phase change material (PCM). The thermal effects of coolant flow rate examined using a computational fluid dynamics model. In the passive cooling system, Paraffin wax used as a heat dissipation source to control battery temperature rise. The effect of module size and battery spacing is studied to find the optimal weight of PCM required. The results show that although the active cooling system has the capability to reduce the peak temperatures, it leads to a large temperature difference over the battery module.

Alumina (Al2O3) thin film coatings are applied on Al alloys using Plasma Electrolytic Oxidation (PEO) method to reduce the wear and corrosion problems. Plasma Electrolytic Aluminating (PEA) is a technique which could generate Alumina coatings on cast iron, mild steel and copper alloys. In this study, the aim is to explore the anti-wear and anti-corrosion behaviours of PEA Alumina coatings on gray cast iron. The dry sliding tribology test data was obtained from Pin-on-Disk (POD) tests against SAE 52100 steel and Tungsten Carbide (WC) counterfaces. Comparing with the PEO Alumina coatings, the PEA Alumina coating has much lower Coefficient of Friction (COF) and less wear. The microstructure, chemical composition and phase composition of this coating were investigated with Scanning Electron Microscope (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX) and X-Ray Diffraction (XRD), respectively. There was FeO (or FeAl2O4) found on the PEA Alumina coating.

Explicit finite element simulations were conducted on an aluminum wheel model where a rotating bend moment was applied on its hub to simulate wheel cornering fatigue testing. A post-processor was developed to calculate equivalent von Mises alternating and mean stresses from stress tensor. The safety factors of fatigue design for each finite element were determined to assess the fatigue performance by utilizing the Goodman linear relationship. Elements with low safety factors were identified due to the prescribed boundary conditions and stress concentrations arising from wheel geometry.

In recent years, bearing electrical failures have been a significant concern in electric cars, restricting electric engine life. This work aims to introduce a coating approach for preventing electrical erosion on 52100 alloy steel samples, the most common material used on manufacturing bearings. This paper discusses the causes of shaft voltage and bearing currents, and summarizes standard electrical bearing failure mechanisms, such as morphological damages and lubrication failures. Alumina coatings are suitable for insulating the 52100 alloy steel samples because alumina coatings provide excellent insulation, hardness, and corrosion resistance, among other characteristics. The common method to coat an insulated alumina coating on the bearing is thermal spraying, but overspray can cause environmental issues, and the coating procedures are costly and time-consuming.

Automotive steering wheels depend on a structural skeleton made of steel, aluminum, or magnesium to be the basis for the mechanical properties of the finished part. The mechanical properties of concern are the fatigue properties and the crash performance. The purpose of this study was to evaluate the crash and the fatigue performance of a steering wheel skeleton fabricated by high pressure die casting. Two materials were used to produce two groups of wheels with identical geometry. The production part was designed, optimized and fabricated with AM50A magnesium. The production magnesium component met all of the regulatory design and performance requirements. A small sample run was made in a proprietary aluminum - magnesium alloy. The fatigue and crash properties were evaluated empirically. In fatigue testing, the aluminum skeletons displayed a significant improvement, with respect to the magnesium skeletons, in the number of cycles to failure at the loads tested.