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Technical Paper

Formation Process of Soot Precursors in a Laminar Flow Reactor

2007-01-23
2007-01-0061
The Poly-Aromatic Hydrocarbon (PAH) formation process from benzene was studied using a laminar flow reactor and GC-MS. In addition to PAH, acetylene and ethylene were observed. Without oxygen at temperatures over 1070 K, the amount of PAH and C2 species increased as the benzene concentration decreased. Addition of oxygen caused a linear decrease in the benzene concentration, and almost all of the benzene was consumed under stoichiometric conditions at all temperatures. At 1053 K, the concentrations of PAH and C2 species were not affected by the addition of oxygen. On the other hand, when the temperature was greater than 1070 K, the amount of PAH formed increased as the equivalence ratio increased, until the equivalence ratio was about 4. Above this equivalence ratio, the amounts decreased. Amounts of phenanthrene and biphenyl were large compared to those of other PAHs, which indicated that the dominant PAH formation path is the formation of phenanthrene via biphenyl.
Technical Paper

Spray and Combustion Characteristics of Reformulated Biodiesel with Mixing of Lower Boiling Point Fuel

2007-04-16
2007-01-0621
Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.
Technical Paper

Controlling PCCI Combustion with Mixed Fuel - Application of Flashing Spray to Early Injection

2007-04-16
2007-01-0624
A diesel engine operating in premixed charge compression ignition (PCCI) mode promises the reduction of engine-out emissions of NOx and particulate matter. A serious issue for PCCI operation with the early injection timing during the compression stroke is the difficulty of controlling the mixture formation process. In this study, a mixed fuel consisting of high volatility fuel and high ignitability one is applied in order to develop a control technique for the mixture preparation. In particular, we focuses on a flash boiling phenomenon of mixed fuel. For pure substance, the quality of flashing spray is dominated by the degree of superheat. In contrast, that of mixed fuel is affected much by low boiling point fuel.
Technical Paper

Study on Characteristics of Auto-Ignition and Combustion of Unsteady Synthetic Gas Jet

2007-04-16
2007-01-0629
It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.
Technical Paper

Optimization of Engine System for Application of Biodiesel Fuel

2007-07-23
2007-01-2028
Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because biodiesel is carbon neutral in principle. However, biodiesels yield an increase in NOx emission from conventional diesel engine, compared with diesel fuel case. Therefore, some strategies are needed for meeting the future emission regulations when using biodiesel. In this study, rapeseed oil methyl ester (RME) was applied to diesel engine equipped with exhaust gas recirculation (EGR) system and NOx storage reduction (NSR) catalyst. NOx reduction rate of NSR catalyst was drastically decreased by using RME, even if injection quantity of RME for rich spike was enhanced. However, an increase in EGR rate could reduce NOx emission without the deterioration in smoke and PM emissions.
Technical Paper

Soot formation/oxidation and fuel-vapor concentration in a DI diesel engine using laser-sheet imaging method

2000-06-12
2000-05-0078
Four kinds of optical measurements were performed to investigate the process of soot formation and oxidation in a direct-injection (DI) diesel engine. Measurements were carried out in an optically accessible DI diesel engine that allows planar laser sheet for combustion diagnostics to enter the combustion chamber either horizontally or along the axis of the fuel jet. The temporal and spatial distribution of soot particles has been investigated using the laser- induced incandescence (LII) and high-speed direct photography. Fuel vapor concentration, which is directly linked to the soot formation process in diesel combustion, has been deduced from the images obtained by the measurements of laser shadowgraph and elastic Mie scattering. According to the experimental results, soot formation begins to occur near the injector nozzle in which a fuel-rich mixture is distributed with a homogeneous condition. LII signal is dominated by the fuel vapor concentration in initial combustion period.
Technical Paper

Mixing and soot formation processes in transient gas jet flame

2000-06-12
2000-05-0075
A transient gas jet and its flame are the most fundamental phenomena of a transient spray and its flame breaking out in a CI engine and an SI engine with the direct injection system. In the case of CNG and LNG engines, the fuel itself is just gaseous state. The 2-LIF technique was applied to the transient gas jet to obtain the mixing process between the surroundings and it, and the simultaneous application of LII and LIS techniques were applied to the transient gas jet flame to obtain the soot formation process.
Technical Paper

PM Measurement with Partial Dilution Tunnel - Influence of Sampling Line on PM Measurement -

2001-09-24
2001-01-3580
The full-flow dilution tunnel (hereinafter referred to as full tunnel) measurement method has become the de facto standard for the evaluation of particulate matter (hereinafter referred to as PM) emitted from diesel-powered vehicles. However, due to its drawbacks such as bulkiness and expensiveness, a method that uses a very small partial dilution tunnel (hereinafter referred to as micro tunnel) has been developed, mainly in Europe, nearly to the level of practicality. With this method, a higher degree of freedom in controlling sampling flow and temperature can be obtained. Another advantage of the micro tunnel is that the system is compact. However, the micro tunnel's measurement accuracy remains uncertain because the accumulation of measurement data is not yet sufficient. Measuring PM while varying micro tunnel operating parameters permitted a check on the equivalency with a full tunnel system.
Technical Paper

A New Type Partial Flow Dilution Tunnel with Geometrical Partitioning for Diesel Particulate Measurement

2001-09-24
2001-01-3579
The authors have developed a new partial flow dilution tunnel (hereafter referred to as PPFT), whose principal device is a flux splitting gas divider, as a new means of measuring particulate emissions which can be applied to transient cycle testing of diesel engines. The advantage of this system is that it can achieve perfect constant velocity splitting by means of its structure, and theoretically can also maintain high splitting performance despite fluctuations in the exhaust flow rate, including those due to engine exhaust pulsation. We compared this system with a full tunnel by analyzing the basic performance of the system and measuring particulate matter (PM) using an actual vehicle engine.
Technical Paper

Effect of Exhaust Gas Recirculation on Exhaust Emissions from Diesel Engines Fuelled with Biodiesel

2007-09-16
2007-24-0128
Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because bio-diesel is carbon neutral in principle. However, when biodiesel was applied to conventional diesel engines without modification for biodiesel, NOx emission was increased by the change in fuel characteristics. It is necessary to introduce some strategies into diesel engines fuelled with biodiesel for lower NOx emission than conventional diesel fuel case. The purpose of this study is to reveal that exhaust gas recirculation (EGR) is one of the solutions for the reduction of NOx emission and meeting the future emission regulations when using biodiesel. Neat Rapeseed oil methyl ester (RME) as a biodiesel (B100) was applied to diesel engines equipped with high pressure loop (HPL) EGR system and low pressure loop (LPL) EGR system. Cooled HPL EGR was increased during steady-state operations and JE05 transient mode tests.
Technical Paper

Emission Characteristics of a Urea SCR System under the NOx Level of Japanese 2009 Emission Regulation

2007-10-29
2007-01-3996
In order to discuss future technical issues for urea SCR (selective catalytic reduction) system, it is necessary to assess various technical possibilities that would be applied to urea SCR systems which is capable of complying with future emission level requirements, for example Japanese 2009 emission regulation. In this paper, three measures (enhanced insulation on a DOC (diesel oxidation catalyst), aggressive urea solution injection and idling stop) are installed on a urea SCR system of a commercial engine system in order to achieve further NOx (nitrogen oxide) reductions. With combination of these three measures, NOx is drastically reduced to the levels lower than 0.7 g/kWh, which is a NOx limit value of the Japanese 2009 emission regulation. NH3 (ammonia) and HCN (hydro cyanide) are also measured as unregulated harmful components.
Technical Paper

Study of the Effect of Boiling Point on Combustion and PM Emissions in a Compression Ignition Engine Using Two-Component n-Paraffin Fuels

2002-03-04
2002-01-0871
Fuel composition is investigated as a parameter influencing fuel/air mixing of direct injected fuel and the subsequent consequences for particulate emissions. Presumably, enhanced mixing prior to ignition results in a larger portion of fuel burning as a premixture and a smaller portion of diffusion burning around fuel-rich regions. This would potentially lower particulate emissions without overly compromising hydrocarbon emissions or high load operation. Using mixtures of n-paraffin fuels, particulate emissions were measured and the results were compared with in-cylinder visualization of the injection process and two-color method calculations of flame temperature. In general, lower boiling point fuels exhibited higher flame temperatures, less visible flame, and lower particulate emissions.
Technical Paper

Experimental Analysis on Soot Formation Process In DI Diesel Combustion Chamber by Use of Optical Diagnostics

2002-03-04
2002-01-0893
Soot formation process inside the combustion chamber of an DI diesel engine is focused as a phenomenological basic scheme by using several optical diagnostics technique for the improvement of diesel exhaust emission. We have conducted the series of optical measurement research for the clarification of combustion field in an DI diesel engine. Then, this paper is a kind of review by adding the fuel vapor properties and particle image velocimetry (PIV) analysis with focusing the soot formation process. The experiments were carried out in a small sized high-speed DI diesel engine installed with an optical access view. The spray characteristics and its flow field in 2-D field were measured by laser sheet scattering (LIS) method and PIV scheme.
Technical Paper

Detailed Chemical Kinetic Modeling of Diesel Spray Combustion with Oxygenated Fuels

2001-03-05
2001-01-1262
This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.
Technical Paper

The Effect of Fuel-Vapor Concentration on the Process of Initial Combustion and Soot Formation in a DI Diesel Engine Using LII and LIEF

2001-03-05
2001-01-1255
A phenomenological or empirical model based on experimental results obtained from various optical measurements is critical for the understanding of DI diesel combustion phenomena as well as for the improvement of its emission characteristics. Such a model could be realized by the application of advanced optical measurement, which is able to isolate a particular phenomenon amongst complicated physical and chemical interactions, to a DI diesel combustion field. The authors have conducted experimental studies to clarify the combustion characteristics of unsteady turbulent diffusion flames in relation to the soot formation and oxidation process in a small-sized DI diesel engine. In the present study, the effect of fuel vapor concentration on the process of early combustion and soot formation has been investigated using several optical measurements.
Technical Paper

Performance and Emission Characteristics of a DI Diesel Engine Operated on Dimethyl Ether Applying EGR with Supercharging

2000-06-19
2000-01-1809
This research investigates engine performance and the possibility of reducing exhaust emissions by using Dimethyl Ether (DME). There are high expectations for DME as a new alternative fuel for diesel engines for heavy-duty vehicles. In this experiment, a single cylinder direct-injection diesel engine with displacement of 1.05 liter and a compression ratio of 18:1 was used as a base engine. Common rail type DME fuel injection equipment for the single cylinder engine experiment was installed, and direct injection in the cylinder of DME was tried. Results indicated that high injection pressure, high swirl ratio, and supercharging using multi-hole injectors are effective for combustion promotion in the DME fueled diesel engine (DME engine). The output of the DME engine using supercharging with an intercooler and EGR was higher than that of a diesel engine. By increasing the EGR rate Nox emission was reduced to about 1/3 that of the diesel engine. Smoke was not completely emitted.
Technical Paper

Evaluation of Regulated Materials and Ultra Fine Particle Emission from Trial Production of Heavy-Duty CNG Engine

2006-10-16
2006-01-3397
A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.
Technical Paper

SOF Component of Lubricant Oil on Diesel PM in a High Boosted and Cooled EGR Engine

2007-04-16
2007-01-0123
The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.
Technical Paper

Advanced Diesel Combustion Using of Wide Range, High Boosted and Cooled EGR System by Single Cylinder Engine

2006-04-03
2006-01-0077
For reducing exhaust emissions of heavy-duty diesel engines, the authors made an experimental study of diesel combustion using a single cylinder engine. The engine performance and exhaust emissions have been measured using a wide range and high EGR rate under the conditions of high boost intake pressure. The engine test cell has been equipped the external supercharger that is able to raise the boost pressure to 500 kPa, and also equipped the EGR system to increase the EGR rate until 50% under the 500 kPa boost condition. In various test conditions of load and engine speeds the authors have obtained the results, that is, NOx has been reduced drastically without increasing Particulate Matter (PM).
Technical Paper

Application of Biodiesel Fuel to Modern Diesel Engine

2006-04-03
2006-01-0233
The 1997 Kyoto protocol came into effect in February, 2005 to reduce greenhouse gases within the period 2008-2012 by at least 5 % with respect to 1990 levels. Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because BDF is carbon neutral in principle. The purpose of this project is to produce a light-duty biodiesel truck which can be suitable for emission regulation in next generation. The effect of BDF on the performance and emissions of modern diesel engine which was equipped with the aftertreatment for PM and NOx emissions was investigated without modifications of engine components and parameters, as a first step for research and development of biodiesel engine. Rapeseed oil methyl ester (RME) was selected in behalf of BDF, and combustion characteristics, engine performance and exhaust emissions were made a comparison between RME and petroleum diesel fuel by steady operation and Japan transient mode (JE05) tests.
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