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To detect an air-fuel ratio in wide range is very important to control the automotive engines with low fuel consumption and low exhaust emissions. Although the application of zirconia electrolyte for this purpose has been proposed by the authors several years ago, there remained several problems due to the contamination of gas diffusion apertures which are exposed to the exhaust gas environment. Here the behavior of ions transported in zirconia electrolyte have been analyzed to optimize the structure and characteristics, and to guarantee the long life operation of sensor. Gas contents and their reactions in combustion process under the wide range air-fuel ratio have been analyzed, and these results were reflected to the analysis of ion transportation in zirconia electrolyte. Experimental results supported the analytical results, and they showed the possibilities of long life operation of zirconia air-fuel ratio sensor utilizing ion transportation phenomena.

A thermodynamic analysis of mixture formation in cylinders that takes into account mixture inhomogeneity and the wall film is presented. Conditions for obtaining low hydrocarbon emission are clarified analytically as a function of the fuel mass of the wall film and inhomogeneity of the mixture. Optimum processes for atomizing and vaporizing fuel are presented to reduce the inhomogeneity and the fuel mass of the film.

Mixture formation technology for gasoline engine multipoint fuel injection systems has been investigated. The fuel injector's spray, the volatility of droplets floating in the air flow, the movement of droplets around the intake valve's upper surface, the volatility of droplets on heated surfaces, and the process of atomizing droplets in the intake valve air flow was analyzed. Droplet diameters and spray patterns for good mixture formation without liquid film in cylinders have been clarified. When sequential injection is used for better responsiveness in fuel injection systems, engine performance may be reduced through increased HC emissions in some conditions. Reducing the diameter of spray droplets and preventing fuel from concentrating in the intake valve promotes vaporization, reduces fuel concentration on cylinder walls, and prevents reductions in engine performance.