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The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.

The combustion and exhaust emission characteristics of a DME fueled HCCI engine were investigated. Different fuel injection strategies were tested under various injection quantities and timings with exhaust gas recirculation (EGR). The combustion phase in HCCI was changed by an in-cylinder direct injection and EGR, due to changes in the in-cylinder temperature and mixture homogeneity. The gross indicated mean effective pressure (IMEPgross) increased and the hydrocarbon (HC) and carbon monoxide (CO) emissions decreased as the equivalence ratio was augmented. The IMEPgross with direct injection was greater than with the port injection due to retarded ignition timing resulting from latent heat of direct injected DME fuel. It was because that most of burn duration was completed before top dead center owing to higher ignitability for DME with high cetane number. However, HC and CO emissions were similar for both injection locations.

Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.

Direct injection of natural gas under high pressure conditions has emerged as a promising option for improving engine fuel economy and emissions. However, since the gaseous injection technology is new, limited experience exists as to the optimum configuration of the injection system and associated combustion chamber design. The present study uses KIVA-3 based, multidimensional modeling to improve the understanding and assist the optimization of the gaseous injection process. Compared to standard k-ε models, a Renormalization Group Theory (RNG) based k-ε model [1] has been found to be in better agreement with experiments in predicting gaseous penetration histories for both free and confined jet configurations. Hence, this validated RNG model is adopted here to perform computations in realistic engine geometries.

A detailed chemical kinetic mechanism, consisting of 22 species and 104 elementary reactions, has been used in conjunction with the multi-dimensional reactive flow code KIVA-3 to study autoignition of natural gas injected under compression ignition conditions. Calculations for three different blends of natural gas are performed on a three-dimensional computational grid by modeling both the injection and ignition processes. Ignition delay predictions at pressures and temperatures typical of top-dead-center conditions in compression ignition engines compare well with the measurements of Naber et al. [1] in a combustion bomb. Two different criteria, based on pressure rise and mass of fuel burned, are used to detect the onset of ignition. Parametric studies are conducted to show the effect of additives like ethane and hydrogen peroxide in increasing the fuel consumption rate.

The combustion, knock characteristics and exhaust emissions in an engine were investigated under homogeneous charge compression ignition operation fueled with liquefied petroleum gas with regard to variable valve timing and the addition of di-methyl ether. Liquefied petroleum gas was injected at an intake port as the main fuel in a liquid phase using a liquefied injection system, while a small amount of di-methyl ether was also injected directly into the cylinder during the intake stroke as an ignition promoter. Different intake valve timings and fuel injection amount were tested in order to identify their effects on exhaust emissions, combustion and knock characteristics. The optimal intake valve open timing for the maximum indicated mean effective pressure was retarded as the λTOTAL was decreased. The start of combustion was affected by the intake valve open timing and the mixture strength (λTOTAL) due to the volumetric efficiency and latent heat of vaporization.

A naturally-aspirated, Miller cycle, Spark-Ignition (SI) engine that controls output with variable intake valve closure is compared to a conventionally-throttled engine using computer simulation. Based on First and Second Law analyses, the two load control strategies are compared in detail through one thermodynamic cycle at light load conditions and over a wide range of loads at 2000 rpm. The Miller Cycle engine can use late intake valve closure (LIVC) to control indicated output down to 35% of the maximum, but requires supplemental throttling at lighter loads. The First Law analysis shows that the Miller cycle increases indicated thermal efficiency at light loads by as much as 6.3%, primarily due to reductions in pumping and compression work while heat transfer losses are comparable.

This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.

Dimethyl ether (DME) as a high cetane number fuel and liquefied petroleum gas (LPG) as a high octane number fuel were supplied together to evaluate the controllability of combustion phase and improvement of power and exhaust emission in homogeneous charge compression ignition (HCCI) engine. Each fuel was injected at the intake port and in the cylinder separately during the same cycle, i.e., DME in the cylinder and LPG at the intake port, or vice versa. Direct injection timing was varied from 200 to 340 crank angle degree (CAD) while port injection timing was fixed at 20 CAD. In general, the experimental results showed that DME direct injection with LPG port injection was the better way to increase the IMEP and reduce emissions. The direct injection timing of high cetane number fuel was important to control the auto-ignition timing because the auto-ignition was occurred at proper area, where the air and high cetane number fuel were well mixed.

The effect of the composition of propane (C₃H₈) and butane (C₄H₁₀) in liquefied petroleum gas (LPG) was investigated in a dual-fuel HCCI engine fueled with di-methyl ether (DME) and LPG. The composition of LPG affects DME-LPG dual fuel HCCI combustion due to the difference in the physical properties of propane that and butane such as octane number, auto-ignition temperature and heat of vaporization. DME was injected directly into the cylinder at various injection timing from 160 to 350 crank angle degrees (CAD). LPG was injected at the intake port with a fixed injection timing at 20 CAD. It was found that power output was increased with propane ratio. This gain in power output resulted from increased expansion work due to the better anti-knock properties of propane. However, higher propane ratio made combustion efficiency decrease because of the suppression in low temperature reaction of DME which determines heat release amount of high temperature reaction.

Combustion and flame propagation characteristics of the liquid phase LPG injection (LPLI) engine were investigated in a single cylinder optical engine. Lean burn operation is needed to reduce thermal stress of exhaust manifold and engine knock in a heavy duty LPG engine. An LPLI system has advantages on lean operation. Optimized engine design parameters such as swirl, injection timing and piston geometry can improve lean burn performance with LPLI system. In this study, the effects of piston geometry along with injection timing and swirl ratio on flame propagation characteristics were investigated. A series of bottom-view flame images were taken from direct visualization using a UV intensified high-speed CCD camera. Concepts of flame area speed, in addition to flame propagation patterns and thermodynamic heat release analysis, was introduced to analyze the flame propagation characteristics.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

Dimethyl Ether (DME) has been considered as one of the most attractive alternative fuels for compression ignition engine. Its main advantage in compression-ignition engine application is high efficiency of diesel cycle with soot free combustion though conventional fuel injection system has to be modified due to the intrinsic properties of the DME. Experimental study of the DME and conventional diesel spray employing a common-rail type fuel injection system with a sac type injector was performed in a constant volume vessel pressurized by nitrogen gas. A CCD camera was employed to capture time series of spray images, so that spray cone angles and penetrations of the DME spray were characterized and compared with those of diesel. Intermittent hesitating DME spray appeared at injection pressures of 25MPa and 40MPa in both atmospheric and 3MPa chamber pressures.

This work reports the development and application of multi-dimensional ignition, combustion and emissions models that account for detailed chemistry and mixing effects in a direct injection engine simulation. A detailed chemical reaction mechanism, consisting of 24 species and 104 reactions, is used for increased accuracy of emissions predictions. Turbulent combustion is represented using a modified Eddy Dissipation Concept (EDC) model to account for mixing effects. The soot model includes all aspects of soot formation and destruction. Particle transport equations are used to realistically track transport of the soot particles formed. All computational sub-models developed in this work have been implemented in a modified version of the KIVA-3V code. In order to illustrate the behavior of the new models, soot and NO emissions have been predicted at different operating conditions by varying injection timing, exhaust gas recirculation (EGR) and injection pressure.

To investigate the mixture distributions in an LPG engine with Liquid phase port injection for heavy duty vehicles, an optical single cylinder engine, which is optically accessible both in side and bottom view, and laser diagnostic system were incorporated to apply PLIF (planar laser induced fluorescence) technique. Acetone was used as a dopant in LPG fuel, which was excited by KrF excimer laser (248nm), and its fluorescence images were acquired with ICCD camera. The effects of fuel injection timing, swirl intensity and excess air ratio were investigated. For the case of open valve injection, favorable stratification of fuel, both in axial and radial direction, was clearly observed compared to the closed valve injection, where reverse stratification in axial direction was observed. At the Ricardo swirl ratio of 3.4, it was apparent that excessive axial stratification of fuel got dominant, which would lead to poor engine performances.

Submodels are developed for injection, evaporation and wall impingement of a liquid LPG spray. The injection model determines the quality of fuel as two-phase choke flow at the nozzle exit. Wind tunnel experiments show the spray penetration more sensitive to ambient flow velocity than to injection pressure. Most evaporation occurs during choking, while heat transfer from surrounding air has a negligible effect on downstream droplet sizes. Three dimensional simulation shows that the bathtub cavity is better than the dog-dish cavity for stable flame propagation in lean-burn conditions. The injection timing during the IVC period has a negligible effect, while injection during an intake stroke enhances fuel/air mixing to result in more homogeneous cylinder charge.

In this study, macroscopic spray characteristics of Waste cooking oil (WCO), Jatropha oil, Karanja oil based biodiesels and baseline diesel were compared under simulated engine operating condition in a constant volume spray chamber (CVSC). The high pressure and high temperature ambient conditions of a typical diesel engine were simulated in the CVSC by performing pre-ignition before the fuel injection. The spray imaging was conducted under absence of oxygen in order to prevent the fuels from igniting. The ambient pressure and temperature for non-evaporating condition were 3 MPa and 300 K. Meanwhile, the spray tests were performed under the ambient pressure and temperature of 4.17 MPa and 804 K under evaporating condition. The fuels were injected by a common-rail injection system with injection pressure of 80 MPa. High speed Mie-scattering technique was employed to visualize the evaporating sprays.

Fuel atomization and air-fuel mixing processes play a dominant role on engine performance and emission characteristics in a direct injection compression ignition engine. Understanding of microscopic spray characteristics is essential to predict combustion phenomena. The present work investigated near nozzle flow and atomization characteristics of biodiesel fuels in a constant volume chamber. Waste cooking oil, Jatropha, and Karanja biodiesels were applied and the results were compared with those of conventional diesel fuel. The tested fuels were injected by a solenoid injector with a common-rail injection system. A high-speed camera with a long distance microscopic lens was utilized to capture the near nozzle flow. Meanwhile, Sauter mean diameter (SMD) was measured by a phase Doppler particle analyzer to compare atomization characteristics.

The compression ignition combustion fuelled with hydrogen and dimethyl-ether was investigated. Exhaust gas recirculation was applied to reduce noise and nitrogen oxide (NOx) emission. When dimethyl-ether was injected earlier, combustion showed two-stage ignitions known as low temperature reaction and high temperature reaction. With advanced dimethyl-ether injection, combustion temperature and in-cylinder pressure rise were lowered which resulted in high carbon monoxide and hydrocarbon emissions. However, NOx emission was decreased due to relatively low combustion temperature. The engine combustion showed only high temperature reaction when dimethyl-ether was injected near top dead center. When exhaust gas recirculation gas was added, the in-cylinder pressure and heat release rate were decreased. However, it retarded combustion phase resulting in higher indicated mean effective pressure.