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The range of tasks in automotive electrical system development has clearly grown and now includes goals such as achieving efficiency requirements and complying with continuously reducing CO2 limits. Improvements in the vehicle electrical system, hereinafter referred to as the power net, are mandatory to face the challenges of increasing electrical energy consumption, new comfort and assistance functions, and further electrification. Novel power net topologies with dual batteries and dual voltages promise a significant increase in efficiency with moderate technological and financial effort. Depending on the vehicle segment, either an extension of established 12 V micro-hybrid technologies or 48 V mild hybridization is possible. Both technologies have the potential to reduce fuel consumption by implementing advanced stop/start and sailing functionalities.