Search Results

Several complementary experimental techniques were applied to investigate kinetics of diesel soot oxidation by O2 in an attempt to provide accurate data for modeling of the Diesel Particulate Filters regeneration process. For two diesel soot samples with measurably different properties, it was shown that the complexity of their overall kinetic behavior was due to an initial period of rapidly changing reactivity. This initial high reactivity was understood not to be related to the SOF, and was quantitatively correlated to the extent of soot pre-oxidation. This initial reactivity can affect the averaged apparent kinetic parameters, for example resulting in the lower apparent activation energy values. After the initial soot pre-oxidation, which consumed ∼10-25% of carbon, the remaining soot was behaving very uniformly, producing linear Arrhenius plots in a remarkably broad range of temperatures (330-610°C) and integral conversions (up to 90%).