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Technical Paper

Diffusion Limited Supercritical Water Oxidation (SCWO) in Microgravity Environments

2006-07-17
2006-01-2132
Tests designed to quantify the gravitational effects on thermal mixing and reactant injection in a Supercritical Water Oxidation (SCWO) reactor have recently been performed in the Zero Gravity Facility (ZGF) at NASA's Glenn Research Center. An artificial waste stream, comprising aqueous mixtures of methanol, was pressurized to approximately 250 atm and then heated to 450°C. After uniform temperatures in the reactor were verified, a controlled injection of air was initiated through a specially designed injector to simulate diffusion limited reactions typical in most continuous flow reactors. Results from a thermal mapping of the reaction zone in both 1-g and 0-g environments are compared. Additionally, results of a numerical model of the test configuration are presented to illustrate first order effects on reactant mixing and thermal transport in the absence of gravity.
Technical Paper

Gravity Effects on Premixed and Diffusion Limited Supercritical Water Oxidation

2005-07-11
2005-01-3036
Supercritical water oxidation (SCWO) may become an attractive technology for processing solid and liquid wastes for long duration space and extraterrestrial planetary missions. Gravitational influences on the operation of SCWO reactors are discussed in the context of key dimensionless parameters for two general modes of operation: a “premixed” mode, where the reactants are brought to supercritical temperatures and pressures simultaneously, and a “diffusion limited” mode, where one of the reactants (typically the oxidizer) is injected into the reactor after the bulk fluid is raised to supercritical temperatures and pressures. An experimental facility for testing the gravitational influences on a SCWO reactor is then discussed.
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