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Unregulated emissions from a DI diesel engine with ultra-high EGR low temperature combustion were analyzed using Fourier transform infrared (FTIR) spectroscopy and the reduction characteristics of both regulated and unregulated emissions by two exhaust catalysts were investigated. With ultra-high EGR suppressing the in-cylinder soot and Nox formation as well as with the exhaust catalysts removing the engine-out THC and CO emissions, clean diesel operation in terms of ultra-low regulated emissions (Nox, PM, THC, and CO) is established in an operating range up to 50% load. To realize smokeless low temperature combustion at higher loads, EGR has to be increased to a rate with the overall (average) excess air ratio less than the stoichiometric ratio.

A variable valve timing (VVT) mechanism has been applied in a high-speed direct injection (HSDI) diesel engine. The effective compression ratio (εeff) was lowered by means of late intake valve closing (LIVC), while keeping the expansion ratio constant. Premixed charge compression ignition (PCCI) combustion, adopting the Miller-cycle, was experimentally realized and numerically analyzed. Significant improvements of NOx and soot emissions were achieved for a wide range of engine speeds and loads, frequently used in a transient mode test. The operating range of the Miller-PCCI combustion has been expanded up to an IMEP of 1.30 MPa.

Repeatabilities of PM measurements on a heavy-duty diesel engine equipped with a diesel particulate filter (DPF) using a filter weighing method and a number counting method with a full flow dilution system and a partial flow system were evaluated. The filter method with partial flow exhibited the best repeatability. However, a good correlation between the full flow and the partial flow number counting results suggests that the fluctuations observed using the number counting method were caused by changes in the engine exhaust. Applying a strict preconditioning procedure should improve the repeatability of the number counting method because this method is more sensitive than the filter weighing method. In addition, the effects of the specifications for the number counting method were evaluated. The results indicate that the hose length from the tip of the sampling probe to the inlet of the number counting system had a negligible effect.

A homogeneous-charge compression-ignition (HCCI) engine system that was fuelled with dimethyl ether (DME) and methanol-reformed gas (MRG) has been proposed in the previous research. Adjusting the proportion of DME and MRG can effectively control the ignition timing of the engine. In the system, both fuels are to be produced from methanol in onboard reformers utilizing the engine exhaust gas heat. While hydrogen contained in MRG has the main role of the ignition control, hydrogen increases with carbon dioxide in the methanol reforming. This paper investigates the influence of carbon dioxide on HCCI combustion engine with the ignition control by hydrogen. Both thermal and chemical effects of carbon dioxide are analyzed.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

The use of biomass fuels for vehicles has been a focus of attention all over the world in terms of prevention of global warming, effective utilization of resources and local revitalization. For the purpose of beneficial use of unused biomass resources, the movement of the use of bioethanol and biodiesel made from them has spread in Japan. In Japan, biodiesel is mainly made from waste cooking oil collected by local communities or governments, and in terms of local production for local consumption, it is used as neat fuel (100% biofuel) or mixed with diesel fuel in high concentration for the vehicles. On the other hand, extremely low emission level must be kept for not only gasoline vehicles but also diesel vehicles in the post new long-term regulation implemented from 2009 in Japan.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

In order to discuss future technical issues for urea SCR (selective catalytic reduction) system, it is necessary to assess various technical possibilities that would be applied to urea SCR systems which is capable of complying with future emission level requirements, for example Japanese 2009 emission regulation. In this paper, three measures (enhanced insulation on a DOC (diesel oxidation catalyst), aggressive urea solution injection and idling stop) are installed on a urea SCR system of a commercial engine system in order to achieve further NOx (nitrogen oxide) reductions. With combination of these three measures, NOx is drastically reduced to the levels lower than 0.7 g/kWh, which is a NOx limit value of the Japanese 2009 emission regulation. NH3 (ammonia) and HCN (hydro cyanide) are also measured as unregulated harmful components.

The effects of blending ETBE to diesel fuel on the characteristics of low temperature diesel combustion and exhaust emissions were investigated in a naturally-aspirated DI diesel engine with large rates of cooled EGR. Low temperature smokeless diesel combustion in a wide EGR range was established with ETBE blended diesel fuel as mixture homogeneity is promoted with increased premixed duration due to decreases in ignitability as well as with improvement in fuel vaporization due to the lower boiling point of ETBE. Increasing the ETBE content in the fuel helps to suppress smoke emissions and maintain efficient smokeless operation when increasing EGR, however a too high ETBE content causes misfiring at larger rates of EGR. While the NOx emissions increase with increases in ETBE content at high intake oxygen concentrations, NOx almost completely disappears when reducing the intake oxygen content below 14 % with cooled EGR.

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO2 + 64% Ar mixture which has a similar specific heat capacity as N2 shows lower smoke emissions than with N2. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation.

The Poly-Aromatic Hydrocarbon (PAH) formation process from benzene was studied using a laminar flow reactor and GC-MS. In addition to PAH, acetylene and ethylene were observed. Without oxygen at temperatures over 1070 K, the amount of PAH and C2 species increased as the benzene concentration decreased. Addition of oxygen caused a linear decrease in the benzene concentration, and almost all of the benzene was consumed under stoichiometric conditions at all temperatures. At 1053 K, the concentrations of PAH and C2 species were not affected by the addition of oxygen. On the other hand, when the temperature was greater than 1070 K, the amount of PAH formed increased as the equivalence ratio increased, until the equivalence ratio was about 4. Above this equivalence ratio, the amounts decreased. Amounts of phenanthrene and biphenyl were large compared to those of other PAHs, which indicated that the dominant PAH formation path is the formation of phenanthrene via biphenyl.

Palm oil has the important advantage of productivity compared to other vegetable oils such as rapeseed oil and soybean oil. However, the cold flow performance of palm oil methyl ester (PME) is poorer than other vegetable oil based biodiesel fuels. Previous research by the authors has shown that ethanol blending into PME improves the cold flow performance and considerably reduces smoke emission. The reduced smoke may be expected to allow an expansion in the EGR limit and lead to reduced NOx. This paper experimentally analyses the influence of EGR on smoke and NOx emissions from the diesel combustion with PME/ethanol blended fuel. The mechanisms in the smoke reduction are also analyzed.

The biomass fuel is expected to solve the global warming due to a carbon neutral. A rapeseed oil methyl ester (RME) as biomass fuel was selected, and also a low sulfur diesel fuel is tested as reference fuel in this study. The experiments were carried out to improve diesel emissions and engine performance using high boost and high rate EGR system and a common rail injection system in a single cylinder engine. The diesel emissions and engine performance have been measured under the experimental conditions such as charging boost pressure from atmospheric pressure to 401.3kPa maximum and changing EGR rate from 0% to 40% maximum. RME contain about 10 mass % oxygen in the fuel molecule. Furthermore, RME does not contain aromatic hydrocarbons in the fuel. Due to these chemical properties, RME can be used at 40% high EGR condition.

Supersonic jet / resonance enhanced multi-photon ionization (Jet-REMPI) technique was focused on the analyzing method for gas mixture like exhaust gas from automobiles. In this method, when the mass number and wavelength of excitation laser are determined adequately, the target compound can be monitored selectively. We developed a new analyzer utilizing REMPI method. Using this analyzer, real-time monitoring of exhaust gas from a motorcycle and diesel vehicles was conducted. As a result of real-time monitoring test of the vehicles, concentrations of aromatic compounds like benzene toluene etc. were quantified and real-time changes of their concentrations were observed.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).

The use of biodiesel fuels as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO2 emission, because biodiesel is produced from renewable biomass resources. Biodiesel is usually blended to conventional diesel fuel in various proportions. It is possible that this biodiesel blending causes the problems on emission characteristics of modern diesel engine, because it could be confirmed that the application of neat biodiesel to modern diesel engines whose control parameters were optimized for conventional diesel fuel deteriorated the emission performances. It is necessary to clarify the effect of biodiesel blending on exhaust emissions of modern diesel engine. Rapeseed oil methyl ester (RME) was selected as a biodiesel used in this study.

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

Lean NOx trap (LNT) and Urea-SCR system are effective aftertreatment systems as NOx reduction device in diesel engines. On the other hand, DPF has already been developed as PM reduction device and it has been used in various vehicles. LNT can absorb and reduce NOx emission in wide range exhaust temperatures, from 150°C to 400°C, and the size of LNT component can be compact in comparison with Urea-SCR system because LNT uses the diesel fuel as a reducing agent and it is needless to install the reducing agent tank in the vehicle. In this study, authors have shown that the NOx conversion rate of LNT is high in the case of extremely low NOx concentration from the engine. Also, the effects of LNT and DPF were examined using the Super Clean Diesel (SCD) Engine, which has low NOx level before aftertreatment and has been finished as Japanese national project.

The regulation of particulate matter (PM) from diesel engines is coming to be very stringent at present. The usage of diesel particulate filter (DPF) is now under consideration in many heavy-duty diesel vehicle manufacturers to reduce PM emission from a diesel engine. The possibility that very fine particles may pass through DPF is suggested. The understanding of fine particles emission behaviors and the countermeasure of reducing particle emissions from DPF will come to be important in near future. The behavior of particle size distribution after DPF has not been studied enough yet. In this study, fine particles generated by a diesel engine are introduced to honeycomb type and SiC (Silicon Carbite) fiber type DPFs and the collection performances of fine particles by various DPFs with different surface structures have been examined.