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A combined experimental and computational study of 3-D unsteady compressible flow in exhaust manifold and CCC system was performed to understand the flow characteristics and to improve the flow distribution of pulsating exhaust gases within monolith. An experimental study was carried out to measure the velocity distribution in production exhaust manifold and CCC under engine operating conditions using LDV (Laser Doppler Velocimetry) system. Velocity characteristics were measured at planes 25 mm away from the front surface of first monolith and between two monolithic bricks. To provide boundary conditions for the computational study, velocity fields according to crank angle were also measured at the entrance of exhaust manifold. The comparisons of exhaust gas flow patterns in the junction and mixing pipe between experimental and computational results were made.

As the current and future emission regulations become stringent, the research on exhaust manifold with CCC (Close Coupled Catalyst) has been the interesting and remarkable subject. To design of exhaust manifold with CCC is a difficult task due to the complexity of the flow distribution caused by the pulsating flows that are emitted at the exhaust ports. This study is concerned with the theoretical and experimental approach to improve catalyst flow uniformity through the basic understanding of exhaust flow characteristics. Computational and experimental approach to the flow for exhaust manifold of conventional cast type, stainless steel bending type with 900 cell CCC system in a 4-cylinder gasoline engine was performed to investigate the flow distribution of exhaust gases.

Diesel engines are the most commonly used power plant of freight and public transportations in the world. Also, the newly developed injection system, Common Rail system, increases the demands for both light and heavy duty diesel vehicles. On the other hand, stringent emission regulations are being proposed with growing concern on NOx and PM emissions from diesel engines. Future emission regulations require advanced emission control technologies, such as EGR and SCR. Exhaust gas recirculation (EGR) is a commonly used technique to reduce NOx emission. In this paper, a model-based investigation was conducted to compare the effect of high pressure loop (HPL) EGR and low pressure loop (LPL) EGR system on NOx level and BSFC of a heavy-duty diesel engine. A WAVE model was created to simulate EURO 3 engine and each component of the engine was modeled using CATIA and WaveMesher.

Today's diesel PM reduction systems are mainly based on catalyzed particulate filter(CPF) systems. However, most of their reaction kinetics remain unresolved. Among others, the soot oxidation rate over catalyst is particularly important in the evaluation of the performance of the catalysts and the efficient control of CPF regeneration. This study, therefore, investigated the oxidation rate of carbon black (Printex-U) over various Pt supported catalysts using a flow reactor setup simulating diesel exhaust conditions. Compared to non-catalyzed soot oxidation, the oxidation rate of carbon black over Pt catalysts was to an extent shifted towards low temperatures. This activity enhancement of soot oxidation over a catalyst can be attributed principally to NO to NO2 conversion because NO2 oxidizes soot with much lower activation energy (Ea=60kJ/mol) than O2 (Ea=177kJ/mol).

The oxidation of soot (carbon black) which is assisted by Pt/CeO2 catalyst is studied using a flow reactor system simulating the condition of diesel exhaust. In this study, the temperature programmed oxidation (TPO) scheme is mainly used for different NO and O2 concentrations and soot oxidation rate is evaluated by monitoring both CO and CO2 concentrations. Pt/CeO2 catalyst lowers the temperature of the peak CO/CO2 concentrations significantly when there is either NO or O2. Oxidation starts at 200°C and the peak CO2 concentration is observed at 360°C, which depends on the amount of catalyst and NO concentration. The effect of catalyst on NO2 recycling is also investigated. For this purpose, two different types of sample have been prepared. For the mixed case, 10mg of carbon black is mixed with 50mg of Pt/CeO2 catalyst under conditions of loose contact. For the unmixed case, the catalyst layer is placed on top of soot layer without mixing.

Plasma-catalyst (Ag, Au/Al2O3) systems were applied to NOx reduction in a model lean-burn engine exhaust gas. Also, DeNOx test of real diesel exhaust gas was performed by plasma-Ag/Al2O3 system. In the case of model exhaust gas, the catalytic activity for NOx reduction was enhanced by the assistance of plasma in the wide temperature range. The NOx conversion efficiency of plasma-Ag/Al2O3 was 40∼90% under the condition of C3 H6 3200ppm (C1/NOx = 5.96) and 10% O2 over the temperature range of 250∼400°C. The plasma-Au/Al2 O3 system showed remarkable low temperature NOx reduction activity at 100∼250°C. The real engine full flow test was performed for 70% of the full load and at engine speed of 1500rpm. NOx removal of 46% from the diesel exhaust gas was achieved by the plasma-Ag/Al2O3 catalyst system at 364°C(C1/NOx = 6). In the case of higher C1/NOx = 10, the NOx conversion increased up to 73% at 381°C. Also, DeNOx engine tests were performed for full load of 1500, 2000 and 2500rpm.

Among the recent research ideas to reduce hydrocarbon emissions emitted from SI engines till light-off of catalyst since cold start are those exploiting non-thermal plasma technique and photo-catalyst that draws recent attention by virtue of its successful application to practical use to clean up the atmosphere using the feature of its relative independence on temperature. Based on the previous research results [6] obtained with model exhaust gases using an experimental emissions reduction system that utilizes the non-thermal plasma and photo-catalyst technique, further investigation was conducted on a production N/A 1.5 liter DOHC gasoline engine during cold start to warm-up. For the effects of non-thermal plasma-photocatalyst combined reactor, 10% concentration reduction was achieved with the fuel component paraffins, and the large increase in non-fuel paraffinic components and acetylene concentrations were similar to those of base condition.

Diesel engines are the most commonly used power train of the freight and public transportations in the world. From the viewpoint of global warming restraint, however, reduction of exhaust emissions from the diesel engine is urgent demand. Stringent emission regulations are being proposed with growing concern on NOx, PM and CO2 emissions. Future emission regulations require advanced emission control technologies, such as SCR(Selective Catalytic Reduction), LNT(Lean NOx Trap) and EGR(Exhaust Gas Recirculation). The EGR is a commonly used technique to reduce emission. In this study, a LP-EGR(Low Pressure Exhaust Gas Recirculation) system was investigated to evaluate its potential on emission reduction and fuel economy improvement, especially for a passenger diesel engine. A 3.0ℓ diesel engine equipped with the LP-EGR system was tested using an in-house control algorithm.

As environmental problems such as global warming are emerging, regulations on automobile exhaust gas are strengthened and various exhaust gas reduction technologies are being developed in various countries in order to satisfy exhaust emission regulations. Exhaust gas recirculation (EGR) technology is a very effective way to reduce nitrogen oxides (NOx) at high combustion temperatures by using EGR coolers to lower the combustion temperature. This EGR cooler has been mass-produced in stainless steel, but it is expensive and heavy. Recently, high efficiency and compactness are required for the EGR cooler to meet the new emission regulation. If aluminum material is applied to the EGR cooler, heat transfer efficiency and light weight can be improved due to high heat transfer coefficient of aluminum compared to conventional stainless steel, but durability is insufficient. Therefore, the aluminum EGR cooler has been developed to enhance performance and durability.

High specific power, additional hardware and mapping optimization was done to achieve reduction of fuel economy for current engine in this study. 2 stage turbocharger with serial configuration was best candidate not only for high specific power at high engine speed but also for increase of low end torque for current engine. This increase of low end torque is important for development of transient characteristic of vehicle. DoE and efficient EGR Cooler was applied for optimization of fuel economy. DoE was useful for optimization of fuel consumption affected by various fuel injection parameters. This DoE was also efficient for matching optimal fuel economy after change of engine hardware. Performance improvement of engine with 2 stage turbocharger VGT was evaluated and additional development of fuel economy was performed in this study.

We developed new single coated Pd/Rh three-way catalysts (TWC). Several Pd/Rh single layered catalysts were prepared by changing the precious metal (PM) fixation method and adding new base metal oxides (BMO). These samples were compared with double-coated catalyst by using model gas activity test, BET test, XRD test and vehicle emission test. It is found that the performance of the single coated catalyst is as good as that of commercialized double-coated catalyst. The oxygen storage capacity of the single coated catalyst is better than that of double-coated catalyst. Moreover, manufacturing the single coated catalyst enables us to eliminate the unnecessary coating process which is essential to the conventional one. Our test results demonstrate that the developed catalyst has sufficient activity and durability of OSC to meet emission and OBD-II regulations.

As the markets require a more environmentally friendly and high fuel consumption vehicle, we have to satisfy bilateral target. Though many new after-treatment techniques like LNT, SCR are investigated to meet both strong emission regulations and low fuel consumption, high cost of these techniques should be solved to adopt widely. This paper describes how to optimize the dual loop EGR as a tool to reduce CO₂ emission of a HSDI diesel engine in the passenger car application. Focus is not only on the optimization to obtain the maximum CO₂ reduction but also on how to assess and overcome various side effects. As a result of careful optimization, as much as 6% CO₂ reduction was achieved by introduction of low pressure EGR loop, maintaining the same boundary conditions as those with high pressure EGR loop only.

A study of unsteady compressible flow for two types of exhaust manifold and CCC (Close-Coupled Catalyst) systems attached to a 4-cylinder DOHC gasoline engine was carried out to investigate the flow distribution of exhaust gases and finally to make the conversion efficiency of catalyst better. An experimental study was conducted, using LDV technique, to measure the velocity distributions inside exhaust manifolds and CCC under practical engine conditions. In this study, through experiment and calculation, the effects of geometric configuration of exhaust manifold on flow maldistribution in monolith were mainly investigated to understand the exhaust flow structure in terms of flow uniformity and to improve the conversion efficiency. As a result of this fundamental study, the modified exhaust manifold (Type B) was designed and manufactured. Full load performance tests and vehicle emission tests were performed to see the effects of flow characteristics on engine performance and emission.

Improved Lean NOx Trap (LNT) catalysts with enhanced NH3 generation feature were developed for the small diesel engine. The next generation LNT system needs to perform good NOx conversions over the wide temperature range including below 200°C for urban driving and above 400°C for motorway of real road driving. However, the extended use of BaO, a component of LNT known to be very effective for high temperature NOx storage, results in the decrease of low temperature NOx conversion due to the degradation of NO oxidation associating with sulfur over time. The improvement of the low-temperature LNT performance is a key requirement for the real driving emission control as the best operation temperature for urea-SCR is above ~250°C. In this study, our next generation LNT with new washcoat architecture has demonstrated improved NOx removal efficiencies under the wider operation temperature window than the current production technology.

Recently, the design of automotive headlamps has become diversified and complicated according to customer needs. Hence, structural complexity of the headlamps has also increased. Complex structure of the headlamps inevitably causes a disturbance in air circulation. For this reason, inadvertent micro-sized water droplets, called fogging, are condensed on the inner surface of headlamp lens due to temperature difference between the inner and outer lens surfaces. To circumvent fogging inside of the headlamp lens, an anti-fogging coating is indispensable. Conventionally, diverse surfactants have been adopted as substantial material for the anti-fogging coating. However, the usage of the surfactants causes undesirable side effect such as water mark arising from vapor condensation, which is an important issue that must be fully resolved. In this study, we developed an innovative anti-fogging coating material without using conventional surfactant.

The integration of SCR catalyst into diesel-particulate filter (SDPF) may be one of most viable ways to meet upcoming stringent emission regulations with new test protocols such as Worldwide harmonized Light vehicles Test Cycles (WLTC) and Real Driving Emissions (RDE) requirements. The chabazite-structured SSZ-13-based catalysts enabled the wide implementation of urea-SCR technology for mobile applications due to their robust thermal stability up to 750°C compared to the thermally unstable ZSM-5-based technologies. However, the thermally stable Cu-SSZ-13 catalyst starts losing its initial activity with the increase of aging time at 850°C, where the SCR catalyst on SDPF can possibly be exposed during filter regeneration under a drop-to-idle (DTI) condition. Therefore, more durable SCR catalysts that survive under higher temperatures have been strongly desired in automotive industry. Recently, we found Cu-exchanged high silica LTA revealed an excellent hydrothermal stability.

The worldwide fuel economy compliance level has been tightening, at the same time, LEV-III/Euro-6d/China-6/BS-6 regulations for NMOG and NOx emissions are being introduced or already effective. Therefore, intensive research effort has been conducted in order to improve the fuel efficiency of passenger cars and reduce exhaust emission. In response to these demands, turbocharged gasoline direct injection (TGDI) engine is being introduced for gasoline vehicles in consideration of fuel efficiency improvement, high output and driving performance compared to naturally aspirated (NA) engine. However, due to its larger thermal mass from the turbo hardware in the exhaust, it suffers from the cold-start emission. The main hazardous gases emitted from gasoline vehicles are CO, HC and NOx, and a three-way catalyst (TWC) is installed for the purification of these harmful emissions.

Generally, vehicles do not need power during deceleration. Therefore, the fuel efficiency can be improved by stopping the fuel injection in this period. However, when the fuel cut is activated, NOx is emitted immediately after fuel cut. During the fuel cut period, a large amount of fresh air flows into the catalytic converter installed on a vehicle since there is no combustion. Thus, the catalytic materials are converted into an oxidizing atmosphere. As a result, NOx purification performance of the catalyst deteriorates, and eventually NOx is emitted when combustion restarts. The quantity of NOx in this period is relatively small. However, in case of increasing fuel cuts, emission problem could arise. Therefore, in order to meet the stringent regulation such as LEV III-SULEV20 or 30, the number of fuel cuts need to be limited. The problem is that this strategy leads to a disadvantage of fuel efficiency.

The maximum thermal efficiency of gasoline engine has been improving and recently the maximum of 40% has been achieved. In this study, the potential of further improvement on engine thermal efficiency over 40% was investigated. The effects of engine parameters on the engine thermal efficiency were evaluated while the optimization of parameters was implemented. Parameters tested in this study were compression ratio, tumble ratio, twin spark configuration, EGR rate, In/Ex cam shaft duration and component friction. Effects of each parameter on fuel consumption reduction were discussed with experimental results. For the engine optimization, compression ratio was found to be 14, at which the best BSFC without knock and combustion phasing retardation near sweet spot area was showed. Highly diluted combustion was applied with high EGR rate up to 35% for the knock mitigation.