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Journal Article

Effect of Biodiesel on NOx Reduction Performance of Urea-SCR System

2010-10-25
2010-01-2278
The use of biomass fuels for vehicles has been a focus of attention all over the world in terms of prevention of global warming, effective utilization of resources and local revitalization. For the purpose of beneficial use of unused biomass resources, the movement of the use of bioethanol and biodiesel made from them has spread in Japan. In Japan, biodiesel is mainly made from waste cooking oil collected by local communities or governments, and in terms of local production for local consumption, it is used as neat fuel (100% biofuel) or mixed with diesel fuel in high concentration for the vehicles. On the other hand, extremely low emission level must be kept for not only gasoline vehicles but also diesel vehicles in the post new long-term regulation implemented from 2009 in Japan.
Technical Paper

Exhaust Emission Characteristics of Commercial Vehicles Fuelled with Biodiesel

2010-10-25
2010-01-2276
The application of biodiesel as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO₂ emission, because biodiesel is produced from renewable biomass resources. In Japan, neat biodiesel derived from waste cooking oil has often been applied to commercial vehicles. However, it is possible that the difference of fuel properties between conventional diesel fuel and biodiesel causes the problems on exhaust emission characteristics of diesel engine. Therefore, it is necessary to clarify the effect of biodiesel fuelling on exhaust emissions from commercial vehicles. Light-duty garbage trucks and heavy-duty diesel buses which were actually fueled with biodiesel in Kyoto, Japan, were used for test vehicles in this study. The exhaust emissions from these vehicles during JE05 mode tests were compared between biodiesel derived from waste cooking oil and conventional diesel fuel.
Technical Paper

A Study on N2O Formation Mechanism and Its Reduction in a Urea SCR System Employed in a DI Diesel Engine

2012-09-10
2012-01-1745
N₂O is known to have a significantly high global warming potential. We measured N₂O emissions in engine-bench tests by changing the NO/NH₃ ratio and exhaust gas temperature at the oxidation catalyst inlet in a heavy-duty diesel engine equipped with a urea SCR (selective catalytic reduction) system. The results showed that the peak N₂O production ratio occurred at an exhaust gas temperature of around 200°C and the maximum value was 84%. Moreover, the N₂O production ratio increased with increasing NO/NH₃. Thus, we concluded that N₂O is produced via the NO branching reaction. Based on our results, two methods were proposed to decrease N₂O formation. At low temperatures ~200°C, NO should be reduced by controlling diesel combustion to lower the contribution of NO to N₂O production. This is essential because the SCR system cannot reduce NOx at low temperatures.
Technical Paper

Ignition and Combustion Control of Diesel HCCI

2005-05-11
2005-01-2132
Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions in diesel engine. In general, high octane number fuels (gasoline components or gaseous fuels) are used for HCCI operation, because these fuels briefly form lean homogeneous mixture because of long ignition delay and high volatility. However, it is necessary to improve injection systems, when these high octane number fuels are used in diesel engine. In addition, the difficulty of controlling auto-ignition timing must be resolved. On the other hand, HCCI using diesel fuel (diesel HCCI) also needs ignition control, because diesel fuel which has a low octane number causes the early ignition before TDC. The purpose of this study is the ignition and combustion control of diesel HCCI. The effects of parameters (injection timing, injection pressure, internal/external EGR, boost pressure, and variable valve timing (VVT)) on the ignition timing of diesel HCCI were investigated.
Technical Paper

Optimization of Engine System for Application of Biodiesel Fuel

2007-07-23
2007-01-2028
Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because biodiesel is carbon neutral in principle. However, biodiesels yield an increase in NOx emission from conventional diesel engine, compared with diesel fuel case. Therefore, some strategies are needed for meeting the future emission regulations when using biodiesel. In this study, rapeseed oil methyl ester (RME) was applied to diesel engine equipped with exhaust gas recirculation (EGR) system and NOx storage reduction (NSR) catalyst. NOx reduction rate of NSR catalyst was drastically decreased by using RME, even if injection quantity of RME for rich spike was enhanced. However, an increase in EGR rate could reduce NOx emission without the deterioration in smoke and PM emissions.
Technical Paper

Application of Biodiesel Fuel to Modern Diesel Engine

2006-04-03
2006-01-0233
The 1997 Kyoto protocol came into effect in February, 2005 to reduce greenhouse gases within the period 2008-2012 by at least 5 % with respect to 1990 levels. Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because BDF is carbon neutral in principle. The purpose of this project is to produce a light-duty biodiesel truck which can be suitable for emission regulation in next generation. The effect of BDF on the performance and emissions of modern diesel engine which was equipped with the aftertreatment for PM and NOx emissions was investigated without modifications of engine components and parameters, as a first step for research and development of biodiesel engine. Rapeseed oil methyl ester (RME) was selected in behalf of BDF, and combustion characteristics, engine performance and exhaust emissions were made a comparison between RME and petroleum diesel fuel by steady operation and Japan transient mode (JE05) tests.
Technical Paper

Diesel Emissions Improvement by RME in a High Boost and EGR Single Cylinder Engine

2008-04-14
2008-01-1376
The biomass fuel is expected to solve the global warming due to a carbon neutral. A rapeseed oil methyl ester (RME) as biomass fuel was selected, and also a low sulfur diesel fuel is tested as reference fuel in this study. The experiments were carried out to improve diesel emissions and engine performance using high boost and high rate EGR system and a common rail injection system in a single cylinder engine. The diesel emissions and engine performance have been measured under the experimental conditions such as charging boost pressure from atmospheric pressure to 401.3kPa maximum and changing EGR rate from 0% to 40% maximum. RME contain about 10 mass % oxygen in the fuel molecule. Furthermore, RME does not contain aromatic hydrocarbons in the fuel. Due to these chemical properties, RME can be used at 40% high EGR condition.
Technical Paper

Study of the Effect of Boiling Point on Combustion and PM Emissions in a Compression Ignition Engine Using Two-Component n-Paraffin Fuels

2002-03-04
2002-01-0871
Fuel composition is investigated as a parameter influencing fuel/air mixing of direct injected fuel and the subsequent consequences for particulate emissions. Presumably, enhanced mixing prior to ignition results in a larger portion of fuel burning as a premixture and a smaller portion of diffusion burning around fuel-rich regions. This would potentially lower particulate emissions without overly compromising hydrocarbon emissions or high load operation. Using mixtures of n-paraffin fuels, particulate emissions were measured and the results were compared with in-cylinder visualization of the injection process and two-color method calculations of flame temperature. In general, lower boiling point fuels exhibited higher flame temperatures, less visible flame, and lower particulate emissions.
Technical Paper

Search for Optimizing Control Method of Homogeneous Charge Diesel Combustion

1999-03-01
1999-01-0184
As a method for reducing exhaust emissions from diesel engines, we have experimented on a homogeneous charge diesel combustion technique (HCDC) whereby a portion of fuel is supplied into the intake port to form a homogeneous premixture, this is then fed into the cylinder from the intake port before ignition of the diesel fuel, which is injected directly into the cylinder. Our results have indicated possibilities of substantially reducing both NOx and smoke emissions. If diesel fuel is premixed with air, the premixture under-goes excessively early self-ignition, making it difficult to maintain ignition timing near top dead center and hence limiting the engine operating conditions. While an important target in emission reduction is to realize stable low-emission combustion during a high-load operation, the actual operation of diesel engines mostly involves partial-load conditions.
Technical Paper

Emission Characteristics of a Urea SCR System under the NOx Level of Japanese 2009 Emission Regulation

2007-10-29
2007-01-3996
In order to discuss future technical issues for urea SCR (selective catalytic reduction) system, it is necessary to assess various technical possibilities that would be applied to urea SCR systems which is capable of complying with future emission level requirements, for example Japanese 2009 emission regulation. In this paper, three measures (enhanced insulation on a DOC (diesel oxidation catalyst), aggressive urea solution injection and idling stop) are installed on a urea SCR system of a commercial engine system in order to achieve further NOx (nitrogen oxide) reductions. With combination of these three measures, NOx is drastically reduced to the levels lower than 0.7 g/kWh, which is a NOx limit value of the Japanese 2009 emission regulation. NH3 (ammonia) and HCN (hydro cyanide) are also measured as unregulated harmful components.
Technical Paper

Improvement of NOx Reduction Rate of Urea-SCR System by NH3 Adsorption Quantity Control

2008-10-06
2008-01-2498
A urea SCR system was combined with a DPF system to reduce NOx and PM in a four liters turbocharged with intercooler diesel engine. Significant reduction in NOx was observed at low exhaust gas temperatures by increasing NH3 adsorption quantity in the SCR catalyst. Control logic of the NH3 adsorption quantity for transient operation was developed based on the NH3 adsorption characteristics on the SCR catalyst. It has been shown that NOx can be reduced by 75% at the average SCR inlet gas temperature of 158 deg.C by adopting the NH3 adsorption quantity control in the JE05 Mode.
Technical Paper

Effect of Exhaust Gas Recirculation on Exhaust Emissions from Diesel Engines Fuelled with Biodiesel

2007-09-16
2007-24-0128
Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because bio-diesel is carbon neutral in principle. However, when biodiesel was applied to conventional diesel engines without modification for biodiesel, NOx emission was increased by the change in fuel characteristics. It is necessary to introduce some strategies into diesel engines fuelled with biodiesel for lower NOx emission than conventional diesel fuel case. The purpose of this study is to reveal that exhaust gas recirculation (EGR) is one of the solutions for the reduction of NOx emission and meeting the future emission regulations when using biodiesel. Neat Rapeseed oil methyl ester (RME) as a biodiesel (B100) was applied to diesel engines equipped with high pressure loop (HPL) EGR system and low pressure loop (LPL) EGR system. Cooled HPL EGR was increased during steady-state operations and JE05 transient mode tests.
Technical Paper

Emission Characteristics of a Urea SCR System under Catalysts Activated and De-Activated Conditions

2006-04-03
2006-01-0639
Urea SCR (Selective Catalytic Reduction) system has high potential of reducing NOx. But such as system durability and safety under deteriorated catalysts conditions have not been well enough clarified because it is new technology for vehicles. In this paper, current NOx emission level of an engine equipped with urea SCR system is discussed and then exhaust emission characteristics were analyzed when the SCR catalyst and/or oxidation catalyst lose their functions. When both SCR and oxidation catalyst were de-activated, not only NOx but also PM increased remarkably, which were much more than the engine-out emissions. Oxidation catalyst downstream of SCR catalyst was effective to suppress such deteriorations.
Technical Paper

Advanced Diesel Combustion Using of Wide Range, High Boosted and Cooled EGR System by Single Cylinder Engine

2006-04-03
2006-01-0077
For reducing exhaust emissions of heavy-duty diesel engines, the authors made an experimental study of diesel combustion using a single cylinder engine. The engine performance and exhaust emissions have been measured using a wide range and high EGR rate under the conditions of high boost intake pressure. The engine test cell has been equipped the external supercharger that is able to raise the boost pressure to 500 kPa, and also equipped the EGR system to increase the EGR rate until 50% under the 500 kPa boost condition. In various test conditions of load and engine speeds the authors have obtained the results, that is, NOx has been reduced drastically without increasing Particulate Matter (PM).
Technical Paper

Effect of Biodiesel Blending on Emission Characteristics of Modern Diesel Engine

2008-10-06
2008-01-2384
The use of biodiesel fuels as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO2 emission, because biodiesel is produced from renewable biomass resources. Biodiesel is usually blended to conventional diesel fuel in various proportions. It is possible that this biodiesel blending causes the problems on emission characteristics of modern diesel engine, because it could be confirmed that the application of neat biodiesel to modern diesel engines whose control parameters were optimized for conventional diesel fuel deteriorated the emission performances. It is necessary to clarify the effect of biodiesel blending on exhaust emissions of modern diesel engine. Rapeseed oil methyl ester (RME) was selected as a biodiesel used in this study.
Technical Paper

Exhaust Purification of Diesel Engines by Homogeneous Charge with Compression Ignition Part 2: Analysis of Combustion Phenomena and NOx Formation by Numerical Simulation with Experiment

1997-02-24
970315
An experimental and a numerical analysis wereconducted based on the concept of homogeneous charge diesel combustion (HCDC), in which most of the fuel is supplied for pre-mixed homogeneous charge which is compressed in the cylinder and then ignited by small amount of diesel fuel directly injected into a cylinder. At the previous report, It was indicated that simultaneous improvement of NOx and smoke were possible. Especially under a certain condition, NOx was extremely reduced. This report describes the preliminary analysis for the cause of this emission improvement with HCDC method. As result, direct optical observation of the combustion phenomena and numerical analysis using KIVA2 code suggested that low NOx combustion may be caused by lowered combustion temperature and reduced combustion period due to the uniform lean combustion.
Technical Paper

Exhaust Purification of Diesel Engines by Homogeneous Charge with Compression Ignition Part 1: Experimental Investigation of Combustion and Exhaust Emission Behavior Under Pre-Mixed Homogeneous Charge Compression Ignition Method

1997-02-24
970313
A homogeneous Charge Compression Ignition Diesel Combustion (HCDC) system has been experimentally studied for it's effect on exhaust purification of diesel engines. In this system, most fuel is injected into the intake manifold to form homogeneous pre-mixture in the combustion chamber beforehand and the pre-mixture is ignited with a small amount of fuel directly injected into the cylinder by a conventional injection system. Because this system performs homogeneous lean-burn, it can realize low emission which cannot be realized by conventional diesel engines without impairing ignition controllability in the operations ranging from idle to full load. In particular, although the operating regions were strictly limited, extremely low Nox emission levels of as low as 10 to 40 ppm were realized with maintaining low smoke emissions, when the ratio of pre-mixed fuel was increased up to approx. 98%.
Technical Paper

Effects of Fuel Properties on Combustion and Exhaust Emissions of Homogeneous Charge Compression Ignition (HCCI) Engine

2004-06-08
2004-01-1966
Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions from diesel engine. In general, high octane number and volatility fuels (gasoline components or gaseous fuels) are used for HCCI operation, because very lean mixture must be formed during ignition delay of the fuel. However, it is necessary to improve fuel injection systems, when these fuels are used in diesel engine. The purpose of the present study is the achievement of HCCI combustion in DI diesel engine without the large-scale improvements of engine components. Various high octane number fuels are mixed with diesel fuel as a base fuel, and the mixed fuels are directly applied to DI diesel engine. At first, the cylinder pressure and heat release rate of each mixed fuel are analyzed. The ignition delay of HCCI operation decreases with an increase in the operation load, although that of conventional diesel operation does not almost varied.
Technical Paper

Comparison of Numerical Results and Experimental Data on Emission Production Processes in a Diesel Engine

2001-03-05
2001-01-0656
Simulations of DI Diesel engine combustion have been performed using a modified KIVA-II package with a recently developed phenomenological soot model. The phenomenological soot model includes generic description of fuel pyrolysis, soot particle inception, coagulation, and surface growth and oxidation. The computational results are compared with experimental data from a Cummins N14 single cylinder test engine. Results of the simulations show acceptable agreement with experimental data in terms of cylinder pressure, rate of heat release, and engine-out NOx and soot emissions for a range of fuel injection timings considered. The numerical results are also post-processed to obtain time-resolved soot radiation intensity and compared with the experimental data analyzed using two-color optical pyrometry. The temperature magnitude and KL trends show favorable agreement.
Technical Paper

N2O Emissions from Vehicles Equipped with Three-Way Catalysts in a Cold Climate

2002-05-06
2002-01-1717
Nitrous oxide (N2O) is a strong green house effect gas and three-way catalyst is one of the major sources. N2O is mostly emitted at temperatures during the process of light off in the catalyst and the frequency of this temperature range over total temperature range distribution affects strongly on N2O emission. The effect of cold ambient on N2O emission was analyzed based on N2O-catalyst temperature characteristics and catalyst temperature data gained by road driving test at north part of Japan in winter. As results, N2O emission may drastically increase in colder cities and winter city traffic conditions.
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