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Evaporative and running loss emissions were measured in a fleet of ten (1 989) current and seven (1983-85) older vehicles with fuels whose compositions varied in aromatic, olefin, and MTBE content and 90 percent distillation temperature (T9O). Emission compositions from each test were analyzed for individual hydrocarbon species. The individual hydrocarbon profiles were used to calculate evaporative and running loss emission reactivities using Carter maximum incremental reactivity (MIR) and maximum ozone reactivity (MOR) scales. Ozone reactivity estimates were expressed as Ozone Forming Potential (gO3/test) and Specific Reactivity (gO3/gNMOG) for both reactivity scales. The data were analyzed by regression analysis to estimate changes in the mass and reactivity of evaporative emissions due to changes in fuel composition. Previous studies have focused on how fuel volatility affects evaporative emissions without regard for the chemical composition of the fuels.