Speciation of Heavy Duty Diesel Exhaust Emissions under Steady State Operating Conditions
This paper presents results from a study on speciation of the emission profiles and on the ozone forming potential of heavy-duty diesel exhaust under steady state engine operation. Very limited attempts have been made at determining the ozone forming potential of heavy duty diesel exhaust emissions. In this study a proportional sample of the dilute exhaust was drawn from a CFV-CVS system using a temperature controlled sampling line. The particulate matter was collected on a 70 mm Teflon coated glass fiber filter (TX40HI20WW), the semi-volatiles on XAD-2 copolymer resin and volatiles in Tedlar bags. The samples were analyzed by gas chromatography after conditioning and chemical extractions. The initial phase of the study was directed towards developing techniques and establishing protocols to determine the ozone forming potential of heavy-duty diesel exhaust. A pre-chamber naturally aspirated engine was tested on steady-state modes 1, 3, 5, 7 and 8 of the ISO 8 mode cycle.