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Journal Article

Review of Soot Deposition and Removal Mechanisms in EGR Coolers

2010-04-12
2010-01-1211
Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOX emissions. Engine coolant is used to cool EGR coolers. The presence of a cold surface in the cooler causes fouling due to particulate soot deposition, condensation of hydrocarbon, water and acid. Fouling experience results in cooler effectiveness loss and pressure drop. In this study, possible soot deposition mechanisms are discussed and their orders of magnitude are compared. Also, probable removal mechanisms of soot particles are studied by calculating the forces acting on a single particle attached to the wall or deposited layer. Our analysis shows that thermophoresis in the dominant mechanism for soot deposition in EGR coolers and high surface temperature and high kinetic energy of soot particles at the gas-deposit interface can be the critical factor in particles removal.
Technical Paper

Biodiesel Imposed System Responses in a Medium-Duty Diesel Engine

2010-04-12
2010-01-0565
The often-observed differences in nitrogen oxides, or NOx, emissions between biodiesel and petroleum diesel fuels in diesel engines remain intense topics of research. In several instances, biodiesel-fuelled engines have higher NOx emissions than petroleum-fuelled engines; a situation often referred to as the "biodiesel NOx penalty." The literature is rich with investigations that reveal many fundamental mechanisms which contribute to (in varying and often inverse ways) the manifestation of differences in NOx emissions; these mechanisms include, for example, differences in ignition delay, changes to in-cylinder radiation heat transfer, and unequal heating values between the fuels. In addition to fundamental mechanisms, however, are the effects of "system-response" issues.
Technical Paper

Comparison of Diesel Oxidation Catalyst Performance on an Engine and a Gas Flow Reactor

2007-04-16
2007-01-0231
This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.
Technical Paper

Speciated Hydrocarbon Emissions from an Automotive Diesel Engine and DOC Utilizing Conventional and PCI Combustion

2006-04-03
2006-01-0201
Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.
Technical Paper

Characterizing Light-Off Behavior and Species-Resolved Conversion Efficiencies During In-Situ Diesel Oxidation Catalyst Degreening

2006-04-03
2006-01-0209
Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.
Technical Paper

Multi-Dimensional Modeling of NO and Soot Emissions with Detailed Chemistry and Mixing in a Direct Injection Natural Gas Engine

2002-03-04
2002-01-1112
This work reports the development and application of multi-dimensional ignition, combustion and emissions models that account for detailed chemistry and mixing effects in a direct injection engine simulation. A detailed chemical reaction mechanism, consisting of 24 species and 104 reactions, is used for increased accuracy of emissions predictions. Turbulent combustion is represented using a modified Eddy Dissipation Concept (EDC) model to account for mixing effects. The soot model includes all aspects of soot formation and destruction. Particle transport equations are used to realistically track transport of the soot particles formed. All computational sub-models developed in this work have been implemented in a modified version of the KIVA-3V code. In order to illustrate the behavior of the new models, soot and NO emissions have been predicted at different operating conditions by varying injection timing, exhaust gas recirculation (EGR) and injection pressure.
Technical Paper

Optimizing Gaseous Fuel-Air Mixing in Direct Injection Engines Using an RNG Based k-ε Model

1998-02-23
980135
Direct injection of natural gas under high pressure conditions has emerged as a promising option for improving engine fuel economy and emissions. However, since the gaseous injection technology is new, limited experience exists as to the optimum configuration of the injection system and associated combustion chamber design. The present study uses KIVA-3 based, multidimensional modeling to improve the understanding and assist the optimization of the gaseous injection process. Compared to standard k-ε models, a Renormalization Group Theory (RNG) based k-ε model [1] has been found to be in better agreement with experiments in predicting gaseous penetration histories for both free and confined jet configurations. Hence, this validated RNG model is adopted here to perform computations in realistic engine geometries.
Technical Paper

Multi-Dimensional Modeling of Natural Gas Ignition Under Compression Ignition Conditions Using Detailed Chemistry

1998-02-23
980136
A detailed chemical kinetic mechanism, consisting of 22 species and 104 elementary reactions, has been used in conjunction with the multi-dimensional reactive flow code KIVA-3 to study autoignition of natural gas injected under compression ignition conditions. Calculations for three different blends of natural gas are performed on a three-dimensional computational grid by modeling both the injection and ignition processes. Ignition delay predictions at pressures and temperatures typical of top-dead-center conditions in compression ignition engines compare well with the measurements of Naber et al. [1] in a combustion bomb. Two different criteria, based on pressure rise and mass of fuel burned, are used to detect the onset of ignition. Parametric studies are conducted to show the effect of additives like ethane and hydrogen peroxide in increasing the fuel consumption rate.
Technical Paper

One-Dimensional Transient Dynamics of Fuel Evaporation and Diffusion in Induction Systems

1997-02-24
970058
Engine performance under transients is greatly affected by the fuel behavior in the induction systems. To better understand the fuel behavior, a computer model has been developed to study the one-dimensional coupled heat and mass transfer processes occurring during the transient evaporation of liquid fuel from a heated surface into stagnant air. The energy and mass diffusion equations are solved simultaneously to yield the transient temperatures and species concentrations using a modified finite difference technique. The numerical technique is capable of solving the coupled equations while simultaneously tracking the movement of the evaporation interface. Evaporation results are presented for various initial film thicknesses representing typical puddle thicknesses for multi-point fuel injection systems using heptane, octane, and nonane pure hydrocarbon fuels.
Technical Paper

Numerical Modeling and Experimental Investigations of EGR Cooler Fouling in a Diesel Engine

2009-04-20
2009-01-1506
EGR coolers are mainly used on diesel engines to reduce intake charge temperature and thus reduce emissions of NOx and PM. Soot and hydrocarbon deposition in the EGR cooler reduces heat transfer efficiency of the cooler and increases emissions and pressure drop across the cooler. They may also be acidic and corrosive. Fouling has been always treated as an approximate factor in heat exchanger designs and it has not been modeled in detail. The aim of this paper is to look into fouling formation in an EGR cooler of a diesel engine. A 1-D model is developed to predict and calculate EGR cooler fouling amount and distribution across a concentric tube heat exchanger with a constant wall temperature. The model is compared to an experiment that is designed for correlation of the model. Effectiveness, mass deposition, and pressure drop are the parameters that have been compared. The results of the model are in a good agreement with the experimental data.
Journal Article

The Impact of Biodiesel on Injection Timing and Pulsewidth in a Common-Rail Medium-Duty Diesel Engine

2009-11-02
2009-01-2782
Due to its ease of use in diesel engines, its presumably lower carbon footprint, and its potential as a renewable fuel, biodiesel has attracted considerable attention in technological development and research literature. Much literature is devoted to evaluating the injection and combustion characteristics of biodiesel fuel using unit injectors, where injection pressure and timing are regulated within the same unit. The use of common rail fuel systems, where fuel pressure is now equally governed to each injector (of a multi-cylinder engine), may change the conventionally accepted impact of biodiesel on injection and combustion characteristics. The objectives of this study are to characterize the responses of an electronically-controlled common-rail fuel injector (in terms of timing and duration) when delivering either 100% palm olein biodiesel or 100% petroleum diesel for a diesel engine, and correlate potential changes in injector characteristics to changes in combustion.
Journal Article

Premixed Low Temperature Combustion of Biodiesel and Blends in a High Speed Compression Ignition Engine

2009-04-20
2009-01-0133
The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.
Technical Paper

Performance Parameter Analysis of a Biodiesel-Fuelled Medium Duty Diesel Engine

2009-04-20
2009-01-0481
Biodiesel remains an alternative fuel of interest for use in diesel engines. A common characteristic of biodiesel, relative to petroleum diesel, is a lowered heating value (or energy content of the fuel). A lower heating value of the fuel would, presuming all other parameters are equal, result in decreased engine torque. Since engine torque is often user-demanded, the lower heating value of the fuel generally translates into increased brake specific fuel consumption. Several literature report this characteristic of biodiesel. In spite of the wealth of fuel consumption characteristic data available for biodiesel, it is not clear how other engine performance parameters may change with the use of biodiesel. Characterizing these parameters becomes complicated when considering the interactions of the various engine systems, such as a variable geometry turbocharger with exhaust gas recirculation.
Technical Paper

Multi-Dimensional Modeling of Ignition, Combustion and Nitric Oxide Formation in Direct Injection Natural Gas Engines

2000-06-19
2000-01-1839
The heat release and pollutant formation processes in a direct injection natural gas engine are studied by coupling detailed chemistry with a multi-dimensional reactive flow code. A detailed kinetic mechanism consisting of 22 species and 104 elementary reactions is chosen by comparing ignition delay predictions with measurements in a combustion bomb. The ignition model is then coupled with a turbulent combustion model and extended Zeldovich kinetics to simulate heat release and nitric oxide production in a direct injection engine. Parametric studies are conducted to investigate the effect of engine operating conditions which include speed, load, injection timing and level of boost. It is shown that use of detailed chemistry is extremely important to predict the correct ignition delay period as engine operating conditions change. Use of both time and crank angle as the independent variable reveals interesting details of the heat release process as a function of engine speed.
Technical Paper

Compression Ratio Influence on Maximum Load of a Natural Gas Fueled HCCI Engine

2002-03-04
2002-01-0111
This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.
Journal Article

Modeling of Thermophoretic Soot Deposition and Hydrocarbon Condensation in EGR Coolers

2009-06-15
2009-01-1939
EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40–90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature.
Technical Paper

High Power Discharge Combustion Effects on Fuel Consumption, Emissions, and Catalyst Heating

2014-10-13
2014-01-2626
A key element to achieving vehicle emission certification for most light-duty vehicles using spark-ignition engine technology is prompt catalyst warming. Emission mitigation largely does not occur while the catalyst is below its “light-off temperature”, which takes a certain time to achieve when the engine starts from a cold condition. If the catalyst takes too long to light-off, the vehicle could fail its emission certification; it is necessary to minimize the catalyst warm up period to mitigate emissions as quickly as possible. One technique used to minimize catalyst warm up is to calibrate the engine in such a way that it delivers high temperature exhaust. At idle or low speed/low-load conditions, this can be done by retarding spark timing with a corresponding increase in fuel flow rate and / or leaning the mixture. Both approaches, however, encounter limits as combustion stability degrades and / or nitrogen oxide emissions rise excessively.
Technical Paper

Experimental and Simulated Results Detailing the Sensitivity of Natural Gas HCCI Engines to Fuel Composition

2001-09-24
2001-01-3609
Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.
Technical Paper

Effect of Exhaust Valve Timing on Gasoline Engine Performance and Hydrocarbon Emissions

2004-10-25
2004-01-3058
Despite remarkable progress made over the past 30 years, automobiles continue to be a major source of hydrocarbon emissions. The objective of this study is to evaluate whether variable exhaust valve opening (EVO) and exhaust valve closing (EVC) can be used to reduce hydrocarbon emissions. An automotive gasoline engine was tested with different EVO and EVC timings under steady-state and start-up conditions. The first strategy that was evaluated uses early EVO with standard EVC. Although exhaust gas temperature is increased and catalyst light-off time is reduced, the rapid drop in cylinder temperature increases cylinder-out hydrocarbons to such a degree that a net increase in hydrocarbon emissions results. The second strategy that was evaluated uses early EVO with early EVC. Early EVO reduces catalyst light-off time by increasing exhaust gas temperature and early EVC keeps the hydrocarbon-rich exhaust gas from the piston crevice from leaving the cylinder.
Journal Article

Evaluation of Diesel Oxidation Catalyst Conversion of Hydrocarbons and Particulate Matter from Premixed Low Temperature Combustion of Biodiesel

2011-04-12
2011-01-1186
Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.
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