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Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEPg) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEPg). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations.

Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

A number of studies have identified a tendency for exhaust gas recirculation (EGR) coolers to foul to a steady-state level and subsequently not degrade further. One possible explanation for this behavior is that the shear force imposed by the gas velocity increases as the deposit thickens. If the shear force reaches a critical level, it achieves a removal of the deposit material that can balance the rate of deposition of new material, creating a stabilized condition. This study reports efforts to observe removal of deposit material in-situ during fouling studies as well as an ex-situ removal through the use of controlled air flows. The critical gas velocity and shear stress necessary to cause removal of deposit material is identified and reported. In-situ observations failed to show convincing evidence of a removal of deposit material. The results show that removal of deposit material requires a relatively high velocity of 40 m/s or higher to cause removal.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

West Virginia University evaluated diesel oxidation catalysts (DOC) and lean-NOX catalysts as part of Diesel Emissions Control-Sulfur Effects (DECSE) project. In order to perform thermal aging of the DOC and lean-NOX catalysts simultaneously and economically, each catalyst was sized to accommodate half of the engine exhaust flow. Simultaneous catalyst aging was then achieved by splitting the engine exhaust into two streams such that approximately half of the total exhaust flowed through the DOC and half through the lean-NOX catalyst. This necessitated splitting the engine exhaust into two streams during emissions measurements. Throttling valves installed in each branch of the split exhaust were adjusted so that approximately half the engine exhaust passed though the active catalyst under evaluation and into a full flow dilution tunnel for emissions measurement.

The goal of the Diesel Emissions Control-Sulfur Effects (DECSE) program was to determine the impact of diesel fuel sulfur levels on emissions control devices that could lower emissions of oxides of nitrogen (NOX) and particulate matter (PM) from on-highway trucks and buses. West Virginia University (WVU) performed evaluations of lean-NOx catalysts to determine the effects of fuel sulfur content on emissions reduction efficiency and catalyst durability in the first 250 hours of operation. A Cummins ISM370 engine (10.8 liter, 370 horsepower), typical of heavy -duty truck applications, was utilized to evaluate high-temperature lean-NOX catalyst while a Navistar T444E (7.3 liter, 210 horsepower), typical of medium-duty applications, was used to evaluate low-temperature catalyst. Catalysts were evaluated periodically during the first 250 hours of exposure to exhaust from engines operated on 3ppm, 30ppm, 150ppm and 350ppm sulfur content diesel fuel.

Because of the great interest in biodiesel fuels around the world, the International Energy Agency's Committee on Advanced Motor Fuels sponsored this project to determine emissions and performance of a number of biodiesel fuels with a special emphasis on unregulated emissions. Oak Ridge National Laboratory (ORNL) and Technical Research Centre in Finland (VTT) carried out the project with complementary work plans. Several different engines were used between the two sites, and in some cases emissions control catalysts were used, both at ORNL and at VTT. ORNL concentrated on light and medium duty engines, while VTT emphasized a heavy-duty engine and also used a light duty car as a test bed. Common fuels between the two sites for these tests were rape methyl ester in 30% blend and neat, soy methyl ester in 30% blend and neat, used vegetable oil methyl ester (UVOME) in 30% blend, and the Swedish environmental class 1 reformulated diesel (RFD).

The aim of this investigation was to improve understanding and quantify the impact of exhaust gas recirculation (EGR) as an emissions control measure onto cyclic variability of a small-bore, single-cylinder, diesel-fueled compression-ignition (CI) power generation unit. Of special interest were how cycle-to-cycle variations of the CI engine affect steady-state voltage deviations and frequency bandwidths. Furthermore, the study strived to elucidate the impact of EGR addition onto combustion parameters, as well as gaseous and particle phase emissions along with fuel consumption. The power generation unit was operated over five discrete steady-state test modes, representative of nominal 0, 25, 50, 75, and 100% engine load (i.e. 0-484kPa BMEP), by absorbing electrical power via a resistive load bank. The engine was equipped with a passive EGR system that directly connected the exhaust and intake runners through a small passage.

Exhaust gas recirculation (EGR) cooler fouling has become a significant issue for compliance with NOX emissions standards and has negative impacts on cooler sizing and engine performance. In order to improve our knowledge of cooler fouling as a function of engine operating parameters and to predict and enhance performance, 19 tube-in-shell EGR coolers were fouled using a 5-factor, 3-level design of experiments with the following variables: (1) EGR flow rate, (2) EGR inlet gas temperature, (3) coolant temperature, (4) soot level, and (5) hydrocarbon concentration. A 9-liter engine and ULSD fuel were used to form the cooler deposits. Coolers were run until the effectiveness stabilized, and then were cooled down to room temperature and run for an additional few hours in order to measure the change in effectiveness due to shut down. The coolers were cut open and the mass per unit area of the deposit was measured as a function of distance down the tube.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

Increasingly stringent oxides of nitrogen (NOx) and particulate matter (PM) regulations worldwide have prompted considerable activity in developing emission control technology to reduce the emissions of these two constituents from heavy-duty diesel engines. NOx has come under particular scrutiny by regulators in the US and in Europe with the promulgation of very stringent regulation by both the US Environmental Protection Agency (EPA) and the European Union (EU). In response, heavy-duty engine manufacturers are considering Selective Catalytic Reduction (SCR) as a potential NOx reduction option. While SCR performance has been well established through engine dynamometer evaluation under laboratory conditions, there exists little data characterizing SCR performance under real-world operating conditions over time. This project evaluated the field performance of ten SCR units installed on heavy-duty Class 8 highway and refuse trucks.

Lean NOx Trap (LNT) catalysts are capable of reducing NOx in lean exhaust from diesel engines. NOx is stored on the catalyst during lean operation; then, under rich exhaust conditions, the NOx is released from and reduced by the catalyst. The process of NOx release and reduction is called regeneration. One method of obtaining the rich conditions for regeneration is to inject additional fuel into the engine cylinders while throttling the engine intake air flow to effectively run the engine at rich air:fuel ratios; this method is called “in-cylinder” regeneration. In-cylinder regeneration of LNT catalysts has been demonstrated and is a candidate emission control technique for commercialization of light-duty diesel vehicles to meet future emission regulations. In the study presented here, a 1.7-liter diesel engine with a LNT catalyst system was used to evaluate in-cylinder regeneration techniques.

There is a need for an efficient, durable technology to reduce NOx emissions from oxidative exhaust streams such as those produced by compression-ignition, direct-injection (CIDI) diesel or lean-burn gasoline engines. A partnership formed between the DOE Office of Advanced Automotive Technology, Pacific Northwest National Laboratory, Oak Ridge National Laboratory and the USCAR Low Emission Technologies Research and Development Partnership is evaluating the effectiveness of a non-thermal plasma in conjunction with catalytic materials to mediate NOx and particulate emissions from diesel fueled light duty (CIDI) engines. Preliminary studies showed that plasma-catalyst systems could reduce up to 70% of NOx emissions at an equivalent cost of 3.5% of the input fuel in simulated diesel exhaust. These studies also showed that the type and concentration of hydrocarbon play a key role in both the plasma gas phase chemistry and the catalyst surface chemistry.

To help guide heavy vehicle engine, fuel, and exhaust after-treatment technology development, the U.S. Department of Energy and the Lovelace Respiratory Research Institute are conducting research not addressed elsewhere on aspects of the toxicity of particulate engine emissions. Advances in these technologies that reduce diesel particulate mass emissions may result in changes in particle composition, and there is concern that the number of ultrafine (<0.1 micron) particles may increase. All present epidemiological and laboratory data on the toxicity of diesel emissions were derived from emissions of older-technology engines. New, short-term toxicity data are needed to make health-based choices among diesel technologies and to compare the toxicity of diesel emissions to those of other engine technologies.

All high-pressure exhaust gas recirculation (EGR) coolers become fouled during operation due to thermophoresis of particulate matter and condensation of hydrocarbons present in diesel exhaust. In some EGR coolers, fouling is so severe that deposits form plugs strong enough to occlude the gas passages thereby causing a complete failure of the EGR system. In order to better understand plugging and means of reducing its undesirable performance degradation, EGR coolers exhibiting plugging were requested from and provided by industry EGR engineers. Two of these coolers contained glassy, brittle, lacquer-like deposits which were analyzed using gas chromatography-mass spectrometry (GC-MS) which identified large amounts of oxygenated polycyclic aromatic hydrocarbons (PAHs). Another cooler exhibited similar species to the lacquer but at a lower concentration with more soot.

Biodiesel may be derived from either plant or animal sources, and is usually employed as a compression ignition fuel in a blend with petroleum diesel (PD). Emissions differences between vehicles operated on biodiesel blends and on diesel have been published previously, but data do not cover the latest engine technologies. Prior studies have shown that biodiesel offers advantages in reducing particulate matter, with either no advantage or a slight disadvantage for oxides of nitrogen emissions. This paper describes a recent study on the emissions impact of two biodiesel blends B20A, made from 20% animal fat (tallow) biodiesel and 80% PD, and B20B, obtained from 20% soybean biodiesel and 80% PD. These blends used the same PD fuel for blending and were contrasted with the same PD fuel as a reference. The research was conducted on a 2007 medium heavy-duty diesel truck (MHDDT), with an engine equipped with Exhaust Gas Recirculation (EGR) and a Diesel Particulate Filter (DPF).

Most transient heavy duty diesel emissions data in the USA have been acquired using the Federal Test Procedure (FTP), a heavy-duty diesel engine transient test schedule described in the US Code of Federal Regulations. The FTP includes both urban and freeway operation and does not provide data separated by driving mode (such as rural, urban, freeway). Recently, a four-mode engine test schedule was created for use in the Advanced Collaborative Emission Study (ACES), and was demonstrated on a 2004 engine equipped with cooled Exhaust Gas Recirculation (EGR). In the present work, the authors examined emissions using these ACES modes (Creep, Cruise, Transient and High-speed Cruise) and the FTP from a Detroit Diesel Corporation (DDC) Series 60 1992 12.7 liter pre-EGR engine. The engine emissions were measured using full exhaust dilution, continuous measurement of gaseous species, and filter-based Particulate Matter (PM) measurement.

Exhaust gas recirculation (EGR) cooler fouling has become a significant issue for compliance with nitrogen oxides (NOx) emissions standards. In order to better understand fouling mechanisms, eleven field-aged EGR coolers provided by seven different engine manufacturers were characterized using a suite of techniques. Microstructures were characterized using scanning electron microscopy (SEM) and optical microscopy following mounting the samples in epoxy and polishing. Optical microscopy was able to discern the location of hydrocarbons in the polished cross-sections. Chemical compositions were measured using thermal gravimetric analysis (TGA), differential thermal analysis (DTA), gas chromatography-mass spectrometry (GC-MS), x-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS) and x-ray diffraction (XRD). Mass per unit area along the length of the coolers was also measured.