Search Results

A numerical model is used to examine the chemical kinetic processes leadING to knocking in spark-ignition internal combustion engines. The construction and validation of the model is described in detail, including low temperature reaction paths involving alkylperoxy radical isomerization. The numerical model is applied to C1 to C7 paraffinic hydrocarbon fuels, and a correlation is developed between the Research Octane Number (RON) and the computed time of ignition for each fuel. Octane number is shown to depend on the rates of OH radical production through isomerization reactions, and factors influencing the rate of isomerization such as fuel molecule size and structure are interpreted in terms of the kinetic model. knock behavior of fuel mixtures is examined, and the manner in which pro-knock and anti-knock additives influence ignition is studied numerically. The kinetics of methyl tert-butyl ether (MTBE) is discussed in particular detail.

This paper presents the results of an experimental investigation of the fuel-air mixing process in a port-fuel-injected, 4-valve, spark-ignited engine that was motored to simulate cold cranking and start-up conditions. An infrared fiber-optic instrumented spark plug probe was used to measure the local, crank angle resolved, fuel concentration in the vicinity of the spark gap of a single-cylinder research engine with a production head and fuel injector. The crank-angle resolved fuel concentrations were compared for various injection timings including open-intake-valve (OIV) and closed-intake-valve (CIV) injection, using federal certification gasoline. In addition, the effects of speed, intake manifold pressure, and injected fuel mass were examined.

A liquid-phase port injection system for liquefied petroleum gas (LPG) generally consists of a fuel storage tank with extended capability of operating up to 600 psi, a fuel pump, and suitable fuel lines to and from the LPG fuel injectors mounted in the fuel rail manifold. Port injection of LPG in the liquid phase is attractive due to engine emissions and performance benefits. However, maintaining the LPG in the liquid phase at under-hood conditions and re-starting after hot soak can be difficult. Multiphase behavior within a liquid-phase LPG injection system was investigated computationally and experimentally. A commercial chemical equilibrium code (ASPEN PLUS™) was used to model various LPG compositions under operating conditions.

This paper presents the latest developments in the design and performance of an electronic particulate matter (PM) sensor developed at The University of Texas at Austin (UT) and suitable, with further development, for applications in active engine control of PM emissions. The sensor detects the carbonaceous mass component of PM in the exhaust and has a time-resolution less than 20 (ms), allowing PM levels to be quantified for engine transients. Sample measurements made with the sensor in the exhaust of a single-cylinder light duty diesel engine are presented for both steady-state and transient operations: a steady-state correlation with gravimetric filter measurements is presented, and the sensor response to rapid increases in PM emission during engine transients is shown for several different tip-in (momentary increases in fuel delivery) conditions.

The Texas Project was a multi-year study of aftermarket conversions of a variety of light-duty vehicles to CNG or LPG. Emissions and fuel economy when using these fuels are compared to the results for the same vehicles operating on certification gasoline and Federal Phase 1 RFG. Since 1993, 1,040 tests were conducted on 10 models, totally 86 light-duty vehicles. The potential for each vehicle model/kit combination to attain LEV certification was assessed. Also, comparisons of emissions and fuel economy between converted vehicles when operating on gasoline and nominally identical un-converted gasoline control vehicles were analyzed. Additional evaluations were performed for a subfleet that was subjected to exhaust speciations for operation over the Federal Test Procedure cycle and also for off-cycle tests.

An electronic particulate matter sensor (EPMS) developed at the University of Texas was used to characterize exhaust gases from a single-cylinder diesel engine and a light-duty diesel vehicle. Measurements were made during transient tip-in events with multiple sensor configurations in the single-cylinder engine. The sensor was operated in two modes: one with the electric field energized, and the other with no electric field present. In each mode, different characteristic signals were produced in response to a tip-in event, highlighting the two primary mechanisms of sensor operation. The sensor responded to both the natural charge of the particulate matter (PM) emitted from the engine, and was also found to create a signal by charging neutral particles. The characteristics of the two mechanisms of operation are discussed as well as their implications on the placement and operation of the sensor.

The Texas Department of Transportation began using an emulsified diesel fuel in 2002. They initiated a simultaneous study of the effectiveness of this fuel in comparison to 2D on-road diesel fuel and 2D off-road diesel. The study included comparisons of fuel economy and emissions for the emulsion, Lubrizol PuriNOx®, relative to conventional diesel fuels. Two engines and eight trucks, four single-axle dump trucks, and four tandem-axle dump trucks were tested. The equipment tested included both older mechanically-controlled diesels and newer electronically-controlled diesels. The two engines were tested over two different cycles that were developed specifically for this project. The dump trucks were tested using the “route” technique over one or the other of two chassis dynamometer cycles that were developed for this project In addition to fuel efficiency, emissions of NOx, PM, CO, and HCs were measured. Additionally, second-by-second results were obtained for NOx and HCs.

The Texas Department of Transportation (TxDOT) began using an emulsified diesel fuel as an emissions control measure in July 2002. They initiated a study of the effectiveness of this fuel in comparison to conventional diesel fuel for TxDOT's Houston District operations and included the fleet operated by the Associated General Contractors (AGC) in the Houston area. Cost-effectiveness analyses, including the incremental cost per ton of NOx removed, were performed. NOx removal was the focus of this study because Houston is an ozone nonattainment area, and NOx is believed to be the limiting factor in ozone formation in the Houston area. The cost factors accounted for in the cost-effectiveness analyses included the incremental cost of the fuel (including an available rebate from the State of Texas), the cost of refueling more often, implementation costs, productivity costs, maintenance costs, and various costs associated with the tendency of the emulsion to separate.

The University of Texas 2000 Ethanol Vehicle Challenge team remains focused on cold start, cold drivability, fuel economy, and emissions reduction for our 2000 Ethanol Vehicle Challenge entry. We used the stock PCM for all control functions except control of an innovative cold-start system our team designed. The primary modifications for improved emissions control involved ceramic coating of the exhaust manifolds, use of close-coupled ethanol-specific catalysts, use of a moddified version of the California Emissions Calibrated PCM, and our cold-start system that eliminates the need to overfuel the engine at the beginning of the FTP. Additionally, we eliminated EGR at high load to improve power density. Major modifications, such as increasing the compression ratio or pressure boosting, were eliminated from consideration due to cost, complexity, reliability, or emissions penalties.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

An optical access engine was used to image the liquid film evaporation off the piston of a simulated direct injected gasoline engine. A directional injector probe was used to inject liquid fuel (gasoline, i-octane and n-pentane) directly onto the piston of an engine primarily fueled on propane. The engine was run at idle conditions (750 RPM and closed throttle) and at the Ford World Wide Mapping Point (1500 RPM and 262 kPa BMEP). Mie scattering images show the liquid exiting the injector probe as a stream and directly impacting the piston top. Schlieren imaging was used to show the fuel vaporizing off the piston top late in the expansion stroke and during the exhaust stroke. Previous emissions tests showed that the presence of liquid fuel on in-cylinder surfaces increases engine-out hydrocarbon emissions.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.

A nephelometer system was developed to characterize engine particulate emissions from DISI engines. Results were correlated with images showing the location and history of particulates in the cylinder of an optical engine. The nephelometer's operation is based upon the dependence of scattered laser light on particulate size from a flow sampled from the exhaust of an engine. The nephelometer simultaneously measured the scattered light from angles of 20° to 160° from the forward scattering direction in 4° increments. The angular scattering measurements were then compared with calculations using a Mie scattering code to infer information regarding particulate size. Measurements of particulate mass were made based upon a correlation developed between the scattered light intensity and particulate mass samples trapped in a 0.2-micron filter. Measurements were made in a direct injection single-cylinder spark ignition research engine having a transparent quartz cylinder.

A fiber optic instrumented spark plug was used to make time-resolved measurements of the fuel vapor concentration history near the spark gap in a four-valve DISI engine. Four different bulk flow were investigated. Several early and late injection timings were examined. The fuel concentration at the spark gap was correlated with IMEP. Emissions of CO, HCs, and NOx were related to the type of bulk flow. For both early and late injection the CoVs of fuel concentration were generally lowest for the weakest bulk flow which resulted in a stable stratification. Strong bulk flows convected the inhomogeneities through the measurement area near the spark plug resulting in both large intracycle and cycle-to-cycle variation in equivalence ratio at the time of ignition.

We have examined the influence of piston wetting on the size distribution and mass of particulate matter (PM) emissions in a SI engine using several different fuels. Piston wetting was isolated as a source of PM emissions by injecting known amounts of liquid fuel onto the piston top using an injector probe. The engine was run predominantly on propane with approximately 10% of the fuel injected as liquid onto the piston. The liquid fuels were chosen to examine the effects of fuel volatility and molecular structure on the PM emissions. A nephelometer was used to characterize the PM emissions. Mass measurements from the nephelometer were compared with gravimetric filter measurements, and particulate size measurements were compared with scanning electron microscope (SEM) photos of particulates captured on filters. The engine was run at 1500 rpm at the Ford world-wide mapping point with an overall equivalence ratio of 0.9.

Improved submodels for use in a dynamic engine/vehicle model have been developed and the resulting code has been used to analyze the tip-in, tip-out behavior of a computer-controlled port fuel injected SI engine. This code consists of four submodels. The intake simulation submodel is similar to prior intake models, but some refinements have been made to the fuel flow model to more properly simulate a timed port injection system, and it is believed that these refinements may be of general interest. A general purpose engine simulation code has been used as a subroutine for the cycle simulation submodel. A conventional vehicle simulation submodel is also included in the model formulation. Perhaps most importantly, a submodel has been developed that explicitly simulates the response of the on-board computer (ECM) control system.

In this pilot study conducted by the Auto/Oil Air Quality Improvement Research Program, engine-out and tailpipe speciated hydrocarbon emissions were obtained for three vehicles operated over the Federal Test Procedure on two different fuels, both of which were speciated. The fates of the fuel species were traced across the engine and across the catalyst, and relationships were developed between engine-out and tailpipe hydrocarbon emissions and fuel composition. These relationships allowed separating the fuel's contribution to engine-out and tailpipe hydrocarbon emissions into two parts, unreacted fuel and partial oxidation products. Specific ozone reactivities and toxic air pollutants were analyzed for both engine-out and tailpipe emissions. Vehicle-to-vehicle, fuel-to-fuel, and bag-to-bag differences have been highlighted.

EmiSense Technologies, LLC (www.emisense.com) is commercializing its electronic particulate matter (PM) sensor that is based on technology developed at the University of Texas at Austin (UT). To demonstrate the capability of this sensor for real-time PM measurements and on board diagnostics (OBD) for failure detection of diesel particle filters (DPF), independent measurements were performed to characterize the engine PM emissions and to compare with the PM sensor response. Computational fluid dynamics (CFD) modeling was performed to characterize the hydrodynamics of the sensor's housing and to develop an improved PM sensor housing with reproducible hydrodynamics and an internal baffle to minimize orientation effects. PM sensors with the improved housing were evaluated in the truck exhaust of a heavy duty (HD) diesel engine tested on-road and on a chassis dynamometer at the University of California, Riverside (UCR) using their Mobile Emissions Laboratory (MEL).

Fuel effects on exhaust emissions of a sample of seven high emitting vehicles were studied. The vehicles had various mechanical problems and all ran fuel rich. The degree of enrichment varied between tests, and strongly affected mass emissions. Variable enrichment can cause incorrect apparent fuel effects to be calculated if not accounted for in data analysis. After variable enrichment was compensated for, the percentage effects of fuel oxygen, RVP, and olefins were largely in agreement with prior findings for normally emitting vehicles. Reducing fuel sulfur and T90 may have less benefit on hydrocarbon emissions in these high emitters than in normal emitters, and reducing sulfur may have less benefit on CO emissions. Reducing aromatics may be somewhat more helpful in reducing hydrocarbon and CO emissions in the high emitters.

Effects of gasoline sulfur content on emissions were measured in a fleet of ten 1989 model year vehicles. Two ranges of sulfur content were examined. In a set of five fuels, reducing sulfur from 450 to 50 ppm, reduced fleet average tailpipe emissions of HC, NMHC and CO each by about 18%, and reduced NOx 8%. The largest effect on HC and CO emissions was observed in FTP Bag 2. This and the absence of any significant effect on engine emissions indicate that sulfur affected the performance of the catalytic converters. The response of HC and NMHC to fuel sulfur content was non-linear and increased as sulfur level was reduced. In the second set of three fuels, reducing sulfur from 50 to 10 ppm reduced HC and NMHC by 6% and CO by 10%, but had no significant effect on NOx. The effects on HC, NMHC and NOx were not significantly different from predictions based on the prior fuel set. The reduction in CO was larger than predicted.