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The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

Flow control by fluidic devices - without moving parts - offers advantages of reliability and low cost. As an example of their automobile application based on authors'' long-time experience the paper describes a fluidic valve for switching exhaust gas flow in a NOx absorber into a by-pass during regeneration phase. The unique feature here is the fluidic valve being of monostable and of axisymmetric design, integrated into the absorber body. After development in aerodynamic laboratory, the final design was tested on engine test stand and finally in a car. This proved that the performance under high temperature and pulsation existing in exhaust systems is reliable and promising. Fluidic valves require, however, close matching with aerodynamic load. To optimize the exhaust system layout for the whole load-speed range and reaching minimum counter- pressure, both the components of exhaust system and control strategy have to be properly adopted.

For the measurement of NO and NO2 the CLD-analyzer (chemiluminescense detector) has been used for more than twenty-five years. The disadvantage of the CLD is that NO can be measured only. To obtain total NOX (NO+NO2) the exhaust gas sample has to flow through a catalytic converter, which reduces NO2 to NO. The converter has a efficiency between 90 and 100%. For precise NO and NO2 values it is an advantage to analyze NO and NO2 directly. This paper describes a new UV NOX-analyzer for the simultaneous measurement of NO and NO2. Two different configurations, for high and low concentrations, eg. CVS-bag analysis are presented. The performance of the analyzers is documented in comparison to the UV-RAS analyzer with converter for NOX [1] and the conventional CLD-analyzer. The benefits of the new analyzer compared to analyzers equipped with a converter are given in detailed test results.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

More stringent emissions regulations, space limitations for catalytic converters in modern automotive applications, and new engine technologies constitute design challenges for today's engineers. In that context high cell density thinwall and ultrathinwall ceramic substrates have been designed into advanced catalytic converters. Whereas the majority of these substrates have a square cell geometry, a potential for further emissions improvement has been predicted for hexagonal cell structures. In order to verify these predictions, a ceramic substrate has been developed combining the features of high cell density, ultrathin cell walls, and hexagonal cell structure. Based on modeling data, the actual cell density and wall thickness of the hexagonal cell substrate will be defined. The performance of that substrate will be assessed by comparing experimental emissions results using two modern Volkswagen engines.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

This paper summarizes the validation of prototype vehicle-to-infrastructure (V2I) safety applications based on Dedicated Short Range Communications (DSRC) in the United States under a cooperative agreement between the Crash Avoidance Metrics Partners LLC (CAMP) and the Federal Highway Administration (FHWA). After consideration of a number of V2I safety applications, Red Light Violation Warning (RLVW), Curve Speed Warning (CSW) and Reduced Speed Zone Warning with Lane Closure Warning (RSZW/LC) were developed, validated and demonstrated using seven different vehicles (six passenger vehicles and one Class 8 truck) leveraging DSRC-based messages from a Road Side Unit (RSU). The developed V2I safety applications were validated for more than 20 distinct scenarios and over 100 test runs using both light- and heavy-duty vehicles over a period of seven months. Subsequently, additional on-road testing of CSW on public roads and RSZW/LC in live work zones were conducted in Southeast Michigan.

VOLKSWAGEN has conducted a number of investigations on a Multi Fuel Vehicle (MFV), designed for variable fuel operation, to determine the influence of fuel composition and clean fuels on exhaust emissions, mainly on ozone forming potential. Results of the tests indicate a small advantage of Phase II Reformulated Gasoline and a greater one for for methanol fuel M85, compared to today's gasoline. For M85 there is an about 25 % lower ozone forming potential. The most critical components in the exhaust of methanol fueled vehicles (M85) are unburned methanol and formaldehyde, forming more than 60 % of the total ozone forming potential. Therefore improvement of cold start and warmup driving during the first two to three minutes is of great importance, because in this time about 90 % of the mentioned components are formed.

A uniform flow distribution at converter inlet is one of the fundamental requirements to meet high catalytic efficiency. Commonly used tools for optimization of the inlet flow distribution are flow measurements as well as CFD analysis. This paper puts emphasis on the experimental procedures and results. The interaction of flow measurements and CFD is outlined. The exhaust gas flow is transient, compressible and hot, making in-situ flow measurements very complex. On the other hand, to utilize the advantages of flow testing at steady-state and cold conditions the significance of these results has to be verified first. CFD analysis under different boundary conditions prove that - in a first approach - the flow situation can be regarded as a sequence of successive, steady-state situations. Using the Reynolds analogy a formula for the steady-state, cold test mass flow is derived, taking into account the cylinder displacement and the rated speed.

Sulfur content in gasoline is known to reduce the efficiency of the catalytic converters that are used to reduce pollutants in the exhaust gas of cars. There is some concern that nitrous oxide emissions (N2O) increase when fuel with a high sulfur content is used. The engine out and tailpipe mass emissions of two cars conforming to the California LEV-standard were analyzed. The influence of the fuel sulfur content on the emissions of the regulated and some unregulated pollutants during FTP test cycles was determined. Four fuels covering the range from less than 1 to 330 ppm sulfur content were used. Over that range of fuel sulfur concentration the engine out emissions of sulfur dioxide (SO2 ) of both cars increased. Tailpipe emissions of SO2 were only found at fuel sulfur concentrations of 150 and 330 ppm. For both vehicles a correlation between the N2O emissions and the fuel sulfur content was found.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

The reduction of both harmful emissions (CO, HC, NOx, etc.) and gases responsible for greenhouse effects (especially CO2) are mandatory aspects to be considered in the development process of any kind of propulsion concept. Focusing on ICEs, the main development topics are today not only the reduction of harmful emissions, increase of thermodynamic efficiency, etc. but also the decarbonization of fuels which offers the highest potential for the reduction of CO2 emissions. Accordingly, the development of future ICEs will be closely linked to the development of CO2 neutral fuels (e.g. biofuels and e-fuels) as they will be part of a common development process. This implies an increase in development complexity, which needs the support of engine simulations. In this work, the virtual modeling of real fuel behavior is addressed to improve current simulation capabilities in studying how a specific composition can affect the engine performance.

Compatibility has been a research issue for many years now. It has gained more importance recently due to significant improvements in primary and secondary safety. Using a rigorous approach, combining accident research and theoretical scientific considerations, measures to improve vehicle-vehicle compatibility, with an emphasis on feasibility, were discussed. German accident research statistics showed that frontal impacts are of higher statistical significance than side impacts. Based on this and the high potential for improvement due high available deformation energy, the frontal impact configuration was identified as the most appropriate collision mode for addressing the compatibility issue. In side impacts, accident avoidance was identified as the most feasible and sensible measure. For frontal vehicle-vehicle impacts, both trucks and passenger cars were identified as opponents of high statistical significance.