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The impingement of liquid fuels on surfaces in IC engines affects performance and emissions. To better understand liquid/solid interactions, the impact of single droplets on a healed surface was experimentally examined. The droplet impingement was photographed with a high speed cine camera to obtain a history of the hydrodynamics of the impingement process. Images obtained from the cine photography were inspected to determine hydrodynamic regimes: wetting, transition, and non-wetting, associated with the specific impingement conditions (droplet size, velocity, surface temperature, and ambient pressure). Images from selected impingement conditions were further analyzed to quantify the atomization resulting from the impingement.