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The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.

A gas chromatographic technique was used to determine the vapor pressures of blends of six candidate diesel fuel oxygenates with three diesel fuels at 0, 5, 10, 30, and 100 percent blend levels. Both the oxygenates and the diesel fuels were selected to represent a variety of chemical compositions. The vapor pressures were determined over a range of temperatures from -30 C to +30 C. In each case the fraction of the vapor pressure derived from the oxygenate and the fuel was identified. The vapor pressure results showed that there were significant deviations from ideality, leading to both higher and lower vapor pressures than would be predicted from Raoult's Law. These results are significant for fire safety and evaporative emissions as well as for a more basic understanding of the behavior of these blends. Data were also obtained on the heats of vaporization for each of the blends.

Miscibility, water tolerance, cloud point, and flash point data are presented for seven candidate diesel fuel oxygenates: dipentyl ether, dibutoxymethane, 2-ethoxyethyl ether, diethyl maleate, tripropylene glycol monomethyl ether, dibutyl maleate, and glycerol tributrate. These oxygenates were blended with three different diesel fuels: an oil sands diesel, an ultra-low sulfur diesel, and a Fischer-Tropsch diesel. Blend levels included 0, 5, 10, 30, and 100 % oxygenate. Properties were measured at temperatures of -30, -15, 0, 15, and 30 C.

The objective of this program, which is supported by the U.S. Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL), is to provide an unbiased and comprehensive comparison of transit buses operating on alternative fuels and diesel fuel. The information for this comparison was collected from eight transit bus sites. The fuels studied are natural gas (CNG and LNG), alcohol (methanol and ethanol), biodiesel (20 percent blend), propane (only projected capital costs; no sites with heavy-duty propane engines were available for studying operating experience), and diesel. Data was collected on operations, maintenance, bus equipment configurations, emissions, bus duty cycle, and safety incidents. Representative and actual capital costs were collected for alternative fuels and were used as estimates for conversion costs. This paper presents preliminary results.

Hydrogen-powered vehicles offer the promise of significantly reducing the amount of pollutants that are expelled into the environment on a daily basis by conventional hydrocarbon-fueled vehicles. While very promising from an environmental viewpoint, the technology and systems that are needed to store the hydrogen (H2) fuel onboard and deliver it to the propulsion system are different from what consumers, mechanics, fire safety personnel, the public, and even engineers currently know and understand. As the number of hydrogen vehicles increases, the likelihood of a rollover or collision of one of these vehicles with another vehicle or a barrier will also increase.

This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.

The Diesel Emission Control - Sulfur Effects (DECSE) program is a joint U.S. government/industry program that studies the impact of diesel sulfur levels on four types of emission control systems. One type of system, Diesel Particulate Filters (DPF), removes particulate matter (PM) from the exhaust stream by collection on a filter. The critical operating issue for DPF technology is the cleaning or regeneration of the control device (by oxidation of the collected PM) to prevent plugging. However, oxidation of sulfur in the exhaust forms sulfates, which are measured as PM. Two types of tests are conducted to evaluate the impacts of fuel sulfur on DPF performance: (1) emissions tests for PM components and gases, and (2) experiments to measure the effect of fuel sulfur on the regeneration temperature required by the filter devices.

Previous studies have shown that regenerating particulate filters are very effective at reducing particulate matter emissions from diesel engines. Some particulate filters are passive devices that can be installed in place of the muffler on both new and older model diesel engines. These passive devices could potentially be used to retrofit large numbers of trucks and buses already in service, to substantially reduce particulate matter emissions. Catalyst-type particulate filters must be used with diesel fuels having low sulfur content to avoid poisoning the catalyst. A project has been launched to evaluate a truck fleet retrofitted with two types of passive particulate filter systems and operating on diesel fuel having ultra-low sulfur content. The objective of this project is to evaluate new particulate filter and fuel technology in service, using a fleet of twenty Class 8 grocery store trucks. This paper summarizes the truck fleet start-up experience.