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We present the development of a semiconductor diode laser spectral absorption based gas species sensor for oxygen concentration measurements, intended for life support system monitoring and control applications. Employing a novel self-compensating, noise cancellation detection approach, we experimentally demonstrate better than 1% accuracy, linearity, and stability for monitoring breathing air conditions with 0.2 second response time. We also discuss applications of this approach to CO2 sensing.

The dual membrane gas trap filter is utilized in the internal thermal control system (ITCS) as part of the pump package assembly to remove non-condensed gases from the ITCS coolant. This improves pump performance and prevents pump cavitation. The gas trap also provides the capability to vent air that is Ingested into the ITCS during routine maintenance and replacement of the International Space Station (ISS) system orbital replacement units. The gas trap is composed of two types of membranes that are formed into a cylindrical module and then encased within a titanium housing. The non-condensed gas that is captured is then allowed to escape through a vent tube in the gas trap housing.

The challenges of missions to the Moon and Mars presents NASA with the need for more advanced life support systems, including better technologies for CO2 removal in spacecraft atmospheres and extravehicular mobility units (EMU). Amine-coated single wall carbon nanotubes (SWCNT) have been proposed as a potential solution because of their high surface area and thermal conductivity. Initial research demonstrated the need for functionalization of SWCNT to obtain optimal adherence of the amine to the SWCNT support phase [1]. Recent efforts focus on the development of new methods to chemically bond amines to SWCNT. Synthesis and characterization methods for these materials are discussed and some preliminary materials characterization data are presented. The CO2 adsorption capacity for several versions of SWCNT supported amine-based CO2 scrubber materials is also determined.

A program is being performed to design, fabricate, and test a metal hydride sorption cryocooler system capable of supplying periodic refrigeration at 10 K. The system is intended to cool a focal plane array for a low-earth orbit satellite. The refrigeration is effected by sublimating solid hydrogen at 10 K. The solid hydrogen is produced in a batch process by cooling, solidifying, and subcooling liquid hydrogen formed at 30 K by a Joule-Thomson expansion. The spent hydrogen from the sublimation and Joule-Thomson expansion is absorbed by two metal hydride sorption bed assemblies.

A regenerable metal oxide CO2 absorber is being developed for future Extravehicular Mobility Unit (EMU) applications. It was designed to fit the existing shuttle EMU without modification of the interfaces. Absorption and regeneration tests were performed with subscale and full-size laboratory absorbers. Data is presented for open and closed loop absorber tests that evaluate the effects of residence time, mass velocity, and internal temperature on performance, with emphasis is on the full-size test unit. Regeneration testing quantified the effects of temperature and air flow rate on desorption rate, and of various absorber cooling modes. Its objective was to optimize conditions for minimum peak power and minimum total energy consumption.

Membranes are highly desirable for separating gases in life-support applications. They are small, light, efficient, selective and require little operational or physical maintenance. Facilitated transport membranes have particularly high flux and selectivity. We created enzyme-based facilitated transport membranes using isozymes and mutants as immobilized arrays alone and in conjunction with polymeric membranes. The enzyme operates efficiently at the low CO2 concentrations encountered in respiratory gases and can bring CO2 to near ambient levels. CO2 flux is greatly enhanced and selectivities for CO2 over O2 of 200:1 or greater are possible. The enzymes are robust and stable for long periods under a variety of storage and use conditions.

On June 25, 1997 a docking mishap of a Progress supply ship caused the Progress vehicle to crash into an array of solar panels and puncture the hull of the Spektr module. The puncture was small enough to allow the crew to seal off the Spektr module and repressurize the rest of the station. The Progress vehicle struck the Spektr module several times and the exact location, size, and number of punctures in the Spektr hull was unknown. Russian cosmonauts donned space suits and went inside the Spektr module to repair some electrical power cables and look for the location of the hull breach, they could not identify the exact location of the hole (or holes). The Spektr module was pressurized with Mir cabin air twice during the STS-86 fly around in an attempt to detect leakage (in the form of ice particles) from the module. Seven particles were observed within a 36 second time span, but tracking the path of the individual particles did not pinpoint a specific leak location.

A spectroscopic trace gas sensor using a distributed feedback diode laser at λ=1.53 µm and based on quartz enhanced photoacoustic spectroscopy technique is described. The sensor is capable of quasi-simultaneous quantification of trace ammonia, hydrogen cyanide, and acetylene (NH3, HCN, and C2H2, respectively) concentrations at ∼100 ppbv levels with a 4s integration time. The sensor design, responsivity, noise, and cross-talk characteristics are reported.