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This study was conducted to investigate the influence of low-temperature reactions on the Homogeneous Charge Compression Ignition (HCCI) combustion process. Specifically, an investigation was made of the effect of the residual gas condition on low-temperature reactions, autoignition and the subsequent state of combustion following ignition. Light emission and absorption spectroscopic measurements were made in the combustion chamber in order to investigate low-temperature reactions in detail. In addition, chemical kinetic simulations were performed to validate the experimental results and to analyze the elemental reaction process. The results made clear the formation behavior of the chemical species produced during low-temperature HCCI reactions.

The Homogenous Charge Compression Ignition (HCCI) engine is positioned as a next-generation internal combustion engine and has been the focus of extensive research in recent years to develop a practical system. One reason is that this new combustion system achieves lower fuel consumption and simultaneous reductions of nitrogen oxide (NOx) and particulate matter (PM) emissions, which are major issues of internal combustion engines today. However, the characteristics of HCCI combustion can prevent suitable engine operation owing to the rapid combustion process that occurs accompanied by a steep pressure rise when the amount of fuel injected is increased to obtain higher power output. A major issue of HCCI is to control this rapid combustion so that the quantity of fuel injected can be increased for greater power. Controlling the ignition timing is also an issue because it is substantially influenced by the chemical reactions of the fuel.

In this study, optical measurements were made of the combustion chamber gas during operation of a Homogeneous Charge Compression Ignition (HCCI) engine in order to obtain a better understanding of the ignition and combustion characteristics. The principal issues of HCCI engines are to control the ignition timing and to optimize the combustion state following ignition. Autoignition in HCCI engines is strongly influenced by the complex low-temperature oxidation reaction process, alternatively referred to as the cool flame reaction or negative temperature coefficient (NTC) region. Accordingly, a good understanding of this low-temperature oxidation reaction process is indispensable to ignition timing control. In the experiments, spectroscopic measurement methods were applied to investigate the reaction behavior in the process leading to autoignition.

Combustion experiments were conducted with an optically accessible engine that allowed the entire bore area to be visualized for the purpose of making clear the characteristics that induce extremely rapid HCCI combustion and knocking accompanied by cylinder pressure oscillations. The HCCI combustion regime was investigated in detail by high-speed in-cylinder visualization of autoignition and combustion and emission spectroscopic measurements. The results revealed that increasing the equivalence ratio and advancing the ignition timing caused the maximum pressure rise rate and knocking intensity to increase. In moderate HCCI combustion, the autoignited flame was initially dispersed temporally and spatially in the cylinder and then gradually spread throughout the entire cylinder.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted much interest as a combustion system that can achieve both low emissions and high efficiency. But the operating region of HCCI combustion is narrow, and it is difficult to control the auto-ignition timing. This study focused on the use of a two-component fuel blend and supercharging. The blended fuel consisted of dimethyl ether (DME), which has attracted interest as alternative fuel for compression-ignition engines, and methane, the main component of natural gas. A spectroscopic technique was used to measure the light emission of the combustion flame in the combustion chamber in order to ascertain the combustion characteristics. HCCI combustion characteristics were analyzed in detail in the present study by measuring this light emission spectrum.

The Homogenous Charge Compression Ignition (HCCI) engine is positioned as a next-generation internal combustion engine and has been the focus of extensive research in recent years to develop a practical system. One reason is that this new combustion system achieves lower fuel consumption and simultaneous reductions of nitrogen oxide (NOx) and particulate matter (PM) emissions, which are major issues of internal combustion engines today. However, the characteristics of HCCI combustion can prevent suitable engine operation owing to the rapid combustion process that occurs accompanied by a steep pressure rise when the amount of fuel injected is increased to obtain higher power output. A major issue of HCCI is to control this rapid combustion so that the quantity of fuel injected can be increased for greater power. Controlling the ignition timing is also an issue because it is substantially influenced by the chemical reactions of the fuel.

In this study, experiments were conducted using a blend of two types of fuel with different ignition characteristics. One was dimethyl ether (DME) that has a high cetane number, autoignites easily and displays low-temperature oxidation reaction mechanisms; the other was methane that has a cetane number of zero and does not autoignite easily. A mechanically driven supercharger was provided in the intake pipe to adjust the intake air pressure. Moreover, flame light in the combustion chamber was extracted using a system for observing light emission that occurred in the space between the cylinder head and the cylinder and in the bore direction of the piston crown. The results of previous studies conducted with a supercharged HCCI engine and a blended fuel of DME and methane have shown that heat release of the hot flame is divided into two stages and that combustion can be moderated by reducing the peak heat release rate (HRR).

This study focused on the use of a two-component fuel blend and supercharging as possible means of overcoming these issues of HCCI combustion. Low-carbon gaseous fuels with clean emissions were used as the test fuels. The specific fuels used were dimethyl ether (DME, cetane number of 55 or higher) that autoignites easily And exhibits pronounced low-temperature oxidation reactions, methane (cetane number of 0) that does not autoignite readily and is the main component of natural gas which is regarded as petroleum substitute, and propane (cetane number of 5) that is a principal component of liquefied petroleum gas. The results of previous investigations have shown that the use of a blended fuel of DME and methane produces a two-stage main combustion process under certain operating conditions, with the result that combustion is moderated.

In this study, it was shown that Homogeneous Charge Compression Ignition (HCCI) combustion in a 4-stroke engine, operating under the conditions of a high compression ratio, wide open throttle (WOT) and a lean mixture, could be simulated by raising the compression ratio of a 2-stroke engine. On that basis, a comparison was then made with the characteristics of Active Thermo-Atmosphere Combustion (ATAC), the HCCI process that is usually accomplished in 2-stroke engines under the conditions of a low compression ratio, partial throttle and a large quantity of residual gas. One major difference observed between HCCI combustion and ATAC was their different degrees of susceptibility to the occurrence of cool flames, which was attributed to differences in the residual gas state. It was revealed that the ignition characteristics of these two combustion processes differed greatly in relation to the fuel octane number.

In this study, light emission and absorption spectroscopic measurement techniques were used to investigate the Homogeneous Charge Compression Ignition (HCCI) combustion process in detail, about which there have been many unclear points heretofore. The results made clear the formation behavior and wavelength bands of the chemical species produced during low-temperature reactions. Specifically, with a low level of residual gas, a light emission band was observed from a cool flame in a wavelength range of 370–470 nm. That is attributed to the light emission of formaldehyde (HCHO) produced in the cool-flame reactions. Additionally, it was found that these light emission spectra were no longer observable when residual gas was applied. The light emission spectra of the combustion flame thus indicated that residual gas has the effect of moderating cool-flame reactions.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

This study examined the effects of fuel composition and intake pressure on two-stage high temperature heat release characteristics of a Homogeneous Charge Compression Ignition (HCCI) engine. Light emission and absorption spectroscopic measurement techniques were used to investigate the combustion behavior in detail. Chemical kinetic simulations were also conducted to analyze the reaction mechanisms in detail. Blended fuels of dimethyl ether (DME) and methane were used in the experiments. It was found that the use of such fuel blends together with a suitable intake air flow rate corresponding to the total injected heat value gave rise to two-stage heat release behavior of the hot flame, which had the effect of moderating combustion. The results of the spectroscopic measurements and the chemical kinetic simulations revealed that the main reaction of the first stage of the hot flame heat release was one that produced CO from HCHO.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted considerable interest in recent years as a new combustion concept for internal combustion engines. On the other hand, two combustion concepts proposed for two-cycle spark-ignition (SI) engines are Active Thermo-Atmosphere Combustion (ATAC) and Activated Radical (AR) combustion. The authors undertook this study to examine the similarities and differences between HCCI combustion and ATAC (AR) combustion. Differences in the low-temperature oxidation reaction behavior between these two combustion processes were made clear using one test engine.

Using absorption spectroscopy, simultaneous measurements were made of the behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2(516.5 nm) radicals in the end-gas region and center of the combustion chamber of a spark-ignition engine during preflame reactions with four types of fuel having different octane numbers. The results of this research show that the behavior of the OH, CH and C2 radicals in preflame reactions differed significantly in both the center and end-gas region of the combustion chamber depending on the octane number of the fuel and also between normal and knocking combustion conditions.

Homogenous Charge Compression Ignition (HCCI) combustion experiments were conducted in this study using a single-cylinder test engine fitted with a sapphire observation window to facilitate visualization of the entire cylinder bore area. In addition to in-cylinder visualization of combustion, spectroscopic measurements were made of light emission and absorption in the combustion chamber to investigate autoignition behavior in detail. Engine firing experiments were conducted to visualize HCCI combustion over a wide range of compression ratios from 12:1 to 22:1. The results showed that increasing the compression ratio advanced the ignition timing and increased the maximum pressure rise rate, making it necessary to moderate combustion. It was also found that autoignition can be induced even in a mixture lean enough to cause misfiring by raising the intake air temperature so as to advance the overall combustion process.

This study examined Homogeneous Charge Compression Ignition (HCCI) combustion characteristics in detail on the basis of in-cylinder combustion visualization, spectroscopic measurements of light emission and absorption and chemical kinetic simulations. Special attention was focused on investigating and comparing the effects of the fuel octane number and residual gas on combustion characteristics. The results made clear the relationship between the production/consumption of formaldehyde (HCHO) in the HCCI autoignition process and flame development behavior in the cylinder. Additionally, it was found that both the fuel octane number and residual gas have the effect of moderating low-temperature oxidation reactions. Furthermore, it was observed that residual gas has the effect of shifting the temperature for the occurrence of the hot flame to a higher temperature range.