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Management of human feces and wastes is a major challenge in space vehicles due to the potential biohazards and malodorous compounds emanating during collection and storage of feces and wastes. To facilitate safe, yet realistic human waste management research, we have previously developed human fecal simulants for research activities. The odoriferous compounds in feces and wastes reduce the quality of life for astronauts, can reduce performance, and can even cause health problems. The major odoriferous compounds of concern belong to four groups of chemicals, volatile fatty acids, volatile sulfurous compounds, nitrogenous compounds and phenols. This paper attempts to review the problem of odor detection and odor control with advanced technology. There has been considerable progress in odor detection and control in the animal industry and in the dental profession.

In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.

Of the many competing technologies for resource recovery from solid wastes for long duration manned missions such as a lunar or Mars base, incineration technology is one of the most promising and certainly the most well developed in a terrestrial sense. Various factors are involved in the design of an optimum fluidized bed incinerator for inedible biomass. The factors include variability of moisture in the biomass, the ash content, and the amount of fuel nitrogen in the biomass. The crop mixture in the waste will vary; consequently the nature of the waste, the nitrogen content, and the biomass heating values will vary as well. Variation in feed will result in variation in the amount of contaminants such as nitrogen oxides that are produced in the combustion part of the incinerator. The incinerator must be robust enough to handle this variability. Research at NASA Ames Research Center using the fluidized bed incinerator has yielded valuable data on system parameters and variables.

Oxidation is one of a number of technologies that are being considered for waste management and resource recovery from waste materials generated on board space missions. Oxidation processes are a very effective and efficient means of clean and complete conversion of waste materials to sterile products. However, because oxidation uses oxygen there is an “oxygen penalty” associated either with resupply of oxygen or with recycling oxygen from some other source. This paper is a systems approach to the issue of oxygen penalty in life support systems and presents findings on the oxygen penalty associated with an integrated oxidation-Sabatier-Oxygen Generation System (OGS) for waste management in an Advanced Life Support System. The findings reveal that such an integrated system can be operated to form a variety of useful products without a significant oxygen penalty.

Pyrolysis is a very versatile waste processing technology which can be tailored to produce a variety of solid, liquid, and/or gaseous products. The main disadvantages of pyrolysis processing are: (1) the product stream is more complex than for many of the alternative treatments; (2) the product gases cannot be vented directly into the cabin without further treatment because of the high CO concentrations. One possible solution is to combine a pyrolysis step with catalytic oxidation (combustion) of the effluent gases. This integration takes advantage of the best features of each process. The advantages of pyrolysis are: insensitivity to feedstock composition, no oxygen consumption, and batch operation. The main advantage of oxidation is the simplicity and consistency of the product stream. In addition, this hybrid process has the potential to result in a significant reduction in Equivalent System Mass (estimated at 10-40%) and system complexity.