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In-situ production of oxygen and methane for utilization as a return propellant from Mars for both sample-return and manned missions is currently being developed by NASA in cooperation with major aerospace companies. Various technologies are being evaluated using computer modeling and analysis at the system level. An integrated system that processes the carbon dioxide in the Mars atmosphere to produce liquid propellants has been analyzed. The system is based on the Sabatier reaction that utilizes carbon dioxide and hydrogen to produce methane and water. The water is then electrolyzed to produce hydrogen and oxygen. While the hydrogen is recycled, the propellant gases are liquefied and stored for later use. The process model considers the surface conditions on Mars (temperature, pressure, composition), energy usage, and thermal integration effects on the overall system weight and size. Current mission scenarios require a system that will produce 0.7 kg of propellant a day for 500 days.

We present the development of a semiconductor diode laser spectral absorption based gas species sensor for oxygen concentration measurements, intended for life support system monitoring and control applications. Employing a novel self-compensating, noise cancellation detection approach, we experimentally demonstrate better than 1% accuracy, linearity, and stability for monitoring breathing air conditions with 0.2 second response time. We also discuss applications of this approach to CO2 sensing.

Space environmental control systems must control cabin temperature and humidity. This can be achieved by transferring the heat load to a circulating coolant, condensing the humidity, and separating the condensate from the air stream. In addition, environmental control systems may be required to remove particulate matter from the air stream. An assembly comprised of a filter, a condensing heat exchanger, a thermal control valve, and a liquid carryover sensor, is used to achieve all these requirements. A condensing heat exchanger and filter assembly (CHXFA) is being developed and manufactured by SECAN/AlliedSignal under a contract from Dornier Daimler-Benz as part of a European Space Agency program. The CHXFA is part of the environmental control system of the Columbus Orbital Facility (COF), the European laboratory module of the International Space Station (ISS).

Advanced life support flight experiments have been conceptualized for the International Space Station (ISS). Two of the experiments, a high pressure oxygen generator and a carbon dioxide reduction subsystem, offer high payback potential to the ISS program. This paper documents the cost-benefit analyses for these two experiments.

A two year test program has been initiated to evaluate the effects of extended duration operation on a solid polymer electrolyte Oxygen Generator Assembly (OGA); in particular the cell stack and membrane phase separators. As part of this test program, the OGA was integrated into the Marshall Space Flight Center (MSFC) Water Recovery Test (WRT) Stage 10, a six month test, to use reclaimed water directly from the water processor product water storage tanks. This paper will document results encountered and evaluated thus far in the life testing program.

CO2 removal, recovery and reduction are essential processes for a closed loop air revitalization system in a crewed spacecraft. Typically, a compressor is required to recover the low pressure CO2 that is being removed from the spacecraft in a swing bed adsorption system. This paper describes integrated tests of a Temperature-Swing Adsorption Compressor (TSAC) with high-fidelity systems for carbon dioxide removal and reduction assemblies (CDRA and Sabatier reactor). It also provides details of the TSAC operation at various CO2 loadings. The TSAC is a solid-state compressor that has the capability to remove CO2 from a low-pressure source, and subsequently store, compress, and deliver it at a higher pressure. TSAC utilizes the principle of temperature-swing adsorption compression and has no rapidly moving parts.

Life Sciences research on Space Station will utilize rats to study the effects of the microgravity environment on mammalian physiology and to develop countermeasures to those effects for the health and safety of the crew. The animals will produce metabolic water which must be reclaimed to minimize logistics support. The condensate from the Research Animal Holding Facility (RAHF) flown on Spacelab Life Sciences-2 (SLS-2) in October 1993 was used as an analog to determine the type and quantity of constituents which the Space Station (SS) water reclamation system will have to process. The most significant organics present in the condensate were 2-propanol, glycerol, ethylene glycol, 1,2-propanediol, acetic acid, acetone, total proteins, urea and caprolactam while the most significant inorganic was ammonia. Microbial isolates included Xanthomonas, Sphingobacterium, Pseudomonas, Penicillium, Aspergillus and Chrysosporium.

The Space Station provides a unique facility for conducting material processing and life science experiments under microgravity conditions. These conditions place special requirements on the U.S. Laboratory for storing and transporting chemicals and process fluids, reclaiming water from selected experiments, treating and storing experiment wastes, and providing vacuum utilities. To meet these needs and provide a safe laboratory environment, the Process Material Management System (PMMS) is being developed. Preliminary design requirements and concepts related to the PMMS are addressed in addition to discussing the MSFC PMMS breadboard test facility and a preliminary plan for validating the overall system design. The system contains a fluid handling subsystem which manages process fluids required by each experiment while a chemical storage facility safely stores potentially hazardous chemicals.

Membranes are highly desirable for separating gases in life-support applications. They are small, light, efficient, selective and require little operational or physical maintenance. Facilitated transport membranes have particularly high flux and selectivity. We created enzyme-based facilitated transport membranes using isozymes and mutants as immobilized arrays alone and in conjunction with polymeric membranes. The enzyme operates efficiently at the low CO2 concentrations encountered in respiratory gases and can bring CO2 to near ambient levels. CO2 flux is greatly enhanced and selectivities for CO2 over O2 of 200:1 or greater are possible. The enzymes are robust and stable for long periods under a variety of storage and use conditions.

On June 25, 1997 a docking mishap of a Progress supply ship caused the Progress vehicle to crash into an array of solar panels and puncture the hull of the Spektr module. The puncture was small enough to allow the crew to seal off the Spektr module and repressurize the rest of the station. The Progress vehicle struck the Spektr module several times and the exact location, size, and number of punctures in the Spektr hull was unknown. Russian cosmonauts donned space suits and went inside the Spektr module to repair some electrical power cables and look for the location of the hull breach, they could not identify the exact location of the hole (or holes). The Spektr module was pressurized with Mir cabin air twice during the STS-86 fly around in an attempt to detect leakage (in the form of ice particles) from the module. Seven particles were observed within a 36 second time span, but tracking the path of the individual particles did not pinpoint a specific leak location.