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Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.

A quasi-dimensional computer simulation of the turbocharged spark-ignition engine has been developed in order to study system performance as various design parameters and operating conditions are varied. The simulation is of the “filling and emptying” type. Quasi-steady flow models of the compressor, intercooler, manifolds, turbine, wastegate, and ducting are coupled with a multi-cylinder engine model where each cylinder undergoes the same thermodynamic cycle. A turbulent entrainment model of the combustion process is used, thus allowing for studies of the effects of various combustion chamber shapes and turbulence parameters on cylinder pressure, temperature, NOx emissions and overall engine performance. Valve open areas are determined either based on user supplied valve lift data or using polydyne-generated cam profiles which allow for variable valve timing studies.

A study has been conducted in order to investigate the effect of the location of knock initiation on heat flux in a Spark-Ignition (SI) combustion chamber. Heat flux measurements were taken on the piston and cylinder head under different knock intensity levels, induced by advancing the spark timing. Tests were performed with two engine configurations, the first with the spark-plug located on the rear side of the chamber and the other having a second non-firing spark-plug placed at the front side of the chamber. The presence of the non-firing spark-plug consistently shifted the location of autoignition initiation from the surface of the piston to its vicinity, without causing a noticeable increase in knock intensity. By localizing the initiation of knock, changes induced in the secondary flame propagation pattern affected both the magnitude and the rate of change of peak heat flux under heavy knock.

This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.

Extending the operating range of the gasoline HCCI engine is essential for achieving desired fuel economy improvements at the vehicle level, and it requires deep understanding of the thermal conditions in the cylinder. Combustion chamber deposits (CCD) have been previously shown to have direct impact on near-wall phenomena and burn rates in the HCCI engine. Hence, the objectives of this work are to characterize thermal properties of deposits in a gasoline HCCI engine and provide foundation for understanding the nature of their impact on autoignition and combustion. The investigation was performed using a single-cylinder engine with re-induction of exhaust instrumented with fast-response thermocouples on the piston top and the cylinder head surface. The measured instantaneous temperature profiles changed as the deposits grew on top of the hot-junctions.

Naturally aspirated HCCI operation is typically limited to medium load operation (∼ 5 bar net IMEP) by excessive pressure rise rate. Boosting can provide the means to extend the HCCI range to higher loads. Recently, it has been shown that HCCI can achieve loads of up to 16.3 bar of gross IMEP by boosting the intake pressure to more than 3 bar, using externally driven compressors. However, investigating HCCI performance over the entire speed-load range with real turbocharger systems still remains an open topic for research. A 1 - D simulation of a 4 - cylinder 2.0 liter engine model operated in HCCI mode was used to match it with off-the-shelf turbocharger systems. The engine and turbocharger system was simulated to identify maximum load limits over a range of engine speeds. Low exhaust enthalpy due to the low temperatures that are characteristic of HCCI combustion caused increased back-pressure and high pumping losses and demanded the use of a small and more efficient turbocharger.

The number of control actuators available on spark-ignition engines is rapidly increasing to meet demand for improved fuel economy and reduced exhaust emissions. The added complexity greatly complicates control strategy development because there can be a wide range of potential actuator settings at each engine operating condition, and map-based actuator calibration becomes challenging as the number of control degrees of freedom expand significantly. Many engine actuators, such as variable valve actuation and flow control valves, directly influence in-cylinder combustion through changes in gas exchange, mixture preparation, and charge motion. The addition of these types of actuators makes it difficult to predict the influences of individual actuator positioning on in-cylinder combustion without substantial experimental complexity.

This paper reports the development of a model of diesel combustion and NO emissions, based on a modified eddy dissipation concept (EDC), and its implementation into the KIVA-3V multidimensional simulation. The EDC model allows for more realistic representation of the thin sub-grid scale reaction zone as well as the small-scale molecular mixing processes. Realistic chemical kinetic mechanisms for n-heptane combustion and NOx formation processes are fully incorporated. A model based on the normalized fuel mass fraction is implemented to transition between ignition and combustion. The modeling approach has been validated by comparison with experimental data for a range of operating conditions. Predicted cylinder pressure and heat release rates agree well with measurements. The predictions for NO concentration show a consistent trend with experiments. Overall, the results demonstrate the improved capability of the model for predictions of the combustion process.

Adjusting the Residual Gas Fraction (RGF) by means of Variable Valve Actuation (VVA) is a strong candidate for controlling the ignition timing in Homogeneous Charge Compression Ignition (HCCI) engines. However, at high levels of residual gas fraction, insufficient mixing can lead to the presence of considerable temperature and composition variations. This paper extends previous modeling efforts to include the effect of RGF distribution on the onset of ignition and the rate of combustion using a multi-dimensional fluid mechanics code (KIVA-3V) sequentially with a multi-zone code with detailed chemical kinetics. KIVA-3V is used to simulate the gas exchange processes, while the multi-zone code computes the combustion event. It is shown that under certain conditions the effect of composition stratification is significant and cannot be captured by a single-zone model or a multi-zone model using only temperature zones.

In this paper, a new method for cylinder pressure reconstruction is proposed based on the concept of a dimensionless pressure curve in the frequency domain. It is shown that cylinder pressure profiles, acquired over a wide range of engine speeds and loads, exhibit similarity. Hence, cylinder pressure traces collapse into a set of dimensionless curves within a narrow range after normalization in the frequency domain. The dimensionless pressure traces can be described by a curve-fit family, which can be used for reconstructing pressure diagrams back into the time domain at any desired condition. The accuracy associated with this method is analyzed and its application to engine heat transfer analysis is demonstrated.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

The present study introduces a modeling approach for investigating the effects of valve events and gas exchange processes in the framework of a full-cycle HCCI engine simulation. A multi-dimensional fluid mechanics code, KIVA-3V, is used to simulate exhaust, intake and compression up to a transition point, before which chemical reactions become important. The results are then used to initialize the zones of a multi-zone, thermo-kinetic code, which computes the combustion event and part of the expansion. After the description and the validation of the model against experimental data, the application of the method is illustrated in the context of variable valve actuation. It has been shown that early exhaust valve closing, accompanied by late intake valve opening, has the potential to provide effective control of HCCI combustion.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Modern diesel engines operate under injection pressures varying from 30 to 200 MPa and employ combinations of very early and conventional injection timings to achieve partially homogeneous mixtures. The variety of injection and cylinder pressures results in droplet atomization under a wide range of Weber numbers. The high injection velocities lead to fast jet disintegration and secondary droplet atomization under shear and catastrophic breakup mechanisms. The primary atomization of the liquid jet is modeled considering the effects of both infinitesimal wave growth on the jet surface and jet turbulence. Modeling of the secondary atomization is based on a combination of a drop fragmentation analysis and a boundary layer stripping mechanism of the resulting fragments for high Weber numbers. The drop fragmentation process is predicted from instability considerations on the surface of the liquid drop.

This paper describes the concept and a practical implementation of piston-compounding. First, a detailed computer simulation of the piston-compounded engine is used to shed light into the thermodynamic events associated with the operation of this engine, and to predict the performance and fuel economy of the entire system. Starting from a baseline design, the simulation is used to investigate changes in system performance as critical parameters are varied. The latter include auxiliary cylinder and interconnecting manifold volumes for a given main cylinder volume, auxiliary cylinder valve timings in relation to main cylinder timings, and degree of heat loss to the coolant. Optimum designs for either highest power density or highest thermal efficiency (54%) are thus recommended. It is concluded that a piston-compounded adiabatic engine concept is a promising future powerplant.

The finite volume, three-dimensional, turbulent flow code ARIS-3D is applied to the study of the complex flow field through the inlet port and within the cylinder of a uniflow-scavenged engine. The multiblock domain decomposition technique is used to accommodate this complex geometry. In this technique, the domain is decomposed into two blocks, one block being the cylinder and the other being the inlet duct. The effects of inlet duct length, geometric port swirl angle, and number of ports on swirl generating capability are explored. Trade-offs between swirl level and inherent pressure drop can thus be identified, and inlet port design can be optimized.

An early-design methodology for predicting both expected fuel economy and catalyst-out CO, HC and NOx concentrations during arbitrarily-defined transient cycles is presented. The methodology is based on utilizing a vehicle-powertrain model with embedded maps of fully warmed up engine-out performance and emissions, and appropriate temperature-dependent correction factors to account for not fully warmed up conditions during transients. Similarly, engine-out emissions are converted to catalyst-out emissions using conversion efficiencies based on the catalyst brick temperature. A crucial element of the methodology is hence the ability to predict heat flows and component temperatures in the engine and the exhaust system during transients, consistent with the data available during concept definition and early design phases.

Piston heat transfer measurements were taken under varying knock intensity in a modern spark-ignition engine combustion chamber. For a range of knocking spark timings, two knock intensity levels were obtained by using a high (80°C) and a low (50°C) cylinder head coolant temperature. Data were taken with a central and a side spark plug configuration. When the spark-plug was placed at the center of the combustion chamber, a linear variation of peak heat flux with knock intensity was found in the end-gas region. Very large changes in peak heat flux (on the order of 100%) occurred at probes whose relative location with respect to the end gas zone changed from being within (80°C coolant case) to being outside the zone (50°C coolant case). With side spark-plug, distinct differences in peak heat flux occurred at all probes and under all knock intensities, but the correlation between knock intensity and heat flux was not linear.