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Particulate and nitrogen oxide emissions from a 1.9-liter Volkswagen diesel engine were measured for three different fuels: neat diesel fuel, a blend of diesel fuel with 10% ethanol, and a blend of diesel fuel with 15% ethanol. Engine-out emissions were measured on an engine dynamometer for five different speeds and five different torques using the standard engine-control unit. Results show that particulate emissions can be significantly reduced over approximately two-thirds of the engine map by using a diesel-ethanol blend. Nitrogen oxide emissions can also be significantly reduced over a smaller portion of the engine map by using a diesel-ethanol blend. Moreover, there is an overlap between the regions where particulate emissions can be reduced by up to 75% and nitrogen oxide emissions are reduced by up to 84% compared with neat diesel fuel.

A thermophoretic particulate sampling device was used to investigate the detailed morphology and microstructure of diesel particulates at various engine-operating conditions. A 75 HP Caterpillar single-cylinder direct-injection diesel engine was operated to sample particulate matter from the high-temperature exhaust stream. The morphology and microstructure of the collected diesel particulates were analyzed using a high-resolution transmission electron microscope and subsequent image processing/data acquisition system. The analysis revealed that spherical primary particles were agglomerated together to form large aggregate clusters for most of engine speed and load conditions. Measured primary particle sizes ranged from 34.4 to 28.5 nm at various engine-operating conditions. The smaller primary particles observed at high engine-operating conditions were believed to be caused by particle oxidation at the high combustion temperature.

Lean operation of natural gas fired reciprocating engines has been the preferred mode of operation as it allows low NOx emissions and simultaneous high overall efficiencies. In such engines, the operation point is often close to where the ignition boundary and the knock limiting boundary cross-over. While knocking is, to a large extent, limited by engine design, ignition of lean-mixtures is limited by the mode of ignition. Since significant benefits can be achieved by extending the lean-ignition limits, many groups have been researching alternate ways to achieve ignition reliably. One of the methods, laser ignition, appears promising as it achieves ignition at high pressures and under lean conditions relatively easily. However, most of the current knowledge about laser ignition is based on measurements performed at room temperature. In this paper, ignition studies on methane-air mixtures under in-cylinder conditions are presented.

The effects of nitrogen-enriched air, supplied by an air separation membrane, on NOx emissions from a 1.9-L turbocharged direct-injection diesel engine were investigated. To enrich combustion air with more nitrogen, prototype air separation membranes were installed between the after-cooler and intake manifold without any additional controls. The effects of nitrogen-enriched combustion air on NOx emissions were compared with and without exhaust gas recirculation (EGR). At sufficient boost pressures (>50 kPag), nitrogen-enriched air from the membrane provided intake oxygen levels that were similar to those of EGR. Compared with EGR, nitrogen-enriched air provided 10-15% NOx reductions during medium to high engine loads and speeds. At part loads, when turbocharger boost pressure was low, the air separation membrane was not effective in enriching air with nitrogen. As a result, NOx reduction was lower, but it was 15-25% better than when EGR was not used.