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Journal Article

Effects of Reflux Temperature and Molarity of Acidic Solution on Chemical Functionalization of Helical Carbon Nanotubes

2017-09-19
Abstract The use of nanomaterials and nanostructures have been revolutionizing the advancements of science and technology in various engineering and medical fields. As an example, Carbon Nanotubes (CNTs) have been extensively used for the improvement of mechanical, thermal, electrical, magnetic, and deteriorative properties of traditional composite materials for applications in high-performance structures. The exceptional materials properties of CNTs (i.e., mechanical, magnetic, thermal, and electrical) have introduced them as promising candidates for reinforcement of traditional composites. Most structural configurations of CNTs provide superior material properties; however, their geometrical shapes can deliver different features and characteristics. As one of the unique geometrical configurations, helical CNTs have a great potential for improvement of mechanical, thermal, and electrical properties of polymeric resin composites.
Journal Article

Ultraviolet-Initiated Curing of Natural Fiber-Reinforced Acrylated Epoxidized Soybean Oil Composites

2021-06-02
Abstract Sustainable practices are taking precedence across many industries, as evident from their shift towards the use of environmentally responsible materials, such as natural fiber-reinforced acrylated epoxidized soybean oil (NF-AESO). However, due to the lower reactivity of AESO, the curing reaction usually requires higher temperatures and longer curing time (e.g., 150°C for 6-12 h), thus making the entire process unsustainable. In this study, we demonstrate the potential power of photons towards manufacturing NF-AESO composites in a sustainable manner at room temperature (RT) within 10 min. Two photoinitiators, i.e., the 2,2-dimethoxy phenylacetophenone (DMPA) and 1-hydroxycyclohexyl phenyl ketone (HCPK), were evaluated and compared with the thermal initiator, i.e., tert-butyl perbenzoate (TBPB). Based on the mechanical performance of the AESOs, the photoinitiation system for NF-AESO was optimized.
Journal Article

Effect of Interaction between Oil Additive Elements on the Heat Dissipated from Oil-Cooled Engine Parts at Various Wall Temperatures

2020-04-16
Abstract Engine oils have complex packages of additives aimed at improving their tribological properties. However, interactions between elements of these additives may hinder the cooling ability of these oils. The current article addresses the influence of the interaction between chemical elements of oil additives on the cooling capacity of oils for different wall superheats (0°C-150°C) and oil bulk temperatures (60°C, 100°C, and 150°C). A back-propagation neural network (BPNN) is used to conduct the present work. The NN is trained on experimental heat transfer data of five commercial engine oils. Enhancement intensity, interaction sensitivity, and interaction stability of additive elements are investigated for the range of element concentrations of the experimental dataset.
Journal Article

Impact of Siloxanes in Biomethane on the Performance of a CNG Vehicle

2018-03-23
Abstract In this paper, the results of experiments to determine the effects of silicon-containing compounds in biogas on the performance of spark-ignited gas engines for use in CNG vehicles are presented. Initial research was performed on micro-CHP units, which have many features common with automotive engines, to identify engine components sensitive for silica deposition prior to investigating a practical CNG engine. The experiments on the micro-CHP units revealed that the catalyst was the most sensitive part for silica fouling, with strong impact on the reduction of NOx. With the insight gained from these experiments, an 9-week endurance test was performed on a light-duty CNG vehicle.
Journal Article

Comparative Study on the Effect of Different Lubricating Oil Additives on the Tribological Properties of Bearing Steel

2020-01-23
Abstract The purpose of this article is to study the antifriction and anti-wear effect of GCr15 bearing steel under paraffin base oil and the base oil with two additives of T405 sulfurized olefin and nano-MoS2 and compare the synergistic lubrication effect of two different additives (MoS2 and T405) in paraffin base oil. The tribological properties of GCr15 bearing steel under different lubrication conditions were tested on a ball-on-disk tribometer. The three-dimensional profile of disk’s worn surfaces and the scanning electron microscope (SEM) micrographs of corresponding steel balls were analyzed at the same time. The wettability of lubricating oils on the surface of friction pairs and the dispersibility of MoS2 in base oil were characterized.
Journal Article

Chemical Analysis of Deposits Separated from Blocked Fuel Filters

2021-10-25
Abstract Biodiesel was found to be the best candidate to replace diesel fuel mainly due to being renewable, biodegradable, and non-toxic and reduce greenhouse gases, which cause global warming. Nowadays, biodiesel is blended with diesel fuel in different concentrations depending on the country of usage and is used in diesel engines. Concerns about biodiesel were raised after premature fouling of fuel filters were reported before meeting their mileage requirement. Three filters from Brazil were analyzed using different techniques (Energy Dispersive X-Ray [EDX], Fourier Transform Infrared Spectroscopy [FTIR], Thermogravimetric Analysis [TGA], Time of Flight-Secondary Ion Mass Spectrometry [ToF-SIMS], and Gas Chromatography/Mass Spectrometry [GC/MS]) to understand the chemical composition of the filter deposits and highlight the main compounds responsible for the blockage.
Journal Article

A Model Study for Prediction of Performance of Automotive Interior Coatings: Effect of Cross-Link Density and Film Thickness on Resistance to Solvents and Chemicals

2019-03-27
Abstract Automotive interior coatings for flexible and rigid substrates represent an important segment within automotive coating space. These coatings are used to protect plastic substrates from mechanical and chemical damage, in addition to providing colour and design aesthetics. These coatings are expected to resist aggressive chemicals, fluids, and stains while maintaining their long-term physical appearance and mechanical integrity. Designing such coatings, therefore, poses significant challenges to the formulators in effectively balancing these properties. Among many factors affecting coating properties, the cross-link density (XLD) and solubility parameter (δ) of coatings are the most predominant factors.
Journal Article

Improved Test Method for Tribological Evaluation of High Performance Plastics

2019-04-02
Engineering plastics are widely used in many tribological applications due to their inherent advantages such as reduced weight, ease of manufacturing, improved chemical compatibility, and damping characteristics. However, the process of selecting an appropriate polymeric material system for a specific application involves significant experimentation.
Journal Article

Eco-Profiling of Bio-Epoxies via Life Cycle Assessment

2020-03-25
Abstract Epoxies, synthesized from bisphenol-A (BPA) and epichlorohydrin (ECH), are predominantly used as coatings, adhesives, and matrix material in fiber-reinforced composites for body-in-white (BiW) applications in the automotive sector. However, given the production of conventional epoxies from nonrenewable petroleum resource and toxicity of BPA, several initiatives have been undertaken by researchers to synthesize alternative epoxies from various bio-sources that are free of BPA and exhibit similar mechanical performance. As a result, such bio-sourced epoxies are almost immediately termed as “ecofriendly,” despite the lack of comprehensive evaluation of their ecological performance that takes into account enhanced natural resource usage and associated impacts accompanying such epoxies.
Journal Article

Analysis of Metal Pick-Up Formation Process within Automotive Brake Pad

2019-11-19
Abstract Metal Pick-Up (MPU) is a problematic phenomenon in automotive disc brakes. MPU generally forms as some metal lumps on the surface of the brake pad. If brake pads have MPU, during braking they would cause grooving of the disc rotor, generating brake noise and deteriorating the performance of the brake. The previous literature has so far reported that the source of the MPU is an Fe component from a disc rotor or brake pads. However, only a few of the generation mechanisms of MPU have been proven. We investigate MPU to completely elucidate the mechanism of MPU generation by using different analyses than the previous literature. First, to find out the source of MPU generation, we focus on the chemical reaction of a certain component with wear debris during braking, and some of the verification experiments are conducted under the conditions of simulated friction interface.
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