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It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

High concentrations of diesel fuel can accumulate in the engine oil, especially in vehicles equipped with diesel particle filters. Fuel dilution can decrease the viscosity of engine oil, reducing its film thickness. Higher concentrations of fuel are believed to accumulate in oil with biodiesel than with diesel fuel because biodiesel has a higher boiling temperature range, allowing it to persist in the sump. Numerous countries are taking actions to promote the use of biodiesel. The growing interest for biodiesel has been driven by a desire for energy independence (domestically produced), the increasing cost of petroleum-derived fuels, and an interest in reducing greenhouse gas emissions. Biodiesel can affect engine lubrication (through fuel dilution), as its physical and chemical properties are significantly different from those of petrodiesel. Many risks associated with excessive biodiesel dilution have been identified, yet its actual impact has not been well quantified.

A three phase catalytic mathematical model was developed for analysis and optimization of the volatile reactor assembly (VRA) used on International Space Station (ISS) Water Processor. The Langmuir-Hinshelwood Hougen-Watson (L-H) expression was used to describe the surface reaction rate. Small column experiments were used to determine the L-H rate parameters. The test components used in the experiments were acetic acid, acetone, ethanol, 1-propanol, 2-propanol and propionic acid. These compounds are the most prevalent ones found in the influent to the VRA reactor. The VRA model was able to predict performance of small column data and experimental data from the VRA flight experiment.