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Auto-ignition and combustion processes of dual-component fuel spray were numerically studied. A source code of SUPERTRAPP (developed by NIST), which is capable of predicting thermodynamic and transportation properties of pure fluids and fluid mixtures containing up to 20 components, was incorporated into KIVA3V to provide physical fuel properties and vapor-liquid equilibrium calculations. Low temperature oxidation reaction, which is of importance in ignition process of hydrocarbon fuels, as well as negative temperature coefficient behavior was taken into account using the multistep kinetics ignition prediction based on Shell model, while a global single-step mechanism was employed to account for high temperature oxidation reaction. Computational results with the present multi-component fuel model were validated by comparing with experimental data of spray combustion obtained in a constant volume vessel.

Fuel design concept has been proposed for low emission and combustion control in engine systems. In this concept, the multicomponent fuels, which are mixed with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components), are used for artificial control of fuel properties. In addition, these multicomponent fuels can easily lead to flash boiling which promote atomization and vaporization in the spray process. In order to understand atomization and vaporization process of multicomponent fuels in detail, the model for flash boiling spray of multicomponent fuel have been constructed and implemented into KIVA3V rel.2. This model considers the detailed physical properties and evaporation process of multicomponent fuel and the bubble nucleation, growth and disruption in a nozzle orifice and injected fuel droplets.

Diesel sprays injected into a combustion chamber of a small sized high-speed CI engine impinge surely on a piston surface and a cylinder wall. As a consequence, their vaporization, mixture formation and combustion processes are affected by impingement phenomena. And the other important factors affecting on the processes is the injection pressure. Then, the distribution of the vapor concentration in a single diesel spray impinging on a flat and hot wall was experimented by the exciplex fluorescence method, as a simple case. The injection pressure was varied in the range from 55 MPa to 120 MPa. It is found that the distribution of the vapor concentration in this case is much leaner than that in the case of the low injection pressure of 17.8MPa.

CNG is one of the future fuel for a CI engine. Recently, the general tendency is the use of the high pressure injection system over 100 MPa in a CI engine for the near future severe regulation. Combustion phenomenon in a CI engine with such injection system is like a transient gas diffusion flame. The flow in a gas diffusion flame was investigated by the particle image velocimetry on its 2-D images, the relative soot concentration, the temperature and the relative CO2 concentration was detected in the experiments. And the model of transient gas diffusion flame was constructed by use of experimental data.

Instantaneous and statistical spray structures of diesel sprays are examined with numerical simulation and experiment. KIVALES, which is LES version of KIVA code, is used as the computational code. Injection velocity profiles measured by momentum method are employed for the initial condition of the calculation. In the experiment, shadowgraph photography is performed to measure macroscopic spray structure. LES approach predicts the instantaneous structure, which are the heterogeneity and intermittency in the periphery of the spray and the cyclic variability of each injection event. Moreover, LES can predict both the instantaneous and statistical spray structures.

Three-dimensional large eddy simulation (LES) has been conducted for a diesel spray flame using KIVALES which is LES version of KIVA code. Modified TAB model, velocity interpolation model and rigid sphere model are used to improve the prediction of the fuel-mixture process in the diesel spray. Combustion is simulated using the Eddy-Dissipation model. CIP method was incorporated into the KIVALES in order to suppress the numerical instability on the combustible flow. The formation of soot and NO was simulated using Hiroyasu model and KIVA original model. Three different grid resolutions were used to examine the grid dependency. The result shows that the LES approach with 0.5 mm grid size is able to resolve the instantaneous spray with the intermittency in the spray periphery, the axi-symmetric shape and meandering flow after the end of injection as shown in the experimental results.

In this study, the purpose is placed in analysis the structure of diesel spray and, especially, making clear the mixture formation process in the evaporative diesel spray. The liquid fuel was injected from a single-hole nozzle (1/d = 1.0 mm/0.2 mm) into a constant-volume vessel possessing phenomena visualization under high pressure and temperature field. As for measurement method, in order to investigate liquid and vapor-phase of injected spray, exciplex fluorescence method was applied in the evaporative fuel spray. And the interested view region in injected spray is the downstream spray. For the minute investigation of spray flow, the liquid and vapor-phase region is taken with 35 mm still camera and CCD camera, respectively.

LES of non-evaporative diesel spray have been performed to investigate the effects of breakup models of Modified TAB, WAVE and KHRT model on computational results. KIVALES that is LES version of KIVA code was used for base code. In our KIVALES, CIP scheme was incorporated in order to suppress the numerical diffusion. Results showed that the breakup model is significantly affected on the calculated spray shape, because the droplet diameter determined by breakup models affects on the transmittance of the droplet momentum into the ambient gas, the evolution of the vortex structure in the gas phase and the droplet dispersion by the vortex structure.

The maximum liquid-phase penetration and vaporization behavior was investigated by using simultaneous measurement for mie-scattered light images and shadowgraph ones. The objective of this study was to analyze effect of variant parameters (injection pressure, ambient gas condition and fuel temperature) and fuel properties on vaporization behavior, and to investigate liquid phase penetration for the single- and multi-component fuels. The experiments were conducted in a constant-volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector.

This work investigates the soot formation process in diesel jet flame using a detailed kinetic soot model implemented into the KIVA-3V multidimensional CFD code and 2D imaging by use of time-resolved laser induced incandescence (LII). The numerical model is based on the KIVA code which is modified to use CHEMKIN as the chemistry solver using Message Passing Interface (MPI). This allows for the chemical reactions to be simulated in parallel on multiple CPUs. The detailed soot model used is based on the method of moments, which begins with fuel pyrolysis, followed by the formation of polycyclic aromatic hydrocarbons, their growth and coagulation into spherical particles, and finally, surface growth and oxidation of the particles. The model can describe the spatial and temporal characteristics of soot formation processes such as soot precursors distributions, nucleation rate and surface reaction rate.

This study proposes a hybrid model which consists of modified TAB(Taylor Analogy Breakup) model and DVM(Discrete Vortex Method). In this study, the simulation process is divided into three steps. The first step is to analyze the breakup of droplet of injected fuel by using modified TAB model. The second step based on the theory of Siebers' liquid length is analysis of spray evaporation. The liquid length analysis of injected fuel is used for connecting both modified TAB model and DVM. The final step is to reproduce the ambient gas flow and inner vortex flow injected fuel by using DVM. In order to examine the hybrid model, an experiment of a free evaporating fuel spray at early injection stage of in-cylinder like conditions had been executed. The numerical results calculated by using the present hybrid model are compared with the experimental ones.

This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.

It is significant for understanding the phenomena in a stratified charge engine and an SI engine with direct injection system to carry out the fundamental research. The experiments were conducted in a constant volume chamber with atmospheric condition. The pre-mixed charge composed of ethylene and air was charged with various equivalence ratio, the second charge with the same composition was injected into the chamber, thereafter, the combustion started by a spark plug. The phenomena were analyzed by use of the experimental results of shadowgraph, [OH] natural emission, pressure history and NOx and UHC in the exhaust gas.

This paper provides new insights on the mechanism of the smokeless diesel combustion with oxygenated fuels, based on a combination of soot kinetic modeling and optical diagnostics. The chemical effects of fuel compositions, including aromatics - paraffins blend, neat oxygenated fuels and oxygenate additives, on sooting equivalence ratio ‘ϕ’ - temperature ‘T’ dependence were numerically examined using a detailed soot kinetic model. To better understand the physical factors affecting soot formation in oxygenated fuel sprays, the effects of injection pressure and ambient gas temperature on the flame lift-off length and relative soot concentration in oxygenated fuel jets were experimentally investigated. The computational results show that the leaner mixture side of soot formation peninsula on the ϕ - T map, rather than the lower temperature one, should be utilized to suppress the formation of PAHs and ultra-fine particles together with the large reduction in particulate mass.

The experiment-based droplet impinging breakup model was applied to a fan shaped spray and the impinging behavior was analyzed quantitatively. Evaluation of the quantitative results with validation tests verified the following. The model enables prediction of fan shaped spray thickness after impingement caused by the breakup of fuel droplets, which could not be represented with the Wall-Jet model, widely used at present. Fuel film movement on a wall is negligible when the injection pressure of the fan shaped spray is high and the spray travelling length is not too short. The proposed heat transfer coefficient between fuel film and the wall is too small to represent the vaporizing rate of the fuel film.

It is unavoidable that a DI diesel engine exhausts a blue and white smoke at starting, especially in the cold atmosphere. In the experiments presented here, a small DI diesel engine started under the conditions of coolant and suction air whose minimum temperatures were 255 K and 268 K, respectively. The flame was photographed by high-speed photography, the temperature of flame and the soot concentration were measured by two-color method, and CO2 concentration was detected by luminous method. The engine cannot be started over several cycles when the coolant temperature is 255 K and suction air temperature is 268 K. As the temperature of coolant and suction air are decreasing, the maxima of the cylinder pressure, the flame temperature, the soot concentration and CO2 concentration are decreasing. Luminous small dots or small lumps of flame become scattered in the piston cavity.

There is a concept that the increase in the temperature of charge in a combustion chamber and the shield of heat transferred through a chamber wall can facilitate the oxidation of soot and reduce the discharge of soot from the engine. In the experiments presented here in, an IDI diesel engine was used to inspect the concept. The engine was installed a bigger sized cylindrical swirl chamber which was equipped with two flat quarts windows, in order to observe the combustion phenomena and to apply the optical measurement. The experiments were carried out using two types of divided chambers, that is, the swirl chamber made of ceramics and that made of steel, to examine the the effects mentioned above.

In this study, a rapid compression and expansion machine(RCEM) with a pancake combustion chamber was designed to investigate fundamentally on the knocking phenomena in spark ignition(S.I) engines. This RCEM is intended to simulate combustion in an actual engine. The homogeneous pre-mixture of n-pentane and air was charged into a quiescent atmosphere of the chamber. Then, the combustion field become simpler in this machine than it in a real S.I. engine. Also, the combustion phenomena, that is a cylinder pressure history, the behavior of flame propagation and so on, with high reproducibility are realized in this machine. The phenomena caught in this experiment were so-called low speed knocking. And, this knocking characteristics such as a knock intensity and a knock mass fraction were revealed by the cylinder pressure analysis varying the charge pressure and the equivalence ratio of the mixture, a compression ratio and an ignition timing.

This paper presents an atomization mechanism of a spray injected into the low-pressure field, as the subject of injection system in a suction manifold of gasoline engine. Pure liquid fuel, which is n-Pentane or n-Hexane is injected into quiescent gaseous atmosphere at room-temperature and low- pressure through pintle type electronic control injector. Fuel sprays are observed by taking photographs for variation of the back pressure and the changes in spray characteristics with the back pressure below atmospheric pressure are examined in detail. In particular, in the case of the back pressure below the saturated vapor pressure of fuel, the atomization mechanism is discussed from a viewpoint of flash boiling phenomena, those are bubble growth rate and so on.

Large Eddy Simulation (LES) is applied to non-evaporative and evaporative diesel spray simulations. KIVALES, which is LES version of KIVA code, is used as the LES computational code. Modified TAB model is used as breakup model, and interpolated donor cell differencing scheme is employed to calculate convective terms. To validity LES simulation, LES results using KIVALES are compared with experimental results and simulated results with conventional RANS approach using KIVA3V res.2. The results show that the LES simulation of non-evaporative spray depends on the grid size in comparison with RANS simulation, and good agreement is obtained between experimental results and the LES results with fine grid (720,000 cells). Furthermore, asymmetric non-evaporative spray which has intermittency at the outer edge of sprays is simulated, since instantaneous turbulent flow field can be predicted directly in LES case.