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The design and evaluation of a Vacuum-Swing Adsorption (VSA) system to remove metabolic water and metabolic carbon dioxide from a spacecraft atmosphere is presented. The approach for Orion and Altair is a VSA system that removes not only 100 percent of the metabolic CO2 from the atmosphere, but also 100% of the metabolic water as well, a technology approach that has not been used in previous spacecraft life support systems. The design and development of an Orion Crew Exploration Vehicle Sorbent Based Atmosphere Revitalization system, including test articles, a facility test stand, and full-scale testing in late 2008 and early 2009 is discussed.

Developmental efforts are seeking to improve upon the efficiency and reliability of typical packed beds of sorbent pellets by using structured sorbents and alternative bed configurations. The benefits include increased structural stability gained by eliminating clay bound zeolite pellets that tend to fluidize and erode, and better thermal control during sorption leading to increased process efficiency. Test results that demonstrate such improvements are described and presented.

The design of a vacuum-swing adsorption process to remove metabolic water, metabolic carbon dioxide, and metabolic and equipment generated trace contaminant gases from the Orion Crew Exploration Vehicle (CEV) atmosphere is presented. For Orion, the approach is taken that all metabolic water must be removed by the Sorbent-Based Atmosphere Revitalization System (SBAR), a technology approach that has not been used in previous spacecraft life support systems. Design and development of a prototype SBAR, a facility test stand, and subsequent testing of the SBAR in late 2006 and early 2007 is discussed.

This paper analyzes the aging of zeolite based hydrocarbon traps to guide development of diagnostic algorithms. Previous research has shown the water adsorption ability of zeolite ages along with the hydrocarbon adsorption ability, and this leads to a possible diagnostic algorithm: the water concentration in the exhaust can be measured and related to aging. In the present research, engine experiments demonstrate that temperature measurements are also related to aging. To examine the relationship between temperature-based and moisture-based diagnostic algorithms, a transient, nonlinear heat and mass transfer model of the exhaust during cold-start is developed. Despite some idealizations, the model replicates the qualitative behavior of the exhaust system. A series of parametric studies reveals the sensitivity of the system response to aging and various noise factors.

In-situ production of oxygen and methane for utilization as a return propellant from Mars for both sample-return and manned missions is currently being developed by NASA in cooperation with major aerospace companies. Various technologies are being evaluated using computer modeling and analysis at the system level. An integrated system that processes the carbon dioxide in the Mars atmosphere to produce liquid propellants has been analyzed. The system is based on the Sabatier reaction that utilizes carbon dioxide and hydrogen to produce methane and water. The water is then electrolyzed to produce hydrogen and oxygen. While the hydrogen is recycled, the propellant gases are liquefied and stored for later use. The process model considers the surface conditions on Mars (temperature, pressure, composition), energy usage, and thermal integration effects on the overall system weight and size. Current mission scenarios require a system that will produce 0.7 kg of propellant a day for 500 days.

In the closed environment of an inhabited spacecraft, a critical aspect of the air revitalization system is the removal of the carbon dioxide (CO2) and water vapor produced by the crew. A number of different techniques can be used for CO2 removal, but current methods are either non-regenerative or require a relatively high power input for thermal regeneration. Two-bed CO2 adsorption systems that can remove CO2 from humid air and be regenerated using pressure-swing desorption offer mass, volume, and power advantages when compared with the other methods. Two classes of sorbent materials show particular promise for this application: Zeolite sorbents, similar to those in the International Space Station (ISS) CO2 removal assembly Functionalized carbon molecular sieves (FCMS), which adsorb CO2 independent of the humidity in the airstream Pressure-swing testing of these two different sorbents under both space station and space suit conditions are currently underway.

A novel microarray-based approach to simultaneous detection, quantitation, and identification of multiple microorganisms found in water and air supplies is presented. The rapid DNA/RNA probe-based approach avoids time consuming cell cultivation procedures by utilizing the inherent amplification property of rRNA combined with highly sensitive proximal CCD detection. Specifically, optimal DNA probes for simultaneously capturing Escherichia coli and Vibrio proteolyticus were arrayed in a 4 x 4 matrix using a novel microarray printer capable of depositing hundreds of probes within a single well (1cm2) of a conventional 96 well microtiter plate. Following hybridization of a 16S rRNA microorganism mixture to the DNA microarray, detection, imaging, quantitation and identification was performed within seconds employing the complimentary PC-based proximal CCD detector/imager.

We present the development of a semiconductor diode laser spectral absorption based gas species sensor for oxygen concentration measurements, intended for life support system monitoring and control applications. Employing a novel self-compensating, noise cancellation detection approach, we experimentally demonstrate better than 1% accuracy, linearity, and stability for monitoring breathing air conditions with 0.2 second response time. We also discuss applications of this approach to CO2 sensing.

Advanced life support flight experiments have been conceptualized for the International Space Station (ISS). Two of the experiments, a high pressure oxygen generator and a carbon dioxide reduction subsystem, offer high payback potential to the ISS program. This paper documents the cost-benefit analyses for these two experiments.

A test has been completed at NASA's Marshall Space Flight Center (MSFC) to evaluate the Water Recovery and Management (WRM) system and Waste Management (WM) urinal design for the United States On-Orbit Segment (USOS) of the International Space Station (ISS). Potable and urine reclamation processors were integrated with waste water generation equipment and successfully operated for a total of 128 days in recipient mode configuration to evaluate the accumulation of contaminants in the water system and to assess the performance of various modifications to the WRM and WM hardware. No accumulation of contaminants were detected in the product water over the course of the recipient mode test. An additional 18 days were conducted in donor mode to assess the ability of the system to removal viral contaminants, to monitor the breakthrough of organic contaminants through the multifiltration bed, and for resolving anomalies that occurred during the test.

A two year test program has been initiated to evaluate the effects of extended duration operation on a solid polymer electrolyte Oxygen Generator Assembly (OGA); in particular the cell stack and membrane phase separators. As part of this test program, the OGA was integrated into the Marshall Space Flight Center (MSFC) Water Recovery Test (WRT) Stage 10, a six month test, to use reclaimed water directly from the water processor product water storage tanks. This paper will document results encountered and evaluated thus far in the life testing program.

The Lunar-Mars Life Support Test Project (LMLSTP) Phase III test examined the use of biological and physicochemical life support technologies for the recovery of potable water from waste water, the regeneration of breathable air, and the maintenance of a shirt-sleeve environment for a crew of four persons for 91 days. This represents the longest duration ground-test of life support systems with humans performed in the United States. This paper will describe the test from the inside viewpoint, concentrating on three major areas: maintenance and repair of life support elements, the scientific projects performed primarily in support of the International Space Station, and numerous activities in the areas of public affairs and education outreach.

The design of a Vacuum-Swing Adsorption (VSA) system to remove metabolic water and metabolic carbon dioxide from the Orion Crew Exploration Vehicle (CEV) atmosphere is presented. The approach for Orion is a VSA system that removes not only 100 percent of the metabolic CO2 from the atmosphere, but also 100% of the metabolic water as well, a technology approach that has not been used in previous spacecraft life support systems. The design and development of the Sorbent Based Atmosphere Regeneration (SBAR) system, including test articles, a facility test stand, and full-scale testing in late 2007 and early 2008 is discussed.

Although designed to remove organic contaminants from a variety of wastewater streams, the planned U.S. and present Russian-provided water processing systems on board the International Space Station (ISS) have capacity limits for some of the more common volatile cleaning solvents used for housekeeping purposes. Using large quantities of volatile cleaning solvents during the ground processing and in-flight operational phases of a crewed spacecraft such as the ISS can lead to significant challenges to the water processing systems. To understand the challenges facing the management of water processing capacity, the relationship between cabin atmospheric quality and humidity condensate loading is presented. This relationship is developed as a tool to determine the cabin atmospheric loading that may compromise water processing system performance.

The design of a vacuum-swing adsorption process to remove metabolic water, metabolic carbon dioxide, and metabolic and equipment generated trace contaminant gases from the crew exploration vehicle (CEV) atmosphere is presented. For the CEV, the sorbent-based atmosphere revitalization (SBAR) system must remove all metabolic water, a technology approach that has not been used in previous spacecraft life support systems. Design and development of a prototype SBAR, a full scale and subscale facility test stand, and other aspects of the SBAR development program is discussed.

A series of tests has been conducted at the NASA Marshall Space Flight Center (MSFC) to evaluate the performance of the Space Station Freedom (SSF) water recovery system. Potable and urine reclamation processors were integrated with waste water generation equipment and successfully operated for a total of 144 days. This testing marked the first occasion in which the waste feed sources for previous potable and hygiene loops were combined into a single loop and processed to potable water quality. Reclaimed potable water from the combined waste waters routinely met the SSF water quality specifications. In the last stage of this testing, data was obtained that indicated that the Water Processor (WP) presterilizer may not be required to meet the potable water quality specification.

This research focused on the testing of the original potable water processor aboard Space Station Freedom that was to produce potable water from the humidity condensate and additional water generated by carbon dioxide reduction. Humidity condensate was simulated by an influent water model “Ersatz.” The humidity condensate was treated with multifiltration (MF) beds that consisted of a train of sorption beds (referred to as “Unibed”) designed to remove specific contaminants. For the complete simulated MF system runs tested for 100 bed volumes (BV) (volume processed/total column volume), 0.6% of the TOC was removed by the SAC/IRN 77 (Strong Acid Cation exchange resin), 39.6% of the total organic carbon (TOC) was removed by the WBA/IRA 68 (Weak Base Anion exchange resin), 13.2% of the TOC was removed by activated carbon adsorption (580-26), and the remaining sorbent media acted as polishing units to remove an additional 1.6% of the TOC at steady state.

Life Sciences research on Space Station will utilize rats to study the effects of the microgravity environment on mammalian physiology and to develop countermeasures to those effects for the health and safety of the crew. The animals will produce metabolic water which must be reclaimed to minimize logistics support. The condensate from the Research Animal Holding Facility (RAHF) flown on Spacelab Life Sciences-2 (SLS-2) in October 1993 was used as an analog to determine the type and quantity of constituents which the Space Station (SS) water reclamation system will have to process. The most significant organics present in the condensate were 2-propanol, glycerol, ethylene glycol, 1,2-propanediol, acetic acid, acetone, total proteins, urea and caprolactam while the most significant inorganic was ammonia. Microbial isolates included Xanthomonas, Sphingobacterium, Pseudomonas, Penicillium, Aspergillus and Chrysosporium.

Computer models are currently being developed by NASA and major aerospace companies to characterize regenerative life support waste water reclamation bioreactors. Detailed models increase understanding of complex processes within the bioreactors and predict performance capabilities over a wide range of operating parameters. Bench-top scale bioreactors are contributing to the development and validation of these models. The purpose of the detailed bioreactor model is to simulate the complex water purification processes as accurately as possible by minimizing the use of simplifying assumptions and empirical relationships. Fundamental equations of mass transport and microbial kinetics were implemented in a finite-difference model structure to maximize accuracy and adaptability to various bioreactor configurations. The model development is based upon concepts and data from the available literature and data from the bench top bioreactor investigations.

A test has been completed at NASA's Marshall Space Flight Center (MSFC) to evaluate the latest Water Recovery and Management (WRM) system and Waste Management (WM) urinal design for the United States On-Orbit Segment (USOS) of the International Space Station (ISS) with higher fidelity hardware and integration than has been achieved in previous integrated tests. Potable and urine reclamation processors were integrated with waste water generation equipment and successfully operated for a total of 116 days to evaluate the impacts of changes made as a result of the redesign from Space Station Freedom (SSF) to the ISS. This testing marked the first occasion in which the WRM was automated at the system level, allowing for evaluation of the hardware performance under ISS operating conditions. It was also the first time a “flight-like” Process Control Water Quality Monitor (PCWQM) and a WM urinal were tested in an integrated system.