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This study was conducted to investigate the influence of low-temperature reactions on the Homogeneous Charge Compression Ignition (HCCI) combustion process. Specifically, an investigation was made of the effect of the residual gas condition on low-temperature reactions, autoignition and the subsequent state of combustion following ignition. Light emission and absorption spectroscopic measurements were made in the combustion chamber in order to investigate low-temperature reactions in detail. In addition, chemical kinetic simulations were performed to validate the experimental results and to analyze the elemental reaction process. The results made clear the formation behavior of the chemical species produced during low-temperature HCCI reactions.

The Homogenous Charge Compression Ignition (HCCI) engine is positioned as a next-generation internal combustion engine and has been the focus of extensive research in recent years to develop a practical system. One reason is that this new combustion system achieves lower fuel consumption and simultaneous reductions of nitrogen oxide (NOx) and particulate matter (PM) emissions, which are major issues of internal combustion engines today. However, the characteristics of HCCI combustion can prevent suitable engine operation owing to the rapid combustion process that occurs accompanied by a steep pressure rise when the amount of fuel injected is increased to obtain higher power output. A major issue of HCCI is to control this rapid combustion so that the quantity of fuel injected can be increased for greater power. Controlling the ignition timing is also an issue because it is substantially influenced by the chemical reactions of the fuel.

In this study, optical measurements were made of the combustion chamber gas during operation of a Homogeneous Charge Compression Ignition (HCCI) engine in order to obtain a better understanding of the ignition and combustion characteristics. The principal issues of HCCI engines are to control the ignition timing and to optimize the combustion state following ignition. Autoignition in HCCI engines is strongly influenced by the complex low-temperature oxidation reaction process, alternatively referred to as the cool flame reaction or negative temperature coefficient (NTC) region. Accordingly, a good understanding of this low-temperature oxidation reaction process is indispensable to ignition timing control. In the experiments, spectroscopic measurement methods were applied to investigate the reaction behavior in the process leading to autoignition.

Combustion experiments were conducted with an optically accessible engine that allowed the entire bore area to be visualized for the purpose of making clear the characteristics that induce extremely rapid HCCI combustion and knocking accompanied by cylinder pressure oscillations. The HCCI combustion regime was investigated in detail by high-speed in-cylinder visualization of autoignition and combustion and emission spectroscopic measurements. The results revealed that increasing the equivalence ratio and advancing the ignition timing caused the maximum pressure rise rate and knocking intensity to increase. In moderate HCCI combustion, the autoignited flame was initially dispersed temporally and spatially in the cylinder and then gradually spread throughout the entire cylinder.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted much interest as a combustion system that can achieve both low emissions and high efficiency. But the operating region of HCCI combustion is narrow, and it is difficult to control the auto-ignition timing. This study focused on the use of a two-component fuel blend and supercharging. The blended fuel consisted of dimethyl ether (DME), which has attracted interest as alternative fuel for compression-ignition engines, and methane, the main component of natural gas. A spectroscopic technique was used to measure the light emission of the combustion flame in the combustion chamber in order to ascertain the combustion characteristics. HCCI combustion characteristics were analyzed in detail in the present study by measuring this light emission spectrum.

The Homogenous Charge Compression Ignition (HCCI) engine is positioned as a next-generation internal combustion engine and has been the focus of extensive research in recent years to develop a practical system. One reason is that this new combustion system achieves lower fuel consumption and simultaneous reductions of nitrogen oxide (NOx) and particulate matter (PM) emissions, which are major issues of internal combustion engines today. However, the characteristics of HCCI combustion can prevent suitable engine operation owing to the rapid combustion process that occurs accompanied by a steep pressure rise when the amount of fuel injected is increased to obtain higher power output. A major issue of HCCI is to control this rapid combustion so that the quantity of fuel injected can be increased for greater power. Controlling the ignition timing is also an issue because it is substantially influenced by the chemical reactions of the fuel.

In this study, experiments were conducted using a blend of two types of fuel with different ignition characteristics. One was dimethyl ether (DME) that has a high cetane number, autoignites easily and displays low-temperature oxidation reaction mechanisms; the other was methane that has a cetane number of zero and does not autoignite easily. A mechanically driven supercharger was provided in the intake pipe to adjust the intake air pressure. Moreover, flame light in the combustion chamber was extracted using a system for observing light emission that occurred in the space between the cylinder head and the cylinder and in the bore direction of the piston crown. The results of previous studies conducted with a supercharged HCCI engine and a blended fuel of DME and methane have shown that heat release of the hot flame is divided into two stages and that combustion can be moderated by reducing the peak heat release rate (HRR).

This study clarified the influence of hot gas jet on combustion enhancement effect for lean mixture in the plasma jet ignition. The hot gas jet was generated by the high temperature plasma and was ejected from igniter after plasma jet finished issuing. In combustion tests, propane-air mixture at equivalence ratio of 0.6 was used and the mixture was filled in the combustion chamber at atmosphere pressure and room temperature. For generation of the hot gas jet, the standard air was filled in chamber at same conditions and the hot gas jet was visualized by schlieren method in the absence of combustion. The combustion development processes were also visualized and the combustion pressure was measured. The discharge voltage, discharge current and the plasma luminescence were also measured. The plasma luminescence disappeared within 0.05 ms for any experimental conditions. When cavity depth was deep and orifice diameter was small, the maximum plasma luminescence height was short.

In this study, it was shown that Homogeneous Charge Compression Ignition (HCCI) combustion in a 4-stroke engine, operating under the conditions of a high compression ratio, wide open throttle (WOT) and a lean mixture, could be simulated by raising the compression ratio of a 2-stroke engine. On that basis, a comparison was then made with the characteristics of Active Thermo-Atmosphere Combustion (ATAC), the HCCI process that is usually accomplished in 2-stroke engines under the conditions of a low compression ratio, partial throttle and a large quantity of residual gas. One major difference observed between HCCI combustion and ATAC was their different degrees of susceptibility to the occurrence of cool flames, which was attributed to differences in the residual gas state. It was revealed that the ignition characteristics of these two combustion processes differed greatly in relation to the fuel octane number.

In plasma jet ignition, combustion enhancement effects are caused toward the plasma jet issuing direction. Therefore, when the igniter is attached at the center of cylindrically shaped combustion chamber, the plasma jet should issues toward the round combustion chamber wall. The plasma jet igniter that had a concentric circular orifice has been developed. It is expected that the plasma jet is issued and is diffused from concentric circular orifice toward the combustion chamber wall. Relationship between plasma jet and igniter configuration was experimentally clarified. Plasma jet can issue from the entire concentric circular orifice for some igniter. Plasma jet is extended with increasing concentric circular orifice area. Plasma jet penetration increases with increasing concentric circular orifice width.

The uniform lean gasoline-air mixture was provided to diesel engine and was ignited by direct diesel fuel injection. The mixing region that is formed by diesel fuel penetration and entrainment of ambient mixture is regarded as combustible turbulent jet. The ignition occurs in this region and the ambient lean mixture is burned by flame propagation. The lean mixture of air-fuel ratio between 150 and 35 could be ignited and burned by this ignition method. An increase of diesel fuel injection is effective to ensure combustion and ignition. As diesel fuel injection increases, HC concentration decreases, and NOx and CO concentration increases.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. The internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the mixture temperature. The test engine was a 4-stroke, single- cylinder direct-injection diesel engine. The cooling system was forced-air cooling and displacement volume was about 211 (cm3). The compression ratio was about 19.9:1. The experiment was made under constant engine speed of 3000 (r/min). The boost pressure was maintained at 101.3 (kPa). Five values of mass flow rate of diesel fuel injection were selected from 0.060 (g/s) to 0.167 (g/s) and five levels of back pressure: 0), 26.7, 53.3, 80.0 and 106.6 (kPa) were selected for the experiment. The effect of internal EGR is varied by the back pressure level.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.

A new concept of combustion which is using the characteristic of plasma jet ignition, that is the plasma jet diffusive combustion is proposed. The constant volume vessel is used for the experiment, and methanol is charged in the cavity of plasma jet injector and the air at room temperature and atmospheric pressure is charged in the combustion chamber. The combustion characteristic is analyzed by measuring the combustion pressure and visualization of the combustion process. The plasma jet injector configuration and the ratio of methanol volume to cavity volume influence not only the plasma jet diffusive combustion process but also the maximum combustion pressure. In cases of small orifice diameter, the plasma jet diffusive combustion is not recognized, and the maximum combustion pressure increases as the orifice area becomes large.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

The purpose of this study is to clarify ignition characteristics and engine performance of FAME for 4-stroke diesel engine in low compression ratios. Diesel fuel and coconut oil methyl ester (CME) were selected as test fuels, because CME consisted of saturate FAMEs which were good ignition characteristics. To reduce the compression ratio, thin copperplates were inserted between cylinder head and cylinder block and the compression ratio was reduced from 20.6 that was standard to 15. The engine starting test and an ordinary engine performance test were made at 3600 min.-₁. In engine starting test, the engine was soaked at room temperature and the ignition timing of diesel fuel was remarkably delayed compared with CME. When the compression ratio was 16, for diesel fuel, the misfiring cycles were included during engine warming up. In case of 15 of compression ratio, the engine could not be started by diesel fuel; however the engine could be run by CME.

The investigation regarding performance of plasma jet igniters was explored by using a constant volume vessel. This study focused on investigating the relationship between the jet effect, the hot gas jet issued from the igniter, and combustion enhancement. The hot gas penetration was visualized by the schlieren system with CCD camera and image intensifier. In the cases of small energies, 0.63 and 0.90 J, the combustion enhancement effect is similar to that of combustion jet igniter. In cases of supplied energies, 2.45 and 5.00 J, the jet effect influences on the combustion enhancement effect for small characteristic length of the igniter.

Using absorption spectroscopy, simultaneous measurements were made of the behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2(516.5 nm) radicals in the end-gas region and center of the combustion chamber of a spark-ignition engine during preflame reactions with four types of fuel having different octane numbers. The results of this research show that the behavior of the OH, CH and C2 radicals in preflame reactions differed significantly in both the center and end-gas region of the combustion chamber depending on the octane number of the fuel and also between normal and knocking combustion conditions.