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Selective catalytic reduction (SCR) of NOx is coming into worldwide use for automotive diesel emissions control. To meet the most stringent standards, NOx conversion efficiency must exceed 80% while NH3 emissions or slip must be kept below 10-30 ppm. At such high levels of performance, non-uniformities in ammonia-to-NOx ratio (ANR) at the converter inlet can limit the achievable NOx reduction. Despite its significance, this effect is frequently ignored in 1D catalyst models. The corresponding model error is important to system integration engineers because it affects system sizing, and to control engineers because it affects both steady-state and dynamic SCR converter performance. A probability distribution function (PDF) based method is introduced to include mixture non-uniformity in a 1D, real-time catalyst model.

With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.

Hydrogen fuel is a future energy to solve the problems of energy crisis and environmental pollution. Hydrogen internal combustion engines can combine the advantage of hydrogen without carbon pollution and the main basic structure of the traditional engines. However, the power of the port fuel injection hydrogen engines is smaller than the same volume gasoline engine because the hydrogen occupies the volume of the cylinder and reduces the air mass flow. The turbocharger can increase the power of hydrogen engines but also increase the NOx emission. Hence, a comprehensive controlling strategy to solve the contradiction of the power, BTE and NOx emission is important to improve the performance of hydrogen engines. This paper shows the controlling strategy for a four-stroke, 2.3L hydrogen engine with a turbocharger. The controlling strategy divides the operating conditions of the hydrogen engine into six parts according to the engine speeds and loads.

Recently, with the increasing interest on some potential alternative substitutes of petroleum fuels such as biodiesel and butanol, more and more researches are focused on the field of bio-fuels because they are renewable and friendly to the environment and can possibly reduce domestic demand on foreign petroleum. Bio-fuels are generally used in the commercial market by mixing with petroleum-based diesel or gasoline. Since the volatilities and boiling points of ethanol/butanol and diesel/biodiesel fuels are significantly different, micro-explosion can be expected in the blend mixture. In this study, a numerical model of micro-explosion including bubble generation, bubble expansion, and final breakup for multi-component bio-fuel droplets is proposed. From the simulated results of droplet characteristics at the onset of micro-explosion, it is concluded that micro-explosion is possible under engine operation condition for ethanol/butanol-diesel/biodiesel fuel blends.

The combustion and emission characteristics of a diesel engine running on butanol-diesel blends were investigated in this study. The blending ratio of n-butanol to diesel was varied from 0 to 40 vol% using an increment of 10 vol%, and each blend was tested on a 2.7 L V6 common rail direction injection diesel engine equipped with an EGR system. The test was carried out under two engine loads at a constant engine speed, using various combinations of EGR ratios and injection timings. Test results indicate that n-butanol addition to engine fuel is able to substantially decrease soot emission from raw exhaust gas, while the change in NOx emissions varies depending on the n-butanol content and engine operating conditions. Increasing EGR ratio and retarding injection timing are effective approaches to reduce NOx emissions from combustion of n-butanol-diesel blends.

An optically accessible single-cylinder high-speed direct-injection (HSDI) diesel engine equipped with a Bosch common rail injection system was used to study effects of injection pressures on the in-cylinder spray and combustion processes. An injector with an injection angle of 70 degrees and European low sulfur diesel fuel (cetane number 54) were used in the work. The operating load was 2.0 bar IMEP with no EGR added in the intake. The in-cylinder pressure was measured and the heat release rate was calculated. High-speed Mie-scattering technique was employed to visualize the liquid distribution and evolution. High-speed combustion video was also captured for all the studied cases using the same frame rate. NOx emissions were measured in the exhaust pipe. The experimental results indicated that for all of the conditions the heat release rate was dominated by a premixed combustion pattern. Two-stage low temperature reaction was seen for early injection timings.

A single nozzle port fuel injector was modified to apply electrostatic charge to the fuel stream, with the intention of studying electrostatically assisted sprays in a practical, port-injected engine. The modifications were kept external to the injector and involved placing an electrode and insulating liner over the tip of the injector. The performance of the modified injector, which combined pressure driven and electrostatic atomization, was characterized in three phases: the injector sprays themselves were studied, combustion of charged fuel droplets was studied, and the injector was installed and tested on a single cylinder spark ignition engine. In the first phase, Fraunhofer diffraction measurements of droplet size, and particle image velocimetry measurements of droplet velocity were performed. The charge transferred by the sprays was measured using an electrometer, and typical forces exerted on droplets in the sprays were estimated.

HCCI/PCCI combustion concepts have been demonstrated for both high brake thermal efficiency and low engine-out emissions. However, these advanced combustion concepts still could not be fully utilized partially due to the limitations of conventional fixed spray angle nozzle designs for issues related to wall wetting for early injections. The micro-variable circular orifice (MVCO) fuel injector provides variable spray angles, variable orifice areas, and variable spray patterns. The MVCO provides optimized spray patterns to minimize combustion chamber surface-wetting, oil dilution and emissions. Designed with a concise structure, MVCO can significantly extend the operation maps of high efficiency early HCCI/PCCI combustion, and enable optimization of a dual-mode HCCI/PCCI and Accelerated Diffusion Combustion (ADC) over full engine operating maps. The MVCO variable spray pattern characteristics are analyzed with high speed photographing.

Dual-fuel combustion combining a premixed charge of compressed natural gas (CNG) and a pilot injection of diesel fuel offer the potential to reduce diesel fuel consumption and drastically reduce soot emissions. In this study, dual-fuel combustion using methane ignited with a pilot injection of No. 2 diesel fuel, was studied in a single cylinder diesel engine with optical access. Experiments were performed at a CNG substitution rate of 70% CNG (based on energy) over a wide range of equivalence ratios of the premixed charge, as well as different diesel injection strategies (single and double injection). A color high-speed camera was used in order to identify and distinguish between lean-premixed methane combustion and diffusion combustion in dual-fuel combustion. The effect of multiple diesel injections is also investigated optically as a means to enhance flame propagation towards the center of the combustion chamber.

A new approach of NOx reduction in the compression-ignition engine is introduced in this work. The previous research has shown that during the combustion stage, the high temperature ignition tends to occur early at the near-stoichiometric region where the combustion temperature is high and majority of NOx is formed; Therefore, it is desirable to burn the leaner region first and then the near-stoichiometric region, which inhibits the temperature rise of the near-stoichiometric region and consequently suppresses the formation of NOx. Such inverted ignition sequence requires mixture with inverted phi-sensitivity. Fuel selection is performed based on the criteria of strong ignition T-sensitivity, negligible negative temperature coefficient (NTC) behavior, and large heat of vaporization (HoV).

Methanol has been regarded as a potential transportation fuel due to its advanced combustion characteristics and flexible source. However, it is suffering from misfire and high HC emissions problems under cold start and low load conditions either on methanol SI engine or on methanol/diesel dual fuel engine. Hydrogen is a potential addition that can enhance the combustion of methanol due to its high flammability and combustion stability. In the current work, the effect of hydrogen fraction on the laminar flame characteristics of methanol- hydrogen-air mixture under varied equivalence ratio was investigated on a constant volume combustion chamber system coupled with a schlieren setup. Experiments were performed over a wide range of equivalence ratio of the premixed charge, varied from 0.8 to 1.4, as well as different hydrogen fraction, 0%, 5%, 10%, 15% and 20% (n/n). All tests were carried out at fixed temperature and pressure of 400K and 0.1MPa.

CNG-diesel dual fuel combustion mode has been regarded as a practical operation strategy because it not only can remain high thermal efficiency but also make full use of an alternative fuel, natural gas. However, it is suffering from misfire and high HC emissions under cold start and low load conditions. As known, hydrogen has high flammability. Thus, a certain proportion of hydrogen can be added in the natural gas (named HCNG) to improve combustion performance. In this work, the effect of hydrogen volume ratio on combustion characteristics was investigated on an optically accessible single-cylinder CNG-diesel engine using a Phantom v7.3 color camera. HCNG was compressed into the tank under different hydrogen volume ratios varied from 0% to 30%, while the energy substitution rate of` HCNG remained at 70%.

Droplets impacting onto the heated surface is a typical phenomenon either in CI engines or in GDI SI engines, which is regarded significant for their air-fuel mixing. Meanwhile, alcohols including ethanol and butanol, has been widely studied as internal combustion engine alternative fuels due to their excellent properties. In this paper, under different component ratio conditions, the ethanol-butanol droplet impacting onto the heated aluminum surface has been studied experimentally. The falling height of the droplets were set at 5cm. A high-speed camera, set at 512×512pixels, 5000 fps and 20 μs of exposure time, was used to visualize the droplet behavior impinging onto the hot aluminum surface. The impact regimes of the binary droplet were identified. The result showed that the Leidenfrost temperature of droplets was affected by the ratio of ethanol to butanol. The higher the content of butanol in the droplet, the higher the Leidenfrost temperature.

Bio-butanol has been widely investigated as a promising alternative fuel. However, the main issues preventing the industrial-scale production of butanol is its relatively low production efficiency and high cost of production. Acetone-butanol-ethanol (ABE), the intermediate product in the ABE fermentation process for producing bio-butanol, has attracted a lot of interest as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. If ABE could be directly used for clean combustion, the separation costs would be eliminated which save an enormous amount of time and money in the production chain of bio-butanol.

Due to the increasing consumption of fossil fuels, alternative fuels in internal combustion engines have attracted a lot of attention in recent years. Ethanol is the most common alternative fuel used in spark ignition (SI) engines due to its advantages of biodegradability, positively impacting emissions reduction as well as octane number improvement. Meanwhile, acetone is well-known as one of the industrial waste solvents for synthetic fibers and most plastic materials. In comparison to ethanol, acetone has a number of more desirable properties for being a viable alternative fuel such as its higher energy density, heating value and volatility.

The motivation of the present work was to understand the mechanism by which alcohols produce less aromatic species in their combustion process than an equal amount of hydrocarbon with similar molecular structure does. Due to its numerous advantages over short-chain alcohols, butanol has been considered very promising in soot reduction. Excluding the influence of spray, vaporization and mixing process in engine cases, an adiabatic constant-pressure reactor model was applied to investigate the effect of butanol additives on aromatic species, which are known to be soot precursors, in fuel-rich butane flames. To keep the carbon flux constant, 5% and 10% oxygen by mass of the fuel were added to butane using butanol additive, respectively. Based on the soot reduction effects proposed in literature, effects on temperature, key radical concentrations and the carbon removal from the pathway to aromatic species were considered to identify the major mechanism of reduction in aromatic species.

This work presents a comprehensive computational study of diesel - natural gas (NG) dual fuel engine. A complete computational model is developed for the operation of a diesel - NG dual fuel engine modified from an AVL 5402 single cylinder diesel test engine. The model is based on the KIVA-3V program and includes customized sub-models. The model is validated against test cell measurements of both pure diesel and dual fuel operation. The effects of NG on ignition and combustion in dual fuel operation are analyzed in detail. Zero-dimensional computations with a diesel surrogate reaction mechanism are conducted to discover the effects of NG on ignition and combustion and to reveal the fundamental chemical mechanisms behind such effects. Backed by the detailed theoretical analysis, the engine operation parameters are optimized with genetic algorithm (GA) for the dual fuel operation of the modified AVL 5402 test engine.

In order to comply with the stringent emission regulations, many researchers have been focusing on diesel-compressed natural gas (CNG) dual fuel operation in compression ignition (CI) engines. The diesel-CNG dual fuel operation mode has the potential to reduce both the soot and NOx emissions; however, the thermal efficiency is generally lower than that of the pure diesel operation, especially under the low and medium load conditions. The current experimental work investigates the potential of using diesel-1-butanol blends as the pilot fuel to improve the engine performance and emissions. Fuel blends of B0 (pure diesel), B10 (90% diesel and 10% 1-butanol by volume) and B20 (80% diesel and 20% 1-butanol) with 70% CNG substitution were compared based on an equivalent input energy at an engine speed of 1200 RPM. The results indicated that the diesel-1-butanol pilot fuel can lead to a more homogeneous mixture due to the longer ignition delay.

An experimental investigation was conducted using a Ford single-cylinder spark-ignition research engine to compare the performance and emissions of neat n-butanol fuel to that of gasoline and ethanol. Measurements of brake torque and exhaust gas temperature along with in-cylinder pressure traces were used to study the performance of the engine and measurements of emissions of unburned hydrocarbons, carbon monoxide, and nitrogen oxide ere used to compare the three fuels in terms of combustion byproducts. It was found that gasoline and butanol are closest in engine performance with butanol producing slightly less brake torque. Exhaust gas temperature and nitrogen oxide measurements show that butanol combusts at a lower peak temperature. Of particular interest were the emissions of unburned hydrocarbons which were between two and three times those of gasoline suggesting that butanol is not atomizing as effectively as gasoline and ethanol.

Performance and emissions of a common-rail production diesel engine fueled with soybean-derived biodiesel was investigated. The work was broken down into two categories. First, adjustment of injection timing and EGR ratio was investigated as a means to reduce NOx emissions to levels comparable with those obtained when using pure diesel fuel. Next, simultaneous reduction of NOx and soot emissions was investigated using high rates of EGR combined with late injection timings to approach the low-temperature combustion regime. Results from the first part of the study indicate that optimization of engine control parameters for use with biodiesel can be beneficial to performance and emissions. It was found that adjusting the engine's MAF setpoint table to reflect the difference in stoichiometric air-fuel ratio between diesel and biodiesel brought NOx emissions to comparable or lower levels.