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Selective catalytic reduction (SCR) of NOx is coming into worldwide use for automotive diesel emissions control. To meet the most stringent standards, NOx conversion efficiency must exceed 80% while NH3 emissions or slip must be kept below 10-30 ppm. At such high levels of performance, non-uniformities in ammonia-to-NOx ratio (ANR) at the converter inlet can limit the achievable NOx reduction. Despite its significance, this effect is frequently ignored in 1D catalyst models. The corresponding model error is important to system integration engineers because it affects system sizing, and to control engineers because it affects both steady-state and dynamic SCR converter performance. A probability distribution function (PDF) based method is introduced to include mixture non-uniformity in a 1D, real-time catalyst model.

With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.

The dual-fuel Reactivity Controlled Compression Ignition (RCCI) combustion could achieve high efficiency and low emissions over a wide range of operating conditions. However, further high load extension is limited by the excessive pressure rise rate and soot emission. Polyoxymethylene dimethyl ethers (PODE), a novel diesel alternative fuel, has the capability to achieve stoichiometric smoke-free RCCI combustion due to its high oxygen content and unique molecule structure. In this study, experimental investigations on high load extension of gasoline/PODE RCCI operation were conducted using late intake valve closing (LIVC) strategy and intake boosting in a single-cylinder, heavy-duty diesel engine. The experimental results show that the upper load can be effectively extended through boosting and LIVC with gasoline/PODE stoichiometric operation.

Hydrogen fuel is a future energy to solve the problems of energy crisis and environmental pollution. Hydrogen internal combustion engines can combine the advantage of hydrogen without carbon pollution and the main basic structure of the traditional engines. However, the power of the port fuel injection hydrogen engines is smaller than the same volume gasoline engine because the hydrogen occupies the volume of the cylinder and reduces the air mass flow. The turbocharger can increase the power of hydrogen engines but also increase the NOx emission. Hence, a comprehensive controlling strategy to solve the contradiction of the power, BTE and NOx emission is important to improve the performance of hydrogen engines. This paper shows the controlling strategy for a four-stroke, 2.3L hydrogen engine with a turbocharger. The controlling strategy divides the operating conditions of the hydrogen engine into six parts according to the engine speeds and loads.

Recently, with the increasing interest on some potential alternative substitutes of petroleum fuels such as biodiesel and butanol, more and more researches are focused on the field of bio-fuels because they are renewable and friendly to the environment and can possibly reduce domestic demand on foreign petroleum. Bio-fuels are generally used in the commercial market by mixing with petroleum-based diesel or gasoline. Since the volatilities and boiling points of ethanol/butanol and diesel/biodiesel fuels are significantly different, micro-explosion can be expected in the blend mixture. In this study, a numerical model of micro-explosion including bubble generation, bubble expansion, and final breakup for multi-component bio-fuel droplets is proposed. From the simulated results of droplet characteristics at the onset of micro-explosion, it is concluded that micro-explosion is possible under engine operation condition for ethanol/butanol-diesel/biodiesel fuel blends.

The combustion and emission characteristics of a diesel engine running on butanol-diesel blends were investigated in this study. The blending ratio of n-butanol to diesel was varied from 0 to 40 vol% using an increment of 10 vol%, and each blend was tested on a 2.7 L V6 common rail direction injection diesel engine equipped with an EGR system. The test was carried out under two engine loads at a constant engine speed, using various combinations of EGR ratios and injection timings. Test results indicate that n-butanol addition to engine fuel is able to substantially decrease soot emission from raw exhaust gas, while the change in NOx emissions varies depending on the n-butanol content and engine operating conditions. Increasing EGR ratio and retarding injection timing are effective approaches to reduce NOx emissions from combustion of n-butanol-diesel blends.

A fully coupled multi-dimensional CFD and reduced chemical kinetics model is adopted to investigate the effects of charge stratification on HCCI combustion and emissions. Seven different kinds of imposed stratification have been introduced according to the position of the maximal local fuel/air equivalence ratio in the cylinder at intake valve close. The results show that: The charge stratification results in stratification of the in-cylinder temperature. The former four kinds of stratification, whose maximal local equivalence ratios at intake valve close locate between the cylinder center and half of the cylinder radius, advance ignition timing, reduce the pressure-rise rate, and retard combustion-phasing. But the following three kinds of stratification, whose maximal local equivalence ratios at intake valve close appear between half of the cylinder radius and the cylinder wall, have little effect on the cylinder pressure.

The effects of various injection timing of methanol on thermo-atmosphere combustion of methanol by port injection of dimethyl ether (DME) and direct injection of methanol were experimentally investigated. The experiment results show that, as injection timing is at 6 degree before TDC, the combustion process comprises three stages: low temperature heat release of DME, high temperature heat release of DME and diffusion combustion of methanol. As injection timing increases, premixed combustion proportion of methanol is increased and diffusion combustion proportion is decreased. As injection timing increases to 126 degree before TDC, diffusion combustion of methanol disappears. At this time, the combustion process shows typical two stages heat release of HCCI combustion. As injection timing increases, required DME rate is increased, combustion efficiency and indicated thermal efficiency all first increase and then decrease.

A HCCI engine has been run at different operating boundaries conditions with fuels of different RON and MON and different chemistries. The fuels include gasoline, PRF and the mixture of PRF and ethanol. Six operating boundaries conditions are considered, including different intake temperature (Tin), intake pressure (Pin) and engine speed. The experimental results show that, fuel chemistries have different effect on the combustion process at different operating conditions. It is found that CA50 (crank angle at 50% completion of heat release) shows no correlation with either RON or MON at some operating boundaries conditions, but correlates well with the Octane Index (OI) at all conditions. The higher the OI, the more the resistance to auto-ignition and the later is the heat release in the HCCI engine. The operating range is also correlation with the OI. The higher the OI, the higher IMEP can reach.

Exhaust Gas Recirculation (EGR) is an important parameter for control of diesel engine combustion, especially to achieve ultra low NOx emissions. In this paper, the effects of EGR on engine emissions and engine efficiency have been investigated in a heavy-duty diesel engine while changing combustion control parameters, such as injection pressure, injection timing, boost, compression ratio, oxygenated fuel, etc. The engine was operated at 1400 rpm for a cycle fuel rate of 50mg. The results show that NOx emissions strongly depend on the EGR rate. The effects of conventional combustion parameters, such as injection pressure, injection timing, and boost, on NOx emissions become small as the EGR rate is increased. Soot emissions depend strongly on the ignition delay and EGR rate (oxygen concentration). Soot emissions can be reduced by decreasing the compression ratio, increasing the injection pressure, or burning oxygenated fuel.

An optically accessible single-cylinder high-speed direct-injection (HSDI) diesel engine equipped with a Bosch common rail injection system was used to study effects of injection pressures on the in-cylinder spray and combustion processes. An injector with an injection angle of 70 degrees and European low sulfur diesel fuel (cetane number 54) were used in the work. The operating load was 2.0 bar IMEP with no EGR added in the intake. The in-cylinder pressure was measured and the heat release rate was calculated. High-speed Mie-scattering technique was employed to visualize the liquid distribution and evolution. High-speed combustion video was also captured for all the studied cases using the same frame rate. NOx emissions were measured in the exhaust pipe. The experimental results indicated that for all of the conditions the heat release rate was dominated by a premixed combustion pattern. Two-stage low temperature reaction was seen for early injection timings.

A single nozzle port fuel injector was modified to apply electrostatic charge to the fuel stream, with the intention of studying electrostatically assisted sprays in a practical, port-injected engine. The modifications were kept external to the injector and involved placing an electrode and insulating liner over the tip of the injector. The performance of the modified injector, which combined pressure driven and electrostatic atomization, was characterized in three phases: the injector sprays themselves were studied, combustion of charged fuel droplets was studied, and the injector was installed and tested on a single cylinder spark ignition engine. In the first phase, Fraunhofer diffraction measurements of droplet size, and particle image velocimetry measurements of droplet velocity were performed. The charge transferred by the sprays was measured using an electrometer, and typical forces exerted on droplets in the sprays were estimated.

Studies on combustion process of Dimethyl Ether (DME) were carried out on a constant volume combustion bomb (CVCB) and a visualization engine, and the photograph of combustion of DME was taken by high speed digital CCD. The results show that the ignition delay of DME is shorter than that of diesel fuel. When the fuel delivery amounts of DME and diesel in volume are the same, the combustion duration of DME is shorter than that of diesel fuel, and the flame temperature of DME is lower than that of diesel. At the end of combustion, the second injection occurred. The results of high-speed photograph in visualization engine show that, as soon as DME leaves the nozzle, it evaporates rapidly, and under the effect of air swirl, the spray“core” is blown off. Compared to diesel, the penetration of DME is shorter, and the wall combustion of DME is apparently smaller.

HCCI/PCCI combustion concepts have been demonstrated for both high brake thermal efficiency and low engine-out emissions. However, these advanced combustion concepts still could not be fully utilized partially due to the limitations of conventional fixed spray angle nozzle designs for issues related to wall wetting for early injections. The micro-variable circular orifice (MVCO) fuel injector provides variable spray angles, variable orifice areas, and variable spray patterns. The MVCO provides optimized spray patterns to minimize combustion chamber surface-wetting, oil dilution and emissions. Designed with a concise structure, MVCO can significantly extend the operation maps of high efficiency early HCCI/PCCI combustion, and enable optimization of a dual-mode HCCI/PCCI and Accelerated Diffusion Combustion (ADC) over full engine operating maps. The MVCO variable spray pattern characteristics are analyzed with high speed photographing.

The combustion in low-speed two-stroke marine diesel engines can be characterized as large spatial and temporal scales combustion. One of the most effective measures to reduce NOx emissions is to reduce the local maximum combustion temperature. In the current study, multi-dimensional numerical simulations have been conducted to explore the potential of Miller cycle, high compression ratio coupled with EGR (Exhaust Gas Recirculation) and WEF (water emulsified fuel) to improve the trade-off relationship of NOx-ISFC (indicated specific fuel consumption) in a low-speed two-stroke marine engine. The results show that the EGR ratio could be reduced combined with WEF to meet the Tier III emission regulation. The penalty on fuel consumption with EGR and WEF could be offset by Miller cycle and high geometric compression ratio.

In this work, both the ‘SCR-only’ and ‘EGR+SCR’ technical routes are compared and evaluated after the optimizations of both injection strategy and turbocharging system over the World Harmonized Stationary Cycle (WHSC) in a heavy duty diesel engine. The exhaust emissions and fuel economy performance of different turbocharging systems, including wastegate turbocharger (WGT), variable geometry turbocharger (VGT), two-stage fixed geometry turbocharger (WGT+FGT) and two-stage variable geometry turbocharger (VGT+FGT), are investigated over a wide EGR range. The NOx reduction methods and EGR introduction strategies for different turbocharger systems are proposed to improve the fuel economy. The requirement on turbocharging system and their potential to meet future stringent NOx and soot emission regulations are also discussed in this paper.

A new approach of NOx reduction in the compression-ignition engine is introduced in this work. The previous research has shown that during the combustion stage, the high temperature ignition tends to occur early at the near-stoichiometric region where the combustion temperature is high and majority of NOx is formed; Therefore, it is desirable to burn the leaner region first and then the near-stoichiometric region, which inhibits the temperature rise of the near-stoichiometric region and consequently suppresses the formation of NOx. Such inverted ignition sequence requires mixture with inverted phi-sensitivity. Fuel selection is performed based on the criteria of strong ignition T-sensitivity, negligible negative temperature coefficient (NTC) behavior, and large heat of vaporization (HoV).

In this work the gasoline compression ignition (GCI) combustion characterized by both premixed gasoline port injection and gasoline direct injection in a single-cylinder diesel engine was investigated experimentally and computationally. In the experiment, the premixed ratio (PR), injection timing and exhaust gas recirculation (EGR) rate were varied with the pressure rise rate below 10 bar/crank angle. The experimental results showed that higher PR and earlier injection timing resulted in advanced combustion phasing and improved thermal efficiency, while the pressure rise rates and NOx emissions increased. Besides, a lowest ISFC of 176 g/kWh (corresponding to IMEP =7.24 bar) was obtained, and the soot emissions could be controlled below 0.6 FSN. Despite that NOx emission was effectively reduced with the increase of EGR, HC and CO emissions were high. However, it showed that GCI combustion of this work was sensitive to EGR, which may restrict its future practical application.

Methanol has been regarded as a potential transportation fuel due to its advanced combustion characteristics and flexible source. However, it is suffering from misfire and high HC emissions problems under cold start and low load conditions either on methanol SI engine or on methanol/diesel dual fuel engine. Hydrogen is a potential addition that can enhance the combustion of methanol due to its high flammability and combustion stability. In the current work, the effect of hydrogen fraction on the laminar flame characteristics of methanol- hydrogen-air mixture under varied equivalence ratio was investigated on a constant volume combustion chamber system coupled with a schlieren setup. Experiments were performed over a wide range of equivalence ratio of the premixed charge, varied from 0.8 to 1.4, as well as different hydrogen fraction, 0%, 5%, 10%, 15% and 20% (n/n). All tests were carried out at fixed temperature and pressure of 400K and 0.1MPa.

Droplets impacting onto the heated surface is a typical phenomenon either in CI engines or in GDI SI engines, which is regarded significant for their air-fuel mixing. Meanwhile, alcohols including ethanol and butanol, has been widely studied as internal combustion engine alternative fuels due to their excellent properties. In this paper, under different component ratio conditions, the ethanol-butanol droplet impacting onto the heated aluminum surface has been studied experimentally. The falling height of the droplets were set at 5cm. A high-speed camera, set at 512×512pixels, 5000 fps and 20 μs of exposure time, was used to visualize the droplet behavior impinging onto the hot aluminum surface. The impact regimes of the binary droplet were identified. The result showed that the Leidenfrost temperature of droplets was affected by the ratio of ethanol to butanol. The higher the content of butanol in the droplet, the higher the Leidenfrost temperature.