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The objective of this research project was to compare B20 (20% biodiesel fuel) and ultra-low-sulfur (ULSD) diesel-fueled buses in terms of fuel economy, vehicle maintenance, engine performance, component wear, and lube oil performance. We examined 15 model year (MY) 2002 Gillig 40-foot transit buses equipped with MY 2002 Cummins ISM engines. The engines met 2004 U.S. emission standards and employed exhaust gas recirculation (EGR). For 18 months, eight of these buses operated exclusively on B20 and seven operated exclusively on ULSD. The B20 and ULSD study groups operated from different depots of the St. Louis (Missouri) Metro, with bus routes matched for duty cycle parity. The B20- and ULSD-fueled buses exhibited comparable fuel economy, reliability (as measured by miles between road calls), and total maintenance costs. Engine and fuel system maintenance costs were also the same for the two groups after correcting for the higher average mileage of the B20 group.

Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300°C. These stored HCs inhibit or block NOx-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NOx conversion begins at between 100° and 200°C. When exposure to unburned fuel occurs at higher temperatures (250°-400°C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NOx conversion is inhibited until it is heated to 400°C.

A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.

This paper reports the development of new fuel ignition quality and combustion experiments performed using the Ignition Quality Tester (IQT). Prior SAE papers (961182, 971636, 1999-01-3591, and 2001-01-3527) documented the development of the IQT constant volume combustion chamber experimental apparatus to measure ignition qualities of diesel-type fuels. The ASTM International test method D6890 was developed around the IQT device to allow the rapid determination of derived cetane number (DCN). Interest in chemical kinetic models for the ignition of diesel and biodiesel model compounds is increasing to support the development of advanced engines and fuels. However, rigorous experimental validation of these kinetic models has been limited for a variety of reasons. Shock tubes and rapid compression machines are typically limited to premixed gas-phase studies, for example.

The combustion process in spark-ignition engines can vary considerably cycle by cycle, which may result in unstable engine operation. The phenomena amplify in natural gas (NG) spark-ignition (SI) engines due to the lower NG laminar flame speed compared to gasoline, and more so under lean burn conditions. The main goal of this study was to investigate the main sources and the characteristics of the cycle-by-cycle variation in heavy-duty compression ignition (CI) engines converted to NG SI operation. The experiments were conducted in a single-cylinder optically-accessible CI engine with a flat bowl-in piston that was converted to NG SI. The engine was operated at medium load under lean operating conditions, using pure methane as a natural gas surrogate. The CI to SI conversion was made through the addition of a low-pressure NG injector in the intake manifold and of a NG spark plug in place of the diesel injector.

National concerns over energy consumption and emissions from the transportation sector have prompted regulatory agencies to implement aggressive fuel economy targets for light-duty vehicles through the U.S. National Highway Traffic Safety Administration/Environmental Protection Agency (EPA) Corporate Average Fuel Economy (CAFE) program. Automotive manufacturers have responded by bringing competitive technologies to market that maximize efficiency while meeting or exceeding consumer performance and comfort expectations. In a collaborative effort among Toyota Motor Corporation, Argonne National Laboratory (ANL), and the National Renewable Energy Laboratory (NREL), the real-world savings of one such technology is evaluated. A commercially available Toyota Highlander equipped with two-phase cold storage technology was tested at ANL’s chassis dynamometer testing facility.

This study was aimed at experimentally investigating the impact of diesel/natural gas (NG) dual-fuel retrofitting onto gaseous emissions emitted by i) legacy, model year (MY) 2005 heavy-duty engines with cooled EGR and no after-treatment system, and ii) a latest technology engine equipped with DPF and urea-SCR after-treatment systems that is compliant with 2010 US-EPA emissions standards. In particular, two different dual-fuel conversion kits were evaluated in this study with pure methane (CH4) being used as surrogate for natural gas. Experiments were conducted on an engine dynamometer over a 13-mode steady-state test cycle as well as the transient FTP required for engine certification while gaseous emissions were sampled through a CVS system. Tailpipe NOx emissions were observed at a comparable level for diesel and diesel/CH4 dual-fuel operation for the 2010 compliant engine downstream the SCR.

Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.

The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.

The conversion of compression ignition (CI) internal combustion engines to spark-ignition (SI) operation by adding a spark plug to ignite the mixture and fumigating the fuel inside the intake manifold can increase the use of alternative gaseous fuels (e.g., natural gas) in heavy-duty applications. This study proposed a novel, less-complex methodology based on the inflection points in the apparent rate of heat release (ROHR) that can identify and separate the fast-burning stage inside the piston bowl from the slower combustion stage inside the squish region (a characteristic of premixed combustion inside a diesel geometry). A single-cylinder 2L CI research engine converted to natural gas SI operation provided the experimental data needed to evaluate the methodology, at several spark timings, equivalence ratios, and engine speeds.

Due to raising interest in diesel powered passenger cars in the U.S. in combination with a desire to reduce dependency on imported petroleum, there has been increased attention to the operation of diesel vehicles on fuels blended with biodiesel. One of several factors to be considered when operating a vehicle on biodiesel blends is understanding the impact and performance of the fuel on the emission control system. This paper documents the impact of the biodiesel blends on engine-out emissions as well as the overall system performance in terms of emission control system calibration and the overall system efficiency. The testing platform is a light-duty HSDI diesel engine with a Euro 4 base calibration in a 1700 kg sedan vehicle. It employs 2nd generation common-rail injection system with peak pressure of 1600 bar as well as cooled high-pressure EGR. The study includes 3 different fuels (U.S.

Raising interest in Diesel powered passenger cars in the United States in combination with the government mandated policy to reduce dependency of foreign oil, leads to the desire of operating Diesel vehicles with Biodiesel fuel blends. There is only limited information related to the impact of Biodiesel fuels on the performance of advanced emission control systems. In this project the implementation of a NOx storage and a SCR emission control system and the development for optimal performance are evaluated. The main focus remains on the discussion of the differences between the fuels which is done for the development as well as useful life aged components. From emission control standpoint only marginal effects could be observed as a result of the Biodiesel operation. The NOx storage catalyst results showed lower tailpipe emissions which were attributed to the lower exhaust temperature profile during the test cycle. The SCR catalyst tailpipe results were fuel neutral.

In-service 1994-2003 heavy-duty trucks were acquired by West Virginia University (WVU), equipped with the WVU Mobile Emissions Measurement System (MEMS) to measure on-road NOx, and driven on road routes near Sabraton, West Virginia, and extending up to Washington, PA to obtain real-world oxides of nitrogen (NOx) emissions data on highways and local roads. The MEMS measured 5Hz NOx, and load was obtained from the electronic control unit. Trucks were loaded to about 95% of their gross vehicle weights. Emissions in g/mi and g/bhp-hr were computed over the various road routes. In addition, some of the trucks were tested 1 to 2 years later to determine emission changes that may have occurred for these trucks. Emission results varied significantly over the different road routes due to different speeds, driving patterns, and road grades.

A work-based window method has been developed to calculate in-use brake-specific oxides of nitrogen (NOx) emissions for all engine speeds and engine loads. During an in-use test, engine speed and engine torque are read from the engine's electronic control unit, and along with time, are used to determine instantaneous engine power. Instantaneous work is calculated using this power and the time differential in the data collection. Work is then summed until the target amount of work is accumulated. The emissions levels are then calculated for that window of work. It was determined that a work window equal to the theoretical Federal Test Procedure (FTP) cycle work best provides a means of comparison to the FTP certification standard. Also, a failure criterion has been established based on the average amount of power generated in the work window and the amount of time required to achieve the target work window to determine if a particular work window is valid.

As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.

Pollutants are a major issue of diesel engines, with oxides of nitrogen (NOx) and airborne total particulate matter (TPM) of primary concern. Current emission standards rely on laboratory testing using an engine dynamometer with a standard test procedure. Results are reported as an integrated value for emissions from a transient set of engine speed and load conditions over a length of time or a set of prescribed speed-load points. To be considered a valid test by the US EPA, the measured engine speed and load are compared to the prescribed engine speed and load and must be within prescribed regression limits.

This paper discusses the design and qualification of a High Temperature Sampling System (HTSS), capable of stripping the volatile fraction from a sample flow stream in order to provide for quantification of total, solid and volatile particulate matter (PM) on a near real-time basis. The sampling system, which incorporates a heated diesel oxidation catalyst, is designed for temperatures up to 450°C. The design accounts for molecular diffusion of volatile compounds, solid particles diffusion and reaction kinetics inside one channel of the oxidation catalyst. An overall solid particle loss study in the sampling was performed, and numerical results were compared with experimental data gathered at the West Virginia University Engine and Emissions Research Laboratory (EERL) and West Virginia University's Transportable Heavy-Duty Vehicle Emissions Testing Laboratory (THDVETL).