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The Detroit Diesel 6V-92TA engine has been redesigned to run on alcohol fuels to meet 1991 urban bus emission standards. A prototype engine was tested over the EPA transient procedure, using mixtures of methanol, ethanol (with and without water), gasoline, and ignition enhancer. Regulated and selected unregulated emissions were measured. Organic material hydrocarbon equivalent (OMHCE) emissions were significantly above the hydrocarbon emission standard; however, emissions of CO and NO, were below the 1991 emission standards for the fuel combinations used. Particulate emissions were close to the 1991 urban bus emission standard for some configurations. The method used for calculating OMHCE emissions when ethanol was used is also given.

Recent legislation including the California Clean Air Act of 1988 and the Federal Clean Air Act Amendment of 1990 will regulate exhaust emissions from small utility, lawn, and garden equipment engines. In an attempt to gain as much understanding as possible in a short time, SwRI has conducted a series of tests to investigate the effectiveness of late 1960's automotive emission reduction technology on small engines. Experiments were conducted utilizing air injection into the exhaust, exhaust gas recirculation (EGR), and ignition timing changes. The test engine was a 4 stroke generator set engine rated 5.88 Kw at 3600 rpm. Results show these technologies to be very effective in reducing hydrocarbons (HC), oxides of nitrogen (NOx), and carbon monoxide (C0).

This paper covers work performed for the California Air Resources Board and US Environmental Protection Agency by Southwest Research Institute. Emission measurements were made on four in-use off-road two-stroke motorcycles and all-terrain vehicles utilizing oxygenated and non-oxygenated fuels. Emission data was produced to augment ARB and EPA's off-road emission inventory. It was intended that this program provide ARB and EPA with emission test results they require for atmospheric modeling. The paper describes the equipment and engines tested, test procedures, emissions sampling methodologies, and emissions analytical techniques. Fuels used in the study are described, along with the emissions characterization results. The fuel effects on exhaust emissions and operation due to ethanol content and fuel components is compared.

This paper covers work performed for the California Air Resources Board and the United States Environmental Protection Agency by Southwest Research Institute. Emission measurements were made on nine types of off-road equipment with small (<19kW) spark-ignited engines including handheld and non-handheld equipment utilizing oxygenated and non-oxygenated fuels. Emission data was produced to augment ARB and EPA's off-road emission inventory. It was intended that this program provide ARB and EPA with emission test results they require for atmospheric modeling. The paper describes the equipment and engines tested, test procedures, emissions sampling methodologies, and emissions analytical techniques. Fuels used in the study are described, along with the emissions characterization results. The fuel effects on exhaust emissions and operation due to ethanol content and fuel components is compared.

Measurement of emissions from small utility engines has usually been accomplished using steady-state raw emissions procedures such as SAE Recommended Practice J1088. While raw exhaust measurements have the advantage of producing modal exhaust gas concentration data for design feedback; they are laborious, may influence both engine performance and the emissions themselves, and have no provision for concurrent particulate measurements. It is time to consider a full-dilution procedure similar in principle to automotive and heavy-duty on-highway emission measurement practice, leading to improvements in many of the areas noted above, and generally to much higher confidence in data obtained. When certification and audit of small engine emissions become a reality, a brief dilute exhaust procedure generating only the necessary data will be a tremendous advantage to both manufacturers and regulatory agencies.

The U.S. EPA and the California Air Resources Board have adopted standards to reduce emissions from recreational marine vessels. Existing regulations focus on reducing hydrocarbons. There are no regulations on particulate emissions; particulate is expected to be reduced as a side benefit of hydrocarbon control. The goal of this study was to develop a sampling methodology to measure particulate emissions from marine outboard and personal watercraft engines. Eight marine engines of various engine technologies and power output were tested. Emissions measured in this program included hydrocarbons, carbon monoxide, oxides of nitrogen. Particulate emissions will be presented in a follow-up paper.

Natural gas-fueled vehicles impose unique requirements on exhaust aftertreatment systems. Methane conversion, which is very difficult for conventional automotive catalysts, may be required, depending on future regulatory directions. Three-way converter operating windows for simultaneous conversion of HC, CO, and NOx are considerably more narrow with gas engine exhaust. While several studies have demonstrated acceptable fresh converter performance, aged performance remains a concern. This paper presents the results of a durability study of eight catalytic converters specifically developed for natural gas engines. The converters were aged for 300 hours on a natural gas-fueled 7.0L Chevrolet engine operated at net stoichiometry. Catalyst performance was evaluated using both air/fuel traverse engine tests and FTP vehicle tests. Durability cycle severity and a comparison of results for engine and vehicle tests are discussed.

Several properties of a refinery “straightrun kerosene“, which had a narrow boiling range approximating the middle of a No. 1 diesel fuel, were altered to study their effects on regulated and unregulated exhaust emissions. Eleven fuel blends, representing changes in nitrogen content, aromatic level, boiling point distribution, olefin content, and cetane number, were evaluated in a 1975 Mercedes-Benz 240D. Statistical analysis, including regression, was performed using selected fuel properties as independent variables. Higher aromatic levels were generally associated with increased emissions, while increased olefin levels were generally associated with decreased emissions.

In an attempt to characterize emissions from small air-cooled utility engines, five gasoline-fueled models were operated over a variety of speeds and loads, and important exhaust constituents were measured. These emissions included hydrocarbons, CO, CO2, NO, O2, aldehydes, light hydrocarbons, particulates, and smoke. Emissions of SOx were estimated on the basis of the fuel consumed; evaporative losses of hydrocarbons were also estimated. The impact of small engine emissions was calculated on the basis of the test results and information on national engine populations and usage. From these data, it appears that the 50 million or more small engines currently being used account for only a small part of pollutants from all sources.

The research program on which this paper is based included both laboratory emission measurements and extrapolation of results to the national population of heavy-duty farm, construction, and industrial engines. Emission tests were made on four gasoline engines and eight diesel engines typical of those used in F, C, and I equipment. Gaseous and particulate emissions were measured during engine operation on well-accepted steady-state procedures, and diesel smoke was measured during both steady-state conditions and the Federal smoke test cycle. Emissions measured were hydrocarbons, CO, CO2, NO, NOx, O2, aliphatic aldehydes, light hydrocarbons, particulate, and smoke. Emission of sulfur oxides (SOx) was estimated on the basis of fuel consumed, and both evaporative and blowby hydrocarbons were also estimated where applicable (gasoline engines only). Data on emissions obtained from this study were compared with those available in the literature, where possible.

This paper describes the results of a public opinion survey on testing of diesel exhaust odors conducted during 1969 and 1970. Major goals of the research were to relate public opinion of the odors and the objectionability associated with them to odor intensity, and to obtain a dose-response curve as the primary result. The dose-response curve was needed to assess odor-control technology by providing a criterion for deciding whether or not the effect of a given control item would be noticed by the general public, reduce complaints, or be worth the cost and effort required for its implementation. The engine used as the live odor source for the subject research was a two-stroke cycle type similar to those used in many buses. This engine type was chosen because its exposure to the public in urban bus applications is very widespread, and because a large portion of the Environmental Protection Agency's odor research had been performed with similar engines.

Seven motorcycles, ranging in size from 100 to 1200 cm3, were tested for emissions characterization purposes. They were operated on the federal seven-mode test procedure (for 1971 and older light-duty vehicles), the federal LA-4 test procedure (for 1972 and later LDVs), and under a variety of steady-state conditions. Four of the machines tested had 4-stroke engines, and the other three had 2-stroke engines. Emissions which were measured included hydrocarbons, CO, CO2, NO, NOx, O2, aldehydes, light hydrocarbons, particulates, and smoke. Emissions of SOx were estimated on the basis of fuel consumed, and evaporative hydrocarbon losses were also estimated. Crankcase “blowby” emissions from one 4-stroke machine were measured. The impact of motorcycles on national pollutant totals was estimated, based on the test results and information from a variety of sources on national population and usage of motorcycles.

This paper describes a research program on exhaust emissions from snowmobile engines, including both emissions characterization and estimation of national emissions impact. Tests were conducted on three popular 2-stroke twins and on one rotary (Wankel) engine. Emissions that were measured included total hydrocarbons, (paraffinic) hydrocarbons by NDIR, CO, CO2, NO (by two methods), NOx, O2, aldehydes, light hydrocarbons, particulate, and smoke. Emissions of SOx were estimated on the basis of fuel consumed, and evaporative hydrocarbons were projected to be negligible for actual snowmobile operation. During emissions tests, intake air temperature was controlled to approximately -7°C (20°F), and room air at approximately 24°C (75°F) was used for engine cooling. Based on test results and the best snowmobile population and usage data available, impact of snowmobile emissions on a national scale was computed to be minimal.

To characterize exhaust emissions from water-cooled 2-stroke outboard motors (the predominant type), four new motors were tested on dynamometer stands. The engines ranged from 4-65 hp in size, and operating conditions were chosen along lines of simulated boat loading. All the measurements were taken at steady-state conditions. Emission concentrations were measured in raw exhaust gas and after the gases had been bubbled through water in a specially constructed tank. Constituents measured included hydrocarbons, CO, CO2, NO, NOx, O2, light hydrocarbons, and aldehydes. Emissions of sulfur oxides (SOx) were estimated on the basis of fuel consumed, and all the exhaust emissions data were used with available information on population and usage of motors to estimate exhaust emission factors and national exhaust emissions impact.

Particulate and gaseous emissions from two light-duty diesel vehicles were measured over eight operating schedules, using five different fuels. Characterization included regulated exhaust emissions and a number of unregulated constituents. Non-routine gas measurements included phenols, hydrocarbon boiling range, and aldehydes. Particulate characterization included mass rates and concentrations, visible smoke, aerodynamic sizing, total organics, BaP, sulfate, phenols, trace elements, and major elements. Statistical analysis of emissions data was undertaken using fuel properties and operating schedule statistics as independent variables. Regressions were computed for a few variables, and analysis of variance and multiple comparisons were used where the data were not suitable for regression analysis.

Gaseous and particulate emissions from two heavy-duty diesel engines were characterized while the engines were operated on five different fuels. Characterization included mass rates of major exhaust products, plus analysis of particulate matter for sulfate, trace elements, major elements, total solubles, and other properties. Analysis of rate and composition data was conducted with regard to fuel and engine effects on particulate. Two large particulate samples were also collected for later analysis on groups of organics present.

Emissions from two heavy-duty four stroke direct injection engines designed to use methanol fuel, one using Diesel pilot fuel injection and the other using spark ignition, were characterized in this program along with those from a comparably-sized Diesel engine. Emissions evaluated during both steady-state and transient FTP procedures included regulated gases (HC, CO, and NOx), unburned methanol, aldehydes, other gaseous organics, total particulate, sulfate, soluble organics in particulate and BaP. The engines adapted for methanol fuel and using catalysts emitted less HC, CO, particulate, soluble organics, and BaP than the Diesel fueled engine.

Emissions from a modern heavy-duty Diesel truck engine were characterized with five different fuels during transient and steady-state operation. A control fuel (Phillips D-2) was used for baseline emissions, and as base stock in three alternate fuel blends containing EDS or SRC-II middle distillates, or used lubricating oil. The fifth fuel tested was neat soybean oil, heated to 145°C. HC, CO, NOX, and particulate emissions were similar for this engine on all fuels tested, with the exception of higher particulates for the soybean oil and higher NOX for the SRC-II blend.

Exhaust emission data from several fuel effects studies were normalized and subjected to statistical analyses. The goal of this work was to determine whether emission effects of property variation in alternate-source fuels were similar, less pronounced, or more pronounced than the effects of property variation in petroleum fuels. A literature search was conducted, reviewing hundreds of studies and finally selecting nine which dealt with fuel property effects on emissions. From these studies, 15 test cases were reported. Due to the wide variety of vehicles, fuels, test cycles, and measurement techniques used in the studies, a method to relate them all in terms of general trends was developed. Statistics and methods used included bivariate correlation coefficients, regression analysis, scattergrams and goodness-of-fit determinations.

Diesel soot or smoke has been regarded as a nuisance pollutant and potential health hazard, especially in congested urban areas where diesel buses operate. Exhaust emissions from a DDAD 6V-71 coach engine and a similarly-powered 1980 GMC RTS-II coach, fitted with a non-catalyzed particulate trap, were characterized over various Federal Test Procedures for heavy-duty engines, including an experimental test cycle for buses. Regeneration was accomplished using an in-line burner in the exhaust to raise the engines' idle exhaust gas temperature from 120 to 700°C. Trap testing included approximately 15 hours of engine operation and 100 miles of bus operation. Particulate emissions were reduced by an average of 79 percent and smoke emissions were nil using the trap. The effect of the trap on regulated and other unregulated emissions was generally minimal.