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Combination of an NOx storage and reduction catalyst (NSRC, called also lean NOx trap, LNT) and a catalyst for the selective catalytic reduction of NOx by NH₃ (NH₃-SCR) offers a potential to significantly increase the efficiency of NSRC-based exhaust gas aftertreatment systems. Under most situations the SCR catalyst is able to adsorb the NH₃ peaks generated in the NSRC during the regeneration and utilize it for additional NOx reduction in the course of the consequent lean phase. This synergy becomes more important with the aged NSRC, where generally lower NOx conversions and higher NH₃ yields in wider range of operating temperatures are observed (in comparison with the fresh or de-greened NSRC). In this paper we present global kinetic models for the NSRC (Pt/Ba/Ce/gγ-Al₂O₃ catalyst type) and NH₃-SCR (Fe-ZSM5 catalyst type).

Beside hard facts as performance, emissions and fuel consumption especially the brand specific attributes such as styling and sound are very emotional, unique selling prepositions. To develop these emotional characters, within the given boundary conditions of the future pass-by regulation, it is necessary to define them at the very beginning of the project and to follow a consequent development process. The following paper shows examples of motorcycle NVH development work on noise cleaning and sound engineering using a hybrid development process combining front loading, simulation and testing. One of the discussed solutions is the investigation of a piston pin offset in combination with a crankshaft offset for the reduction of friction. The optimization of piston slap noise as a result of the piston secondary motion was performed by simulation. As another example a simulation based development was performed for the exhaust system layout.

The present work introduces an extended particulate filter model focusing on capabilities to cover catalytic and surface storage reactions and to serve as a virtual multi-functional reactor/separator. The model can be classified as a transient, non-isothermal 1D+1D two-channel model. The applied modeling framework offers the required modeling depth to investigate arbitrary catalytic reaction schemes and it follows the computational requirement of running in real-time. The trade-off between model complexity and computational speed is scalable. The model is validated with the help of an analytically solved reference and the model parametrization is demonstrated by simulating experimentally given temperatures of a heat-up measurement. The detailed 1D+1D model is demonstrated in a concept study comparing the impact of different spatial washcoat distributions.

The future emission regulation (BS V) in India is expected to create new challenges to meet the particulate matter (PM) limit for diesel cars. The upcoming emission norms will bring down the limit of PM by 80 % when compared to BS IV emission norms. The diesel particulate filter (DPF) is one of the promising technologies to achieve this emission target. The implementation of DPF system into Indian market poses challenges against fuel quality, driving cycles and warranty. Hence, it is necessary to do a detailed on-road evaluation of the DPF system with commercially available fuel under country specific drive cycles. Therefore, we conducted full vehicle durability testing with DPF system which is available in the European market to evaluate its robustness and reliability with BS III fuel (≤350ppm sulfur) & BS IV (≤50ppm sulfur) fuel under real Indian driving conditions.

The present work describes an existing transient, non-isothermal 1D+1D particulate filter model to capture the impact of different types of particulate matter (PM) on filtration and regeneration. PM classes of arbitrary characteristics (size, composition etc.) are transported and filtered following standard mechanisms. PM deposit populations of arbitrary composition and contact states are used to describe regeneration on a micro-kinetical level. The transport class and deposit population are linked by introducing a splitting deposit matrix. Filtration and regeneration modes are compared to experimental data from literature and a brief numerical assessment on the filtration model is performed. The filter model as part of an exhaust line is used in a concept study on different coating variants. The same exhaust line model is connected to an engine thermodynamic and vehicle model. This system model is run through a random drive cycle in office simulation.

A numerical model for a diesel oxidation catalyst (DOC) is presented. It is based on a spatially 1D, physical and chemically based modeling of the relevant processes within the catalytic monolith. A global reaction kinetic approach has been chosen to describe the chemical reactions. Water condensation and evaporation was also considered, in order to predict the cold start behavior. Reaction kinetic parameters have been evaluated from a series of laboratory experiments. A correlation between the kinetic parameters and the noble metal loading was developed. The model was used in combination with a SCR-Model to study the influence of changes of noble metal loading and DOC volume on the overall transient NOx performance of a DOC+DPF+SCR system.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

This paper presents a numerical study on the impact of washcoat diffusion on the overall conversion performance of catalytic converters. A comprehensive transient 1D pore diffusion reaction model is embedded in state-of-the-art 1D and 3D catalytic converter models. The pore diffusion model is discussed with its model equations and the applied diffusive transport approaches are summarized. The diffusion reaction model is validated with the help of two available analytical solutions. The impact of basic washcoat characteristics such as pore diameters or thickness on overall conversion performance is investigated by selected 1D+1D calculations. This model is also used to highlight the impact of boundary layer transfer, pore diffusion and reaction on the overall converter conversion performance. The interaction of pore diffusion and flow non-uniformities is demonstrated by 3D+1D CFD simulations.

The continuously decreasing emission limits lead to a growing importance of exhaust aftertreatment in Diesel engines. Hence, methods for achieving a rapid catalyst light-off after engine cold start and for maintaining the catalyst temperature during low load operation will become more and more necessary. The present work evaluates several valve timing strategies concerning their ability for doing so. For this purpose, simulations as well as experimental investigations were conducted. A special focus of simulation was on pointing out the relevance of exhaust temperature, mass flow and enthalpy for these thermomanagement tasks. An increase of exhaust temperature is beneficial for both catalyst heat-up and maintaining catalyst temperature. In case of the exhaust mass flow, high values are advantageous only in case of a catalyst heat-up process, while maintaining catalyst temperature is supported by a low mass flow.

Particulate emission reduction has long been a challenge for diesel engines as the diesel diffusion combustion process can generate high levels of soot which is one of the main constituents of particulate matter. Gasoline engines use a pre-mixed combustion process which produces negligible levels of soot, so particulate emissions have not been an issue for gasoline engines, particularly with modern port fuel injected (PFI) engines which provide excellent mixture quality. Future European and US emissions standards will include more stringent particulate limits for gasoline engines to protect against increases in airborne particulate levels due to the more widespread use of gasoline direct injection (GDI). While GDI engines are typically more efficient than PFI engines, they emit higher particulate levels, but still meet the current particulate standards.

While the market share for diesel engines for LD vehicles in Europe has grown continuously in the past years, the market share in North America is still negligible. Until now, it has been possible to fulfill the limits for nitrogen oxides (NOx) both in Europe and in North America by engine measures alone, without using an active NOx aftertreatment system. With the introduction of Tier II Bin 8 and Tier II Bin 5 emissions legislation in the US in 2007, most new diesel applications will now require NOx aftertreatment. One of the possible technologies for the reduction of nitrogen oxides in lean exhaust gas is the NOx storage catalyst which has become the generally-accepted choice for engines with gasoline direct injection systems and which is also utilized in the current diesel Bluetec I systems from Daimler. For heavier applications urea-SCR is the preferred technology to fulfill NOx legislation limits.

Diesel engines have a strong contribution to the CO2 reduction in Europe in the past years. To enable these C02 reduction potential to the US market Mercedes Benz developed the BLUETEC technology for light duty diesel engines. The BLUETEC technology contains an optimized diesel engine and combustion system, an aftertreatment system with DOC, DPF and an active SCR catalyst with AdBlue Dosing System and an enhanced ECU functionality and calibration. For fulfilling the world strongest emission limits of the US legislation there have to be solutions developed for the handling of AdBlue under cold climate below -11°C, managing the refilling event, and the onboard diagnostic. To ensure the emission stability over full useful life on high NOx conversions level, intensive testing of the catalyst technology had to be done. In addition there are self learning functionalities for adapting the dosing strategy to ensure the maximum NOx performance.

The new Sprinter targets the USA and Canada markets nationwide to reconfirm Daimlers statement for Diesel engine in vans. Consequentially, the MY2007 Sprinter follows his successful predecessor as again the first - and up to now the only - Diesel vehicle in its class now meeting even the strict EPA07 requirement in California. For the growing market in North America an unique development for the successor for the previous 5-cylinder Diesel Sprinter had been made. The new 3 liter V6 Diesel engine is based on numerous corporate wide versions from Mercedes and Chrysler Passenger cars and SUVs and has its roots also in smaller and larger Mercedes vans. Effective January 2007 the NAFTA04 requirements have been replaced by the NAFTA07 values. Meeting those led to significant changes of the latest Sprinter in European EURO4 version. Both, engine and exhaust hardware as well as the ECU-data had been modified consequentially.

Catalyzed wall-flow particulate filters are increasingly applied in diesel exhaust after-treatment for multiple purposes, including low-temperature catalytic regeneration, CO and hydrocarbon conversion, as well as exothermic heat generation during forced regeneration. In order to optimize Precious Metals usage, it may be advantageous to apply the catalytic coating non-uniformly in the DPF, a technology referred to as “catalyst zoning”. In order to simulate the behavior of such a filter, one has to consider coupled transport-reaction modeling. In this work, a previously developed model is calibrated versus experimental data obtained with full-scale catalyzed filters on the engine dynamometer. In a next step, the model is validated under a variety of operating conditions using engine experiments with zoned filters. The performance of the zoned catalyst is analyzed by examining the transient temperature and species profiles in the inlet and outlet channels.

In order to control NOx reduction with NOx storing lean NOx traps (LNT), a gas sensor downstream of the LNT is presently preferred. It is a disadvantage that no means are available to gauge directly the LNT NOx loading level and the catalyst quality. The presented novel sensor consists of interdigital electrodes that are deposited on a planar substrate. On its reverse side, a temperature sensor is applied. Both sides are covered with the original catalyst coating, allowing detecting directly electrical impedance and temperature of the coating. Such sensors were integrated in different positions of an LNT. It is shown in synthetic exhausts as well as in engine tests that in-situ measurements of the electrical impedance of the LNT coating are appropriate to determine directly the catalyst status. Hence, the local degree of NOx loading as well as the local regeneration status can be measured. Furthermore, sulfur poisoning, desulfurization, and thermal ageing can be directly seen.

Beginning in 2010, Daimler's well-known Diesel Sprinter van has to fulfill the new and clearly tighter NOx emission standards of NAFTA10 (EPA, CARB). This requires an integrated approach of further engine optimizations and the implementation of an innovative exhaust aftertreatment technology. The goal was to develop an overall concept which meets simultaneously the tightened emission standards (including OBD limits) and the increasing customer demands of more power and torque without losing the high fuel efficiency of the small and highly efficient 3-liter V6 diesel engine OM642, which already has been installed in the NAFTA07 Sprinter. In the early stages of the concept phase, the most appropriate NOx aftertreatment technology and certification form (engine or vehicle) had to be selected for this specific vehicle class in the van segment with enhanced requirements to durability, economical efficiency and specific driving behavior.

For medium- and heavy-duty diesel engines, the development of new catalyst technologies and particulate filters is necessary to fulfill increasingly stringent emission regulations. An important aspect is the durability of the after-treatment system and therefore its efficiency over lifetime. Lubrication oil additives contain components such as phosphorous or zinc to ensure engine durability. Diesel oxidation catalyst (DOC) and coated diesel particulate filter (cDPF) catalytic coatings are negatively influenced by contamination on the surface with these components (chemical ageing). The components have a negative impact on the exhaust after-treatment systems performance. Additionally the cDPF is filled with oil ash. Engine tests are conducted to analyze the effect of lubrication oil additives on after-treatment system performance. In one study, lubrication oil with increased sulfur ash content is used.

Mercedes-Benz BlueTEC passenger cars have been on the cutting edge of clean diesel technology since 2006. These BlueTEC vehicles furthermore passed millions of kilometers in the hands of customers. SCR-equipped passenger cars already meet the most stringent exhaust emissions standards in international markets such as the USA, Europe and Japan. Diesel engines with BlueTEC technology also reduce CO₂ emissions and provide the high torque and performance associated with the diesel engine in addition to keeping exhaust emissions at the lowest possible level. Nowadays the requirements for SCR emission concepts are increasing continuously. In fact the emission legislation is getting stricter with the LEVIII emission standards in 2015. Additionally the requirements and effort for on-board diagnosis are increasing year after year. In combination with ambitious CO₂ targets all these issues constitute the further challenges of BlueTEC SCR emission concepts for worldwide markets.

The acoustics of automotive intake and exhaust systems is typically modeled using linear acoustics or gas-dynamics simulation. These approaches are preferred during basic sound design in the early development stages due to their computational efficiency compared to complex 3D CFD and FEM solutions. The linear acoustic method reduces the component being modelled to an equivalent acoustic two-port transfer matrix which describes the acoustic characteristic of the muffler. Recently this method was used to create more detailed and more accurate models based on a network of 3D cells. As the typical automotive muffler includes perforated elements and sound absorptive material, this paper demonstrates the extension of the 3D linear acoustic network description of a muffler to include the aforementioned elements. The proposed method was then validated against experimental results from muffler systems with perforated elements and sound absorptive material.

Modern Diesel engines require an integrated development of combustion strategies, air management and exhaust aftertreatment. This study presents a comprehensive simulation approach with the aim to support engine development activities in the virtual environment. A real-time capable engine, vehicle and control model is extended by three key features. First, a pollutant production model is embedded in a two-zone cylinder model. Second, a framework for catalytic pollutant conversion is built focusing on modern diesel exhaust aftertreatment systems. Third, an extended species transport model is introduced considering the transport of pollutants through the air path. The entire plant model is validated on the example of a passenger car Diesel engine. The predicted engine behavior is compared with steady-state measurements. The NO formation model is investigated for a series of steady-state and transient operating conditions.