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This paper presents experimental results for two fuel-related topics in a diesel engine: (1) how fuel volatility affects the premixed burn and heat release rate, and (2) how ignition quality influences the soot formation. Fast evaporation of fuel may lead to more intense heat release if a higher percentage of the fuel is mixed with air to form a combustible mixture. However, if the evaporation of fuel is driven by mixing with high-temperature gases from the ambient, a high-volatility fuel will require less oxygen entrainment and mixing for complete vaporization and, consequently, may not have potential for significant heat release simply because it has vaporized. Fuel cetane number changes also cause uncertainty regarding soot formation because variable ignition delay will change levels of fuel-air mixing prior to combustion.

Some soot particles emitted from common-rail diesel engines are so small that can penetrate deep into the human pulmonary system, causing serious health issues. The analysis of nano-scale internal structure of these soot particles sampled from the engine tailpipe has provided useful information about their reactivity and toxicity. However, the variations of carbon fringe structures during complex soot formation/oxidation processes occurring inside the engine cylinder are not fully understood. To fill this gap, this paper presents experimental methods for direct sampling and nanostructure analysis of in-flame soot particles in a working diesel engine. The soot particles are collected onto a lacey carbon-coated grid and then imaged in a high-resolution transmission electron microscope (HR-TEM). The HR-TEM images are post-processed using a Matlab-based code to obtain key nanostructure parameters such as carbon fringe length, fringe-to-fringe separation distance, and fringe tortuosity.

The major challenge of the post-processing of soot aggregates in transmission electron microscope (TEM) images is the detection of soot primary particles that have no clear boundaries, vary in size within the fractal aggregates, and often overlap with each other. In this study, we propose an automated detection code for primary particles implementing the Canny Edge Detection (CED) and Circular Hough Transform (CHT) on pre-processed TEM images for particle edge enhancement using unsharp filtering as well as image inversion and self-subtraction. The particle detection code is tested for soot TEM images obtained at various ambient and injection conditions, and from five different combustion facilities including three constant-volume combustion chambers and two diesel engines.

The importance of radiative heat transfer on the combustion and soot formation characteristics under nominal ECN Spray A conditions has been studied numerically. The liquid n-dodecane fuel is injected with 1500 bar fuel pressure into the constant volume chamber at different ambient conditions. Radiation from both gas-phase as well as soot particles has been included and assumed as gray. Three different solvers for the radiative transfer equation have been employed: the discrete ordinate method, the spherical-harmonics method and the optically thin assumption. The radiation models have been coupled with the transported probability density function method for turbulent reactive flows and soot, where unresolved turbulent fluctuations in temperature and composition are included and therefore capturing turbulence-chemistry-soot-radiation interactions. Results show that the gas-phase (mostly CO2 ad H2O species) has a higher contribution to the net radiation heat transfer compared to soot.

Shadowgraph/schlieren imaging techniques have often been used for flow visualization of reacting and non-reacting systems. In this paper we show that high-speed shadowgraph visualization in a high-pressure chamber can also be used to identify cool-flame and high-temperature combustion regions of diesel sprays, thereby providing insight into the time sequence of diesel ignition and combustion. When coupled to simultaneous high-speed Mie-scatter imaging, chemiluminescence imaging, pressure measurement, and spatially-integrated jet luminosity measurements by photodiode, the shadowgraph visualization provides further information about spray penetration after vaporization, spatial location of ignition and high-temperature combustion, and inactive combustion regions where problematic unburned hydrocarbons exist. Examples of the joint application of high-speed diagnostics include transient non-reacting and reacting injections, as well as multiple injections.

Stringent particulate emission regulations are applied to spark-ignition direct-injection (SIDI) engines, calling for a significant in-cylinder reduction of soot particles. To enhance fundamental knowledge of the soot formation and oxidation process inside the cylinder of the engine, a new in-flame particle sampling system has been developed and implemented in a working optical SIDI engine with a side-mounted, wall-guided injection system. Using the sampling probes installed on the piston top, the soot particles are directly sampled from the petrol flame for detailed analysis of particle size distribution, structure, and shape. At the probe tip, a transmission electron microscope (TEM) grid is stored for the soot collection via thermophoresis, which is imaged and post-processed for statistical analysis. Simultaneously, the flame development was recorded using two high-speed cameras to evidence the direct exposure of the sampling grids to the soot-laden diffusion flames and pool fires.

Future fuels will come from a variety of feed stocks and refinement processes. Understanding the fundamentals of combustion and pollutants formation of these fuels will help clear hurdles in developing flex-fuel combustors. To this end, we investigated the combustion, soot formation, and soot oxidation processes for various classes of fuels, each with distinct physical properties and molecular structures. The fuels considered include: conventional No. 2 diesel (D2), low-aromatics jet fuel (JC), world-average jet fuel (JW), Fischer-Tropsch synthetic fuel (JS), coal-derived fuel (JP), and a two-component surrogate fuel (SR). Fuel sprays were injected into high-temperature, high-pressure ambient conditions that were representative of a practical diesel engine. Simultaneous laser extinction measurement and planar laser-induced incandescence imaging were performed to derive the in-situ soot volume fraction.

For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.

In-flame soot sampling based on the thermophoresis of particles and subsequent transmission electron microscope (TEM) imaging has been conducted in a diesel engine to study size, shape and structure of soot particles within the reacting diesel jet. A direct TEM sampling is pursued, as opposed to exhaust sampling, to gain fundamental insight about the structure of soot during key formation and oxidation stages. The size and shape of soot particles aggregate structure with stretched chains of spherical-like primary particles is currently an unknown for engine soot modelling approaches. However, the in-flame sampling of soot particles in the engine poses significant challenges in order to extract meaningful data. In this paper, the engine modification to address the challenges of high-pressure sealing and avoiding interference with moving valves and piston are discussed in detail.

Wall-deposition of soot particles occurs during the cylinder liner wall/flame interaction, which can potentially deteriorate engine oil quality and alter the heat loss rate in a diesel engine. These issues motivate a detailed study on structure and size of the wall-deposited soot particles. A morphological difference between the wall-deposited soot and in-flame soot particles is another focus of this study. We performed thermophoretic soot sampling in the cylinder liner wall using an in-liner-type sampler. Obtained soot particles were imaged by a transmission electron microscope and post-processed to acquire the number of particles, projection area on the sampling grid, and size distribution. The same set of data was also obtained for soot particles within the diesel flame using a probe-type sampler.

Influence of the injection pressure on the temporal evolution of lifted jet flame base upon the bowl wall impingement has been studied in a small-bore optical diesel engine. Previous studies suggest that the jet-wall interaction causes re-entrainment of combustion products into the incoming jet, which shortens the lift-off length during the injection and thereby increasing downstream soot. After the end of injection, the flame base slowly moves downstream as the diminishing jet momentum results in reduced re-entrainment. How the injection pressure impacts this transient behaviour of the flame base is a main focus of the present study. Common-rail pressure was varied from 70 to 160 MPa at a fixed injection mass (10 mg per hole) and timing (7°CA bTDC).

This paper presents engine performance and emissions of coconut oil-derived 10% biodiesel blends in petroleum diesel demonstrating simultaneous reduction of smoke and NOx emissions and increased brake power. The experiments were performed in a single-cylinder version of a light-duty diesel engine for three different fuels including a conventional diesel fuel and two B10 fuels of chemical-catalyst-based methyl-ester biodiesel (B10mc) and biological-catalyst-based ethyl-ester biodiesel (B10eb). The engine tests were conducted at fixed speed of 2000 rpm and injection pressure of 130 MPa. In addition to the fuel variation, the injection timing and rate of exhaust gas recirculation (EGR) were also varied because they impact the combustion and thus the efficiency and emissions significantly.

A detailed chemical model was implemented in the KIVA-3V two dimensional CFD code to investigate the effects of the spray cone angle and injection timing on the PCCI combustion process and emissions in an optical research diesel engine. A detailed chemical model for Primary Reference Fuel (PRF) consisting of 157 species and 1552 reactions was used to simulate diesel fuel chemistry. The model validation shows good agreement between the predicted and measured pressure and emissions data in the selected cases with various spray angles and injection timings. If the injection is retarded to -50° ATDC, the spray impingement at the edge of the piston corner with 100° injection angle was shown to enhance the mixing of air and fuel. The minimum fuel loss and more widely distributed fuel vapor contribute to improving combustion efficiency and lowering uHC and CO emissions in the engine idle condition.

Diesel fuel injection system is the most important part of the direct-injection diesel engine and, in recent years, it has become one of the critical technologies for emission control with the help of electronically controlled fuel injection. Common rail injection system has great flexibility in injection timing, pressure and multi-injections. Many studies and applications have reported the advantages of using common rail system to meet the strict emission regulation and to improve engine performance for diesel engines. The main objective of this study is to investigate the effect of pilot-, post- and multiple-fuel injection strategies on engine performance and emissions. The study was carried out on a single cylinder optical direct injection diesel engine equipped with a high pressure common rail fuel injection system. Spray and combustion evolutions were visualized through a high speed charge-coupled device (CCD) camera.

A diesel-fueled premixed charged compression ignition (PCCI) combustion technique using a two-stage injection strategy has been investigated in a single cylinder optical engine equipped with a common-rail fuel system. Although PCCI combustion has the advantages of reducing NOx and PM emissions, difficulties in vaporization of a diesel fuel and control of the combustion phase hinder the development of the PCCI engine. A two-stage injection strategy was applied to relieve these problems. The first injection, named as main injection, was an early direct injection of diesel fuel into the cylinder to achieve premixing with air. The second injection was a diesel injection of a small quantity (1.5 mm3) as an ignition promoter and combustion phase controller near TDC. Effects of injection pressure, injected fuel quantity and compression ratio were studied with variation of an intake air temperature.

One major drawback of spark-ignition direct-injection (SIDI) engines is increased particulate matter (PM) and unburned hydrocarbon emissions at high load, due to wall wetting and a reduction in available air/fuel mixing time when compared to port-fuel injection (PFI). It is therefore necessary to understand the mechanics behind injection strategies which are capable of reducing these emissions while also maintaining the performance and efficiency of the engine. This study investigates the effect of varying the number fuel injection events and equivalence ratio on the operation of a wall-guided SIDI (WG-SIDI) engine. Of particular interest is how increased mixture homogeneity achieved by the double injection events impacts in-cylinder conditions and flame development.

Ethanol has been selected as a fuel for gasoline compression ignition (GCI) engines realising partially premixed charge combustion, considering its higher resistance to auto-ignition, higher evaporative cooling and oxygen contents than widely used gasoline, all of which could further improve already high efficiency and low smoke/NOx emissions of GCI engines. The in-cylinder phenomena and engine-out emissions were measured in a single-cylinder automotive-size common-rail diesel engine with a special emphasis on double injection strategies implementing early first injection near BDC and late second injection near TDC.

The present study aims to evaluate the effects of engine speed on gasoline compression ignition (GCI) combustion implementing double injection strategies. The double injection comprises of near-BDC first injection for the formation of a premixed charge and near-TDC second injection for the combustion phasing control. The engine performance and emissions testing of GCI combustion has been conducted in a single-cylinder light-duty diesel engine equipped with a common-rail injection system and fuelled with a conventional gasoline with 91 RON. The double injection strategy was investigated for various engine speeds ranging 1200~2000 rpm and the second injection timings between 12°CA bTDC and 3°CA aTDC.

One major drawback of spark-ignition direct-injection (SIDI) engines is increased particulate matter (PM) emissions at high load, due to increased wall wetting and a reduction in available mixture preparation time when compared to port-fuel injection (PFI). It is therefore necessary to understand the mechanics behind injection strategies which are capable of reducing these emissions while also maintaining the performance and efficiency of the engine. Splitting the fuel delivery into two or more injections is a proven way of working towards this goal, however, many different injection permutations are possible and as such there is no clear consensus on what constitutes an ideal strategy for any given objective. In this study, the effect of the timing of the first and second injections for an evenly split dual injection strategy are investigated in an optical SIDI engine running at 1200 RPM with an unthrottled intake.

Soot particles emitted from modern diesel engines, despite significantly lower total mass, show higher reactivity and toxicity than black-smoking old engines, which cause serious health and environmental issues. Soot nanostructure, i.e. the internal structure of soot particles composed of nanoscale carbon fringes, can provide useful information to the investigation of the particle reactivity and its oxidation status. This study presents the nanostructure details of soot particles sampled directly from diesel flames in a working diesel engine as well as from exhaust gases to compare the internal structure of soot particles in the high formation stage and after in-cylinder oxidation. Thermophoretic soot sampling was conducted using an in-house-designed probe with a lacy transmission electron microscope (TEM) grid stored at the tip.