Search Results

The overall program objectives were three fold: assess the benefits and limitations of oxygenated diesel fuels on engine performance and emissions identify oxygenates most suitable for potential use in future diesel formulations based on physico-chemical properties (e.g. flash point), toxicity, biodegradability and estimated cost of production perform limited emissions and performance testing of the oxygenated diesel blends select at least two oxygenated compounds for advanced engine testing In Part 1 of this program which is described in this paper, an extensive literature review was conducted to identify potential oxygenates for blending into diesel fuels. As many as 71 oxygenates were identified for the initial screening process. Based on a set of physical and chemical properties, a screening methodology was developed to select the 8 oxygenates that will be eligible for engine testing.

Both physical experiments and detailed chemical kinetics studies establish that Sonex micro-chambers imbedded in the walls of the piston bowl of an I.C. engine generate highly reactive intermediate chemical species and radicals- which, when allowed to mix with the fresh charge of the next cycle in the main chamber, substantially alter the chemical kinetics of main chamber combustion. A much more stable overall combustion process is observed, requiring substantially leaner air-fuel ratios than normal, and with much lower ignition temperatures. The net result, without any efficiency penalty, is an engine with an “ultra-clean” exhaust and with a greater tolerance to a wider range of fuels. Crucial to this process is the quenching of the flame in the passages connecting the micro-chambers to the piston bowl. It is flame quenching which enables the incomplete combustion of the charge trapped in the micro-chamber cavities.

This numerical study examines the chemical-kinetics mechanism responsible for EGR NOx reduction in standard engines. Also, it investigates the feasibility of using EGR alone in hydrogen-air and methanol-air combustion to help generate and retain the same radicals previously found to be responsible for the inducement of the autoignition (in such mixtures) in IC engines with the SONEX Combustion System (SCS) piston micro-chamber. The analysis is based on a detailed chemical kinetics mechanism (for each fuel) that includes NOx production. The mechanism for H-air-NOx combustion makes use of 19 species and 58 reactions while the methanol-air-NOx mechanism is based on the use of 49 species and 227 reactions. It was earlier postulated that the combination of thermal control and charge dilution provided by the EGR produces an alteration in the combustion mechanisms (for both the hydrogen and methanol cases) that lowers peak cycle temperatures-thus greatly reducing the production of NOx.