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The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. An investigation program is carried out to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. In this paper, fundamental results of the Diesel engine relevant combustion are presented. To enable optimum engine performance a range of different reference fuels have been investigated. The fundamental effects of different physical and chemical properties on emission formation and engine performance are investigated using a thermodynamic diesel single cylinder research engine and an optically-accessible combustion vessel. Depending on the chain length and molecular structure, fuel compounds vary in cetane number, boiling temperature etc. Therefore, different hydrocarbons including n-heptane, n-dodecane, and l-decanol were investigated.

Today's biofuels require large amounts of energy in the production process for the conversion from biomass into fuels with conventional properties. To reduce the amounts of energy needed, future fuels derived from biomass will have a molecular structure which is more similar to the respective feedstock. Butyl levulinate can be gained easily from levulinic acid which is produced by acid hydrolysis of cellulose. Thus, the Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of this biofuel compound, as a candidate for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. Previous investigations identified most desirable fuel properties like a reduced cetane number, an increased amount of oxygen content and a low boiling temperature for compression ignition engine conditions.

Pilot injection (PI) during the negative-valve-overlap (NVO) period is one method to improve control of combustion in gasoline controlled auto-ignition engines. This is generally attributed to both chemical and thermal effects. However, there are little experimental data on active species formed by the combusting PI and their effect on main combustion in real engines. Thus, it is the objective of the current study to apply and assess optical in-cylinder diagnostics for these species. Firstly, the occurrence and nature of combustion during the NVO period is investigated by spectrally-resolved multi-species flame luminescence measurements. OH*, CH*, HCO*, CO-continuum chemiluminescence, and soot luminosity are recorded. Secondly, spectrally-, spatially-, and cycle-resolved laser-induced fluorescence measurements of formaldehyde are conducted. It is attempted to find a cycle-resolved measure of the chemical effect of PI.

Maintaining low NOx emissions over the operating range of diesel engines continues to be a major issue. However, optical measurements of nitric oxide (NO) are lacking particularly in the core of diesel jets, i.e. in the region of premixed combustion close to the spray axis. This is basically caused by severe attenuation of both the laser light and fluorescent emission in laser-induced fluorescence (LIF) applications. Light extinction is reduced by keeping absorption path lengths relatively short in this work, by investigating diesel jets in a combustion vessel instead of an engine. Furthermore, the NO-detection threshold is improved by conducting 1-d line measurements instead of 2-d imaging. The NO-LIF data are corrected for light attenuation by combined LIF and spontaneous Raman scattering. The quantified maximum light attenuation is significantly lower than in comparable previous works, and its wavelength dependence is surprisingly weak.

With Post Euro 6 emission standards in discussion, stricter particulate number (PN) targets as well as a decreased PN cut-off size from 23 to 10 nm are expected. Sub-23 nm particulates are considered particularly harmful to human health, but are not yet taken into account in the current vehicle certification process. Not considering sub-23 nm particulates during the development process could lead to significant additional efforts for Original Equipment Manufacturers (OEM) to comply with future Post Euro 6 PN emission limits. It is therefore essential to increase knowledge about the formation and filtration of particulates below 23 nm. In the present study, a holistic Gasoline Particulate Filter (GPF) characterization has been carried out on an engine test bench under varying boundary conditions and on a burner bench with a novel ash loading methodology.

Model-based control strategies along with an adapted calibration process become more important in the overall vehicle development process. The main drivers for this development trend are increasing numbers of vehicle variants and more complex engine hardware, which is required to fulfill the more and more stringent emission legislation and fuel consumption norms. Upcoming fundamental changes in the homologation process with EU 6c, covering an extended range of different operational and ambient conditions, are suspected to intensify this trend. One main reason for the increased calibration effort is the use of various complex aftertreatment technologies amongst different vehicle applications, requiring numerous combustion modes. The different combustion modes range from heating strategies for active Diesel Particulate Filter (DPF) regeneration or early SCR light-off and rich combustion modes to purge the NOx storage catalyst (NSC) up to partially premixed combustion modes.

A new index to evaluate the inherent soot reduction in a diesel-like spray plume is proposed in this study. The index is named “Oxidation Potential Number” and was derived with the help of a computational fluid dynamics (CFD) software. C8 - C16 n-alkanes, 1-alcohols and di-n-ethers were studied with the help of this index over four part load engine operating conditions, representative of a C-class diesel vehicle. The CFD modelling results have shown that C8 molecules feature a higher potentiality to reduce the soot. Thus, C8 molecules were tested in a single cylinder diesel engine over the same operating conditions. In conclusion, the proposed index is compared with the soot engine out emission.

A new approach is presented to modelling wall heat transfer in the exhaust port and manifold within 1D gas exchange simulation to ensure a precise calculation of thermal exhaust enthalpy. One of the principal characteristics of this approach is the partition of the exhaust process in a blow-down and a push-out phase. In addition to the split in two phases, the exhaust system is divided into several sections to consider changes in heat transfer characteristics downstream the exhaust valves. Principally, the convective heat transfer is described by the characteristic numbers of Nusselt, Reynolds and Prandtl. However, the phase individual correlation coefficients are derived from 3D CFD investigations of the flow in the exhaust system combined with Low-Re turbulence modelling. Furthermore, heat losses on the valve and the seat ring surfaces are considered by an empirical model approach.

The influence of two oxygenated tailor-made fuels on soot formation and oxidation in an optical single cylinder research diesel engine has been studied. For the investigation a planar laser-induced incandescence (PLII) measurement technique was applied to the engine in order to detect and evaluate the planar soot distribution for the two bio fuels within a laser light sheet. Furthermore the OH* chemiluminescence and broad band soot luminosity was visualized by high speed imaging to compare the ignition and combustion behavior of tested fuels: Two C8 oxygenates, di-n-butylether (DNBE) and 1-octanol. Both fuels have the same molecular formula but differ in their molecular structure. DNBE ignites fast and burns mostly diffusive while 1-octanol has a low cetane number and therefore it has a longer ignition delay but a more homogeneous mixture at time of ignition. The two bio fuels were finally compared to conventional diesel fuel.

The growing number of passenger car variants and derivatives in all global markets, their high degree of software differentiability caused by regionally different legislative regulations, as well as pronounced market-specific customer expectations require a continuous optimization of the entire vehicle development process. In addition, ever stricter emission standards lead to a considerable increase in powertrain hardware and control complexity. Also, efforts to achieve market and brand specific multistep adjustable drivability characteristics as unique selling proposition, rapidly extend the scope for calibration and testing tasks during the development of powertrain control units. The resulting extent of interdependencies between the drivability calibration and other development and calibration tasks requires frontloading of development tasks.

Within a public founded project test cell investigations were undertaken to identify parameters which predominantly influence the development of critical deposits in injection nozzles. A medium-duty diesel engine was operated in two different coking cycles with a zinc-free lubricant. One of the cycles is dominated by rated power, while the second includes a wide area of the operation range. During the experiments the temperatures at the nozzle tip, the geometries of the nozzle orifice and fuel properties were varied. For a detailed analysis of the deposits methods of electron microscopy were deployed. In the course of the project optical access to all areas in the nozzle was achieved. The experiments were evaluated by means of the monitoring of power output and fuel flow at rated power. The usage of a SEM (scanning electron microscope) and a TEM (transmission electron microscope) revealed images of the deposits with a magnification of up to 160 000.

It is the objective of this work to characterize mixture formation in the sprays emanating from Multi-Layer (ML) nozzles under approximately engine-like conditions by quantitative, spatially, and temporally resolved fuel-air ratio and temperature measurements. ML nozzles are cluster nozzles which have more than one circle of orifices. They were introduced previously, in order to overcome the limitations of conventional nozzles. In particular, the ML design yields the potential of variable spray interaction, so that mixture formation could be controlled according to the operating condition. In general, it was also a primary aim of the cluster-nozzle concepts to combine the enhanced atomization and pre-mixing of small nozzle holes with the longer spray penetration lengths of large holes. The applied diagnostic, which is based on 1d spontaneous Raman scattering, yields the quantitative stoichiometric ratio and the temperature in the vapor phase.

Sustainable and energy-efficient consumption is a main concern in contemporary society. Driven by more stringent international requirements, automobile manufacturers have shifted the focus of development into new technologies such as Hybrid Electric Vehicles (HEVs). These powertrains offer significant improvements in the efficiency of the propulsion system compared to conventional vehicles, but they also lead to higher complexities in the design process and in the control strategy. In order to obtain an optimum powertrain configuration, each component has to be laid out considering the best powertrain efficiency. With such a perspective, a simulation study was performed for the purpose of minimizing well-to-wheel CO2 emissions of a city car through electrification. Three different innovative systems, a Series Hybrid Electric Vehicle (SHEV), a Mixed Hybrid Electric Vehicle (MHEV) and a Battery Electric Vehicle (BEV) were compared to a conventional one.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.

To comply with the new regulations on particulate matter emissions, the manufacturers of light-duty as well as heavy-duty vehicles more commonly use diesel particulate filters (DPF). The regeneration of DPF depends to a significant extent on the properties of the soot stored. Within the Cluster of Excellence "Tailor-Made Fuels from Biomass (TMFB)" at RWTH Aachen University, the Institute for Combustion Engines carried out a detailed investigation program to explore the potential of future biofuel candidates for optimized combustion systems. The experiments for particulate measurements and analysis were conducted on a EURO 6-compliant High Efficiency Diesel Combustion System (HECS) with petroleum-based diesel fuel as reference and a today's commercial biofuel (i.e., FAME) as well as a potential future biomass-derived fuel candidate (i.e., 2-MTHF/DBE). Thermo gravimetric analyzer (TGA) was used in this study to evaluate the oxidative reactivity of the soot.

In order to thoroughly investigate and improve the path from biofuel production to combustion, the Cluster of Excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Since then, a variety of fuel candidates have been investigated. In particular, 2-methyl tetrahydrofurane (2-MTHF) has shown excellent performance w.r.t. the particulate (PM) / NOx trade-off [1]. Unfortunately, the long ignition delay results in increased HC-, CO- and noise emissions. To overcome this problem, the addition of di-n-butylether (DNBE, CN ∼ 100) to 2-MTHF was analyzed. By blending these two in different volumetric shares, the effects of the different mixture formation and combustion characteristics, especially on the HC-, CO- and noise emissions, have been carefully analyzed. In addition, the overall emission performance has been compared to EN590 diesel.

The current and future restrictions on pollutant emissions from internal combustion engines require a holistic investigation of the abilities of alternative fuels to optimize the combustion process and ensure cleaner combustion. In this regard, the Tailor-made Fuels from Biomass (TMFB) Cluster at Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen University aims at designing production processes for biofuels as well as fuels optimal for use in internal combustion engines. The TMFB Cluster's scientific approach considers the molecular structure of the fuels as an additional degree of freedom for the optimization of both the production pathways and the combustion process of such novel biofuels. Thus, the model-based specification of target parameters is of the utmost importance to improve engine combustion performance and to send feedback information to the biofuel production process.

The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.

In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

Combustion and pollutant formation in a new recently introduced Common-Rail DI Diesel engine concept with roof-shaped combustion chamber and tumble charge motion are numerically investigated using the Representative Interactive Flamelet concept (RIF). A reference case with a cup shaped piston bowl for full load operating conditions is considered in detail. In addition to the reference case, three more cases are investigated with a variation of start of injection (SOI). A surrogate fuel consisting of n-decane (70% liquid volume fraction) and α-methylnaphthalene (30% liquid volume fraction) is used in the simulation. The underlying complete reaction mechanism comprises 506 elementary reactions and 118 chemical species. Special emphasis is put on pollutant formation, in particular on the formation of NOx, where a new technique based on a three-dimensional transport equation within the flamelet framework is applied.