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Technical Paper

Sampling Strategies for Characterization of the Reactive Components of Heavy Duty Diesel Exhaust Emissions

Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.
Technical Paper

Nitric Oxide Conversion in a Spark Ignited Natural Gas Engine

Understanding the nitric oxide (NO) conversion process plays a major role in optimizing the Selective NOX Recirculation (SNR) technique. SNR has been proven in gasoline and diesel engines, with up to 90% NOX conversion rates being achieved. This technique involves adsorbing NOX from an exhaust stream, then selectively desorbing the NOX into a concentrated NOX stream, which is fed back into the engine's intake, thereby converting a percentage of the concentrated NOX stream into harmless gases. The emphasis of this paper is on the unique chemical kinetic modeling problem that occurs with high concentrations of NOX in the intake air of a spark ignited natural gas engine with SNR. CHEMKIN, a chemical kinetic solver software package, was used to perform the reaction modeling. A closed homogeneous batch reactor model was used to model the fraction of NOX versus time for varying initial conditions and constants.
Technical Paper

Emissions from Low- and Mid-Level Blends of Anhydrous Ethanol in Gasoline

Typically ethanol is present in gasoline as a 10% blend by volume (E10), although E15, E85 (51 to 83%), and E0 are also available at selected stations. Numerous studies of tailpipe regulated emissions have been conducted to compare emissions from E10 and E0, and there is a growing body of literature addressing blends of E15 and higher. Isolating the effect of ethanol in a study is philosophically difficult, because the ethanol naturally displaces some hydrocarbons, because the ethanol interacts with the remaining gasoline, and because properties of mixing are often nonlinear. Some studies have used splash blending, simply mixing the ethanol with a reference gasoline to produce a blend for comparison to the reference. Others have used match blending, where the objective is to match selected properties of the blend to properties of a reference gasoline.