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Blends of gasoline, diesel fuel and ethanol (“dieseline”) have shown promise in engine studies examining low temperature combustion using compression ignition. They offer the possibility of high efficiency combined with low emissions of oxides of nitrogen and soot. However, unlike gasoline or diesel fuel alone, such mixtures can be flammable in the headspace above the liquid in a vehicle fuel tank at common ambient temperatures. Quantifying their flammability characteristics is important if these fuels are to see commercial service. The parameter of most interest is the Upper Flammable Limit (UFL) temperature, below which the headspace vapour is flammable. In earlier work a mathematical model to predict the flammability of dieseline blends, including those containing ethanol, was developed and validated experimentally. It was then used to study the flammability of a wide variety of dieseline blends parametrically.

Gasoline Compression Ignition (GCI) has been identified as a technology which could give both high efficiency and relatively low engine-out emissions. The introduction of any new vehicle technology requires widespread availability of appropriate fuels. It would be ideal therefore if GCI vehicles were able to operate using the standard grade of gasoline that is available at the pump. However, in spite of recent progress, operation at idle and low loads still remains a formidable challenge, given the relatively low autoignition reactivity of conventional gasoline at these conditions. One conceivable solution would be to use both diesel and gasoline, either in separate tanks or blended as a single fuel (“dieseline”). However, with this latter option, a major concern for dieseline would be whether a flammable mixture could exist in the vapour space in the fuel tank.

Low Temperature Combustion using compression ignition may provide high efficiency combined with low emissions of oxides of nitrogen and soot. This process is facilitated by fuels with lower cetane number than standard diesel fuel. Mixtures of gasoline and diesel (“dieseline”) may be one way of achieving this, but a practical concern is the flammability of the headspace vapours in the vehicle fuel tank. Gasoline is much more volatile than diesel so, at most ambient temperatures, the headspace vapours in the tank are too rich to burn. A gasoline/diesel mixture in a fuel tank therefore can result in a flammable headspace, particularly at cold ambient temperatures. A mathematical model is presented that predicts the flammability of the headspace vapours in a tank containing mixtures of gasoline and diesel fuel. Fourteen hydrocarbons and ethanol represent the volatile components. Heavier components are treated as non-volatile diluents in the liquid phase.

Low Temperature Combustion using compression ignition may provide high efficiency combined with low emissions of oxides of nitrogen and soot. This process is facilitated by fuels with lower cetane number than standard diesel fuel. Mixtures of gasoline and diesel (“dieseline”) may be one way of achieving this; however, a gasoline/diesel mixture in a fuel tank can result in a flammable headspace, particularly at very cold ambient temperatures. A mathematical model to predict the flammability of dieseline blends, including those containing ethanol, was previously validated. In this paper, that model is used to study the flammability of dieseline blends parametrically. Gasolines used in the simulations had Dry Vapour Pressure Equivalent (DVPE) values of 45, 60, 75, 90 and 110 kPa.