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Heavy-duty diesel engines (HDDE), because of their widespread use and reputation of expelling excessive soot, have frequently been held responsible for excessive amounts of overall environmental particulate matter (PM). PM is a considerable contributor to air pollution, and a subject of primary concern to health and regulatory agencies worldwide. The U.S. Environmental Protection Agency (EPA) has provided PM emissions regulations and standards of measurement techniques since the 1980's. PM standards set forth by the EPA for HDDEs are based only on total mass, instead of size and/or concentration. The European Union adopted a particle number emission limit, and it may influence the U.S. EPA to adopt particle number or size limits in the future. The purpose of this research was to study the effects biodiesel blended fuel and cetane improvers have on particle size and number.

Diesel engines are highly reliable, durable and are used for a wide range of applications with low fuel usage owing to its higher thermal efficiency compared to other mobile power sources. Heavy-duty diesel engines are used for both on-road and off-road applications and dominate the heavy-duty engine segment of the United States transportation market. Due to their high reliability, there are considerable numbers of on-road legacy heavy-duty diesel engine fleets still in use in the United States. These engines are relatively higher oxides of nitrogen (NOx) and particulate matter (PM) producers than post 2007 model year diesel engines. There have been various emission certification or verification programs which are carried out in states like California and Texas for different aftermarket retrofit devices, fuels and additive technologies for reducing NOx and PM emissions from these legacy diesel engines.