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Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.

Growing concern over ground-level ozone and its role in smog formation has resulted in extensive investigation into identifying ozone sources. Motor vehicle exhaust, specifically oxides of nitrogen and hydrocarbons, have been identified as major ozone precursors in urban areas. Past research has concentrated on assessing the impact of emissions from gasoline fueled light duty vehicles. However, little work has been done on identifying ozone precursors from medium and heavy duty diesel fueled vehicles. This paper presents the results of testing performed on a Navistar T 444E 190 horsepower diesel engine which is certified as a light/heavy-duty emissions classification and is used in medium duty trucks up to 11,800 kg (26,000 lb) GVW. Regulated emissions and speciated hydrocarbon emissions were collected using a filter, bag and Tenax adsorption cartridges for both steady state and transient engine operation.