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Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

This study evaluates iso-butanol as a pathway to introduce higher levels of alternative fuels for recreational marine engine applications compared to ethanol. Butanol, a 4-carbon alcohol, has an energy density closer to gasoline than ethanol. Isobutanol at 16 vol% blend level in gasoline (iB16) exhibits energy content as well as oxygen content identical to E10. Tests with these two blends, as well as indolene as a reference fuel, were conducted on a Mercury 90 HP, 4-stroke outboard engine featuring computer controlled sequential multi-port Electronic Fuel Injection (EFI). The test matrix included full load curves as well as the 5-mode steady-state marine engine test cycle. Analysis of the full load tests suggests that equal full load performance is achieved across the engine speed band regardless of fuel at a 15-20°C increase in exhaust gas temperatures for the alcohol blends compared to indolene.