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Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

A CNG bi-fuel version of the GMC and Chevrolet C2500 pick up trucks was developed as an OEM (Original Equipment Manufacturer) vehicle. The converted bi-fuel vehicles use the same engine with modifications for use with gaseous fuels, and the same catalytic converters as the gasoline baseline. The fuel management system is an automatic switching bi-fuel system which is able to control fuel flow rate, spark timing, EGR, and perform OBD-II (On-Board Diagnostics II) on both gasoline and CNG. This system has been extensively tested and validated for durability, electro magnetic compatibility requirements, crash integrity, corrosion resistance, emissions performance and powertrain performance under extreme environmental conditions and different CNG fuel compositions. The CNG fuel storage technology of the bi-fuel system was validated to the most stringent safety and durability requirements in the industry.

Liquefied Petroleum Gas (LPG) and Compressed Natural Gas (CNG) have long been recognized as ideal clean and potentially available fuels for motor vehicles. However, some disadvantages of the two gaseous fuels such as lower energy density (kW/l) compared to gasoline, a loss of power in unmodified converted engines relative to gasoline and the current shortage of refueling stations hamper their widespread use. Additionally, engines with throttle-body gaseous fuel fumigation need longer cranking time and exhibit relatively slow response during transient engine operation. To alleviate the above shortcomings, a low cost dual-fuel system was developed. The prototype system uses a mixture of gaseous fuel (Liquefied Petroleum Gas) and gasoline to enhance fuel economy, drivability, and lower emissions. The two fuels can be mixed at any percentage depending on the customer's need.

A CNG bi-fuel version of the Chevrolet Cavalier has been developed as an OEM (Original Equipment Manufacturer) vehicle. The fuel management system is an automatically switching bi-fuel system which is able to control fuel flow rate, spark timing, EGR, and perform OBD-II (On-Board Diagnostics II). The system consists of a CNG fuel tank, fuel filter, electric and manual fuel shutoff valves, high and low pressure regulators, gas mass sensor, mixture control valve, gas distribution system, CNG fuel gauge, OEM exhaust gas oxygen sensor, digital engine control unit (ECU), OEM powertrain control module (PCM) and unique wiring harness. This paper discusses the components, operation, and calibration of the CNG bi-fuel management system. A computer engine simulation model able to predict engine performance, fuel economy, and exhaust emissions, was used to assist spark, fuel, and EGR table mapping.

This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

In-use, light-duty vehicles were recruited in Cary, North Carolina for emissions testing on a transportable dynamometer in 1999. Two hundred forty-eight vehicles were tested in as received condition using the IM240 driving cycle. The study was conducted in two phases, a summer and winter phase, with half of the vehicles recruited during each phase. Regulated emissions, PM10, carbonaceous PM, aldehydes and ketones were measured for every test. PM2.5, individual volatile hydrocarbons, polycyclic aromatic hydrocarbons, sterane and hopane emissions were measured from a subset of the vehicles. Average light-duty gasoline PM10 emission rates increased from 6.5 mg/mi for 1993-97 vehicles to 53.8 mg/mi for the pre-1985 vehicles. The recruited fleet average, hot-stabilized IM240 PM10 emission rate for gasoline vehicles was 19.0 mg/mi.

The aim of this investigation was to improve understanding and quantify the impact of exhaust gas recirculation (EGR) as an emissions control measure onto cyclic variability of a small-bore, single-cylinder, diesel-fueled compression-ignition (CI) power generation unit. Of special interest were how cycle-to-cycle variations of the CI engine affect steady-state voltage deviations and frequency bandwidths. Furthermore, the study strived to elucidate the impact of EGR addition onto combustion parameters, as well as gaseous and particle phase emissions along with fuel consumption. The power generation unit was operated over five discrete steady-state test modes, representative of nominal 0, 25, 50, 75, and 100% engine load (i.e. 0-484kPa BMEP), by absorbing electrical power via a resistive load bank. The engine was equipped with a passive EGR system that directly connected the exhaust and intake runners through a small passage.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Gaseous and particulate emissions from heavy-duty vehicles are affected by fuel types, vehicle/engine parameters, driving characteristics, and environmental conditions. Transient chassis tests were conducted on twenty-six heavy-duty vehicles fueled with methanol, compressed natural gas (CNG), #1 diesel, and #2 diesel, using West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory. The vehicles were operated on the central business district (CBD) testing cycle, and regulated emissions of carbon monoxide (CO), total hydrocarbon (HC), nitrogen oxides (NOx), and particulate matter (PM) were measured. Comparisons of regulated emissions results revealed that the vehicles powered on methanol and CNG produced much lower particulate emissions than the conventionally fueled vehicles.

The West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory was employed to conduct chassis dynamometer tests in the field to measure the exhaust emissions from heavy-duty buses and trucks. This laboratory began operation in the field in January, 1992. During the period January, 1992 through June, 1993, over 150 city buses, trucks, and tractors operated by 18 different authorities in 11 states were tested by the facility. The tested vehicles were powered by 14 different types of engines fueled with natural gas (CNG or LNG), methanol, ethanol, liquified petroleum gas (LPG), #2 diesel, and low sulfur diesel (#1 diesel or Jet A). Some of the tested vehicles were equipped with exhaust after-treatment systems. In this paper, a total of 12 CNG-fueled and #2 diesel-fueled transit buses equipped with Cummins L-10 engines, were chosen for investigation.

A set of experiments were conducted to evaluate the performance differences between a Low Heat Rejection Engine (LHRE) which is ceramic-insulated and a conventional baseline metal diesel engine which is water-cooled. Both engines were single cylinder, direct injection, and turbocharged. The objective of the study was to investigate the rate of heat release of these engines so that performance improvement procedures could be obtained. In this paper, the difference of the ignition delay between the two engines was determined. Two methods for improving the combustion process of the LHRE were studied: use of mixture fuels and increase the fuel injection rate. Both methods proved effective and reduced the fuel consumption rate of the LHRE.

Five small two-stroke engine designs were tested at different air/fuel ratios, under steady state and transient cycles. The effects of combustion chamber design, carburetor design, lean burning, and fuel composition on performance, hydrocarbon and carbon monoxide emissions were studied. All tested engines had been designed to run richer than stoichiometric in order to obtain satisfactory cooling and higher power. While hydrocarbon and carbon monoxide emissions could be greatly reduced with lean burning, engine durability would be worsened. However, it was shown that the use of a catalytic converter with acceptably lean combustion was an effective method of reducing emissions. Replacing carburetion with in-cylinder fuel injection in one of the engines resulted in a significant reduction of hydrocarbon and carbon monoxide emissions.

A group of GM C-2500 heavy-duty and GM C-1500 light-duty trucks were modified to bi-fuel compressed natural gas (CNG)/gasoline and liquefied petroleum gas (LPG)/gasoline vehicles. The fuel management systems used for different model year vehicles were introduced. The Alternative Fuel Technology (AFT) System used for 1997 GM C-2500 trucks is discussed in detail. AFT is an automatic switching bi-fuel system which is able to control fuel flow rate, spark timing, and EGR, and perform On-Board Diagnostics (OBD-II). The exhaust emissions of carbon monoxide (CO), total hydrocarbon (HC) and oxides of nitrogen (NOx) were measured using dilute sampling techniques. The vehicles tested were operated on a chassis dynamometer and run on the Federal Test Procedure (FTP) Urban Schedule.

Precipitation chemistry measurements have been made at many California locations, with recorded extreme pH values as low as 2.89 from Pasadena and 3.5 from geologically sensitive Sequoia National Park. However, in northern areas of the state experiencing good air quality, very little acid deposition occurs. California's acid precipitation is apparently locally produced, since there are no major pollution source regions upwind of the state. This is attributable to the extremely rapid rates observed for conversion of NOx to nitric acid and SO2 to sulfuric acid in the atmosphere. Recent monitoring data illustrate extreme variations in precipitation chemistry from adjacent sites and even at the same location from one year to the next. Enrichment factor calculations show that in contrast with data from other locations in the world, nitric acid dominates over sulfuric acid in California's rainfall in many locations.

As emission regulations for off-road engines become more and more stringent, alternative fuel off-road engines are being developed rapidly. This paper studies a closed-loop controlled LPG system, which was developed and tested on four lawn and garden engines. The four engines studied are Kohler 18hp, Kohler 13 hp, Briggs & Stratton 6 hp, and Briggs & Stratton 5hp engines, which power Toro walk-behind commercial lawn mowers, John Deere lawn tractors, John Deere walk-behind commercial lawn mowers, and Toro walk-behind commercial lawn mowers, respectively. All engines are four-stroke, spark-ignited and air-cooled. The fuel management system is an air valve based closed-loop controlled dedicated LPG system. The emissions and durability test results are presented. It was found that all engines operating on propane had significantly lower exhaust emissions than those of gasoline baselines.

This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.

To help guide heavy vehicle engine, fuel, and exhaust after-treatment technology development, the U.S. Department of Energy and the Lovelace Respiratory Research Institute are conducting research not addressed elsewhere on aspects of the toxicity of particulate engine emissions. Advances in these technologies that reduce diesel particulate mass emissions may result in changes in particle composition, and there is concern that the number of ultrafine (<0.1 micron) particles may increase. All present epidemiological and laboratory data on the toxicity of diesel emissions were derived from emissions of older-technology engines. New, short-term toxicity data are needed to make health-based choices among diesel technologies and to compare the toxicity of diesel emissions to those of other engine technologies.

This paper examines the energy pathways of a 29cc air-cooled two-stroke engine operating on natural gas with different exhaust geometries. The engine was operated at wide-open-throttle at a constant speed of 5400 RPM with ignition adjusted to yield maximum brake torque while the fueling was adjusted to examine both rich and lean combustion. The exhaust configurations examined included an off-the-shelf (OTS) model and two other custom models designed on Helmholtz resonance theory. The custom designs included both single and multi-cone features. Out of the three exhaust systems tested, the model with maximum trapping efficiency showed a higher overall efficiency due to lower fuel short-circuiting and heat transfer. The heat transfer rate was shown to be 10% lower on the new designs relative to OTS model.