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In the past few decades, use of energy resources in industrial and transportation sector have reached to its peak resulting in depleting resources and environment squalor. Vegetable oils, which have properties comparable to diesel fuel, are considered promising alternative fuels for unmodified diesel engines. However, high viscosity of vegetable oils is a major challenge which could be reduced by blending with alcohols. The aim of the present study was to investigate the suitability of orange peel oil and n-butanol blends as an alternative fuel for CI engine. Various blends of butanol with orange peel oil were prepared on volumetric basis and named as B10OPO90 (10% n-butanol and 90% orange peel oil), B20OPO80 (20% n-butanol and 80% orange peel oil), B30OPO70 (30% n-butanol and 70% orange peel oil) and B40OPO60 (40% n-butanol and 60% orange peel oil). All blends were found homogenous and various physico-chemical properties were evaluated in accordance to relevant standards.

Diesel engines are employed particularly in the field of heavy transportation and agriculture on account of their higher thermal efficiency and durability. As these engines, are the backbones of contemporary global transportation and accounts a 30% of world's energy consumption, which is second highest after the industrial sector. Therefore, the fossil fuel consumption becomes the prime concern. Following the global energy crisis and the increasingly stringent emission norms, the search for alternative renewable fuels has intensified. Currently, biodiesel (BD) has been identified as the most attractive and practical choice to replace fossil fuel as the main source of energy, due to the similarity in the properties with conventional diesel. However, its development and application have been hindered by the high cost of required feedstock. Therefore, in recent years, researchers have been seeking the alternative sources of non-edible oil which are economical.

The rising cost and limited availability of crude oil in international market has provided an opportunity to look for substitute of fossil fuel. Scientists all over the world are experimenting on variety of renewable fuels for meeting the future energy demands. Bio origin fuels are fast becoming potential alternative resources to replace the fossil fuels. The vegetable oils, derived from oil seed crops have got 90 to 95% energy value of diesel on volume basis, comparable cetane number and can substitute upto 20% (v/v) of diesel fuel. Mahua seed oil is common ingredient of hydrogenated fat. Two-step transesterification process was employed to synthesize biodiesel from Mahua Oil (Madhuca-indica) and analysis of Physico-chemical properties as well as the combustion, performance and emission characteristics was done by taking 10, 20 and 100 % blend with diesel. The physico-chemical properties of the blends were found to be comparable to diesel.

The interest of using alternative fuels in diesel engines has been accelerated exponentially due to a foreseen scarcity in world petroleum reserves, increase in the prices of the conventional fossil fuels and restrictions on exhaust emissions such as greenhouse gases from internal combustion (IC) engines initiated by environmental concerns. The constant trade-off between efficiency and emissions should be in proper balance with the conventional fuels in a fuel design process for future combustors. Unlike gasoline and diesel, alcohols act as oxygenated fuels. Adding alcohols to petroleum products allows the fuel to combust properly due to the presence of oxygen, which enhances premixed combustion phase, improves the diffusive combustion phase which increases the combustion efficiency and reduces air pollution. The higher activation energy of alcohols leads to better resistance to engine knocking that allows higher compression ratios and greater engine thermal efficiencies.

The transportation sector faces great and urgent challenges, including climate impacts of greenhouse gas emissions, local health impacts of criteria pollutants, and political & economic impacts of petroleum dependence. While several revolutionary solutions are being developed to reduce the impact of motor vehicles, such as increased fuel economy standards and accelerated adoption of hybrid vehicles, revolutionary new approaches must also be evaluated. One such opportunity is found in Compressed Air Engine (CA Engine), which is powered solely by compressed air stored in a vehicle on-board pressurized tank. Proponents of this technology claim CA Engines are greener and cheaper to operate, since they do not consume fossil fuels and produce zero tail-pipe emissions, while offering the power and performance needed for light-duty vehicle use.

Primary energy sources can be divided into non-renewable and renewable. The over-exploration of non-renewable sources for energy availability imposes considerable impacts on the environment. Reducing the use of fossil fuels would significantly reduce the carbon dioxide emissions and other pollutants produced. The future drift for sustainable production of renewable energy is cautiously thoughtful for it has been increasingly understood that first generation biofuels, majorly produced from food crops that are limited in their ability to achieve targets for biofuel production, climate change mitigation and economic growth. These concerns have increased the interest in developing second generation biofuels produced from non-edible feedstock such as microalgae, which potentially offers greatest opportunities in the longer term. Microalgae are considered a very promising feedstock for biodiesel production due to their very high yield and their no competition with food crops.

The present consumption rates and heavy dependence on fossil fuels pose a humongous threat to the environment. The increased pollution in urban areas is already causing serious sociological, ecological and economic implications. The issue of energy security led governments and researchers to look for alternate means of renewable and environment friendly fuels. Biodiesel has been one of the promising, and economically viable alternatives. The biodiesels are reported to cause reduction in CO, HC and PM emissions. However, NOx emissions are increased in case of biodiesel in CI engine. Therefore, a Urea-SCR over Fe-ZSM5 honeycomb substrate (400cpsi) zeolite catalyst after treatment system is an effective technology to reduce emissions for biodiesel applications. Exhaust gases pass through the catalyst and reactions take place along its surface, consequently converting NOx into nitrogen and H2O.

The world today is facing the effect of the dependence on fossil fuels. Also, the rate of consumption of Fossil derived fuels is alarming. The use of non-conventional energy sources is to be increased so as to tackle the global climatic changes, environmental pollution and also to lower down the rate of depletion of fossil fuels. The urgent need to replace the petroleum products having harmful emissions has leaded us to the Biodiesel. Biodiesel is a well-known alternative for diesel with an advantage over the later because of its biodegradable, less toxic nature, superior lubricity, better emission characteristics and in a way environment friendly. The present study focuses on the comparative study and analysis of performance and emission characteristics of a light duty diesel engine on blends of Fish oil Biodiesel in Diesel and Calophyllum Inophyllum Oil Biodiesel in Diesel.