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Technical Paper

Scavenger free three-way catalyst with low hydrogen sulfide emission

2000-06-12
2000-05-0308
This study suggests new types of catalysts that show low hydrogen sulfide emission without scavenger such as NiO. Hydrogen sulfide can be reduced by changing the physicochemical properties of washcoat components. Synthesized gas activity tests were performed to investigate the effect of modified washcoat on hydrogen sulfide formation and catalytic activity. BET surface area tests, X- ray diffraction tests, and gas chromatography tests were also carried out to examine the characteristics of catalysts. Preparation methods for catalysts were focused on minimizing the adsorption of sulfur species on catalysts. The first approach is heat treatment of cerium oxide to reduce adsorption sites for sulfur compounds. But this leads to deterioration of CO and NOx conversion efficiencies. The second one is adding new types of promoters that increase thermal durability and dynamic oxygen storing function of cerium oxide.
Technical Paper

Optimization of the Packing Design for Manifold Catalytic Converter Application

1996-02-01
960561
A preconverter is an essential component of the new vehicle exhaust system for the achievement of tightened emission standards. To meet those standards, the Manifold Catalytic Converter (MCC) system has been developed in the Hyundai Motor Company (HMC). Unfortunately, the conventional MCC is no longer a suitable design for the exhaust gas treatment of the newly developed high performance engine since it cannot withstand the engine's exhaust temperature, vibration, pressure pulsation, and many other severe conditions. This paper is focused on a failure-mode analysis and new packing designs for the MCC application through a series of durability tests.
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