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Traditionally in the United States, Diesel engines have negative connotations, primarily due to their association with heavy duty trucks, which are wrongly characterized as “dirty.” Diesel engines are more energy efficient and produce less carbon dioxide than gasoline engines, but their particulate and NOx emissions are more difficult to reduce than spark ignition engines. To tackle this problem, a number of after-treatment technologies are available, such as Diesel Lean NOx Traps (LNTs)), which reduces oxides of nitrogen, and the Diesel particulate filter (DPF), which reduces particulate matter. Sophisticated control techniques are at the heart of these technologies, thus making Diesel engines run cleaner. Another potentially unattractive aspect of Diesel engines is noise.

A prototype CO sensor based on anatase TiO2 was fabricated and tested in a Ford V6 engine. Fuel combustion was programmed to be near stoichiometric conditions, and emissions were monitored with an FT-IR analytical instrument. The sensor, positioned near the oxygen sensor in the exhaust manifold, was successfully tested for 50 cycles of revving and idling, and was observed to respond quickly and reproducibly. The sensor response was correlated to the CO concentration at specific engine temperatures and was found to vary systematically with increasing concentrations. This sensor has promising potentials to monitor the efficiency of the catalytic converter.

One of the gray areas in the implementation of regulations limiting the generation of pollutants from mobile sources is the actual effectiveness of the exhaust gas emissions control strategy in vehicles that have been in use for some time. While it is possible today to conduct limited diagnostics with the on-board engine computer by performing periodic checks to verify the validity of the signals measured by the on-board sensors, and to measure tailpipe emissions during routine inspection and maintenance, the task of correlating these measurements with each other to provide an on-line, accurate diagnosis of critical malfunctions has thus far proven to be a very challenging task, especially in the case of misfire.