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This study was aimed at experimentally investigating the impact of diesel/natural gas (NG) dual-fuel retrofitting onto gaseous emissions emitted by i) legacy, model year (MY) 2005 heavy-duty engines with cooled EGR and no after-treatment system, and ii) a latest technology engine equipped with DPF and urea-SCR after-treatment systems that is compliant with 2010 US-EPA emissions standards. In particular, two different dual-fuel conversion kits were evaluated in this study with pure methane (CH4) being used as surrogate for natural gas. Experiments were conducted on an engine dynamometer over a 13-mode steady-state test cycle as well as the transient FTP required for engine certification while gaseous emissions were sampled through a CVS system. Tailpipe NOx emissions were observed at a comparable level for diesel and diesel/CH4 dual-fuel operation for the 2010 compliant engine downstream the SCR.

Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.

To meet the ignition system needs of large bore high pressure lean burn natural gas engines a laser diode side pumped passively Q-switched laser igniter was designed and tested. The laser was designed to produce the optical intensities needed to initiate ignition in a lean burn high brake mean effective pressure (BMEP) engine. The experimentation explored a variety of optical and electrical input parameters that when combined produced a robust spark in air. The results show peak power levels exceeding 2 MW and peak focal intensities above 400 GW/cm2. Future research avenues and current progress with the initial prototype are presented and discussed.

New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.

The temporary deactivation of the selective catalytic reduction (SCR) device due to malfunction requires the engine control to engage multiple engine-out calibrations. Further, it is expected that emitted particles will be different in composition, size and morphology when an engine, which meets the 2010 particulate matter (PM) gravimetric limits, is programmed with multiple maps. This study investigated the correlation between SCR-out/engine-out PM emissions from an 11-liter Volvo engine. Measurement of PM concentrations and size distributions were conducted under steady state and transient cycles. Ion Chromatograph analysis on gravimetric filters at the SCR-out has revealed the presence of sulfates. Two different PM size-distributions were generated over a single engine test mode in the accumulation mode region with the aid of a design of experiment (DOE) tool. The SCR-out PM size distributions were found to correlate with the two engine-out distributions.

For engine operations involving low load conditions for an extended amount of time, the exhaust temperature may be lower than that necessary to initiate the urea hydrolyzation. This would necessitate that the controller interrupt the urea supply to prevent catalyst fouling by products of ammonia decomposition. Therefore, it is necessary for the engine controller to have multiple calibrations available in regions of engine operation where the aftertreatment does not perform well, so that optimal exhaust conditions are guaranteed during the wide variety of engine operations. In this study the test engine was equipped with a catalyzed diesel particulate filter (DPF) and a selective catalytic reduction system (SCR), and programmed with two different engine calibrations, namely the low-NOx and the low fuel consumption (low-FC).

Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Further growth of diesel engines in the light-duty and heavy-duty vehicular market is closely linked to the potential health risks of diesel exhaust. The California Air Resources Board and the Office of Environmental Health Hazard Assessment have identified diesel exhaust as a toxic air contaminant. The International Agency for Research on Cancer concluded that diesel particulate is a probable human carcinogen [1]. Cleaner burning liquid fuels, such as those derived from natural gas via the Fischer-Tropsch (FT) process, offer a potentially economically viable alternative to standard diesel fuel while providing reduced particulate emissions. Further understanding of FT operation may be realized by investigating the differences in toxicity and potential health effects between particulate matter(PM) derived from FT fuel and that derived from standard Federal diesel No. 2 (DF).

The emissions reduction of Fischer-Tropsch (FT) diesel fuel has been demonstrated in several recent publications in both laboratory engine testing and in-use vehicle testing. Reduced emission levels have been attributed to several chemical and physical characteristics of the FT fuels including reduced density, ultra-low sulfur levels, low aromatic content and high cetane rating. Some of the effects of these attributes on the combustion characteristics in diesel engines have only recently been documented. In this study, a Ricardo Proteous, single-cylinder, 4-stroke DI engine is instrumented for in-cylinder pressure measurements. The engine was run at several steady engine states at multiple timing conditions using both federal low sulfur and natural gas derived FT fuels. The emissions and performance data for each fuel at each steady state operating conditions were compared.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

Reactivity controlled compression ignition (RCCI) is a form of dual-fuel combustion that exploits the reactivity difference between two fuels to control combustion phasing. This combustion approach limits the formation of oxides of nitrogen (NOX) and soot while retaining high thermal efficiency. The research presented herein was performed to determine the influences that high reactivity (diesel) fuel properties have on RCCI combustion characteristics, exhaust emissions, fuel efficiency, and the operable load range. A 4-cylinder, 1.9 liter, light-duty compression-ignition (CI) engine was converted to run on diesel fuel (high reactivity fuel) and compressed natural gas (CNG) (low reactivity fuel). The engine was operated at 2100 revolutions per minute (RPM), and at two different loads, 3.6 bar brake mean effective pressure (BMEP) and 6 bar BMEP.

Diesel Particulate Filters (DPFs) are well assessed exhaust aftertreatment devices currently equipping almost every modern diesel engine to comply with the most stringent emission standards. However, an accurate estimation of soot content (loading) is critical to managing the regeneration of DPFs in order to attain optimal behavior of the whole engine-after-treatment assembly, and minimize fuel consumption. Real-time models can be used to address challenges posed by advanced control systems, such as the integration of the DPF with the engine or other critical aftertreatment components or to develop model-based OBD sensors. One of the major hurdles in such applications is the accurate estimation of engine Particulate Matter (PM) emissions as a function of time. Such data would be required as input data for any kind of accurate models. The most accurate way consists of employing soot sensors to gather the real transient soot emissions signal, which will serve as an input to the model.

In order to comply with stringent 2010 US-Environmental Protection Agency (EPA) on-road, Heavy-Duty Diesel (HDD) emissions regulations, the Selective Catalytic Reduction (SCR) aftertreatment system has been judged by a multitude of engine manufacturers as the primary technology for mitigating emissions of oxides of nitrogen (NOx). As virtually stand-alone aftertreatment systems, SCR technology further represents a very flexible and efficient solution for retrofitting legacy diesel engines as the most straightforward means of cost-effective compliance attainment. However, the addition of a reducing agent injection system as well as the inherent operation limitations of the SCR system due to required catalyst bed temperatures introduce new, unique problems, most notably that of ammonia (NH₃) slip.

Diesel particulate filters (DPFs) are recognized as the most efficient technology for particulate matter (PM) reduction, with filtration efficiencies in excess of 90%. Design guidelines for DPFs typically are: high removal efficiency, low pressure drop, high durability and capacity to resist high temperature excursions during regeneration events. The collected mass inside the trap needs to be periodically oxidized to regenerate the DPF. Thus, an in-depth understanding of filtration and regeneration mechanisms, together with the ability of predicting actual DPF conditions, could play a key role in optimizing the duration and number of regeneration events in case of active DPFs. Thus, the correct estimation of soot loading during operation is imperative for effectively controlling the whole engine-DPF assembly and simultaneously avoidingany system failure due to a malfunctioning DPF. A viable way to solve this problem is to use DPF models.

The need for a cleaner and less expensive alternative energy source to conventional petroleum fuels for powering the transportation sector has gained increasing attention during the past decade. Special attention has been directed towards natural gas (NG) which has proven to be a viable option due to its clean-burning properties, reduced cost and abundant availability, and therefore, lead to a steady increase in the worldwide vehicle population operated with NG. The heavy-duty vehicle sector has seen the introduction of natural gas first in larger, locally operated fleets, such as transit buses or refuse-haulers. However, with increasing expansion of the NG distribution network more drayage and long-haul fleets are beginning to adopt natural gas as a fuel.

Stringent emission regulations have forced drastic technological improvements in diesel after treatment systems, particularly in reducing Particulate Matter (PM) emissions. Those improvements generally regard the use of Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF) and lately also the use of Selective Catalyst Reduction (SCR) systems along with improved engine control strategies for reduction of NOx emissions from these engines. Studies that have led to these technological advancements were made in controlled laboratory environment and are not representative of real world emissions from these engines or vehicles. In addition, formation and evolution of PM from these engines are extremely sensitive to overall changes in the dilution process.

Both field research and certification data show that the lean burn natural gas powered spark ignition engines offer particulate matter (PM) reduction with respect to equivalent diesel power plants. Concerns over PM inventory make these engines attractive despite the loss of fuel economy associated with throttled operation. Early versions of the Cummins L-10 natural gas engines employed a mixer to establish air/fuel ratio. Emissions measurements by the West Virginia University Transportable Heavy Duty Emissions Testing Laboratories on Cummins L-10 powered transit buses revealed the potential to offer low emissions of PM and oxides of nitrogen, (NOx) but variations in the mixture could cause emissions of NOx, carbon monoxide and hydrocarbons to rise. This was readily corrected through mixer repair or readjustment. Newer versions of the L-10 engine employ a more sophisticated fueling scheme with feedback control from a wide range oxygen sensor.